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\(n_{Zn}=\dfrac{9,75}{65}=0,15\left(mol\right)\\
pthh:Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)
0,15 0,15 0,15 0,15
\(V_{H_2}=0,15.22,4=3,36L\\
m_{H_2SO_4}=0,15.98=14,7\left(g\right)\\
m_{ZnSO_4}=161.0,15=24,15g\\
\)
\(n_{CuO}=\dfrac{6}{80}=0,075\left(mol\right)\\
pthh:CuO+H_2\underrightarrow{t^o}Cu+H_2O\\
LTL:0,075< 0,15\)
=> H2 dư
\(n_{Cu}=n_{CuO}=0,075\left(mol\right)\\
m_{Cu}=0,075.64=4,8g\)
a) Mg + 2HCl --> MgCl2 + H2
b) \(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\)
PTHH: Mg + 2HCl --> MgCl2 + H2
0,2--->0,4-------------->0,2
=> mHCl = 0,4.36,5 = 14,6 (g)
c) \(V_{H_2}=0,2.22,4=4,48\left(l\right)\)
d)
PTHH: CuO + H2 --to--> Cu + H2O
0,2------->0,2
=> mCu = 0,2.64 = 12,8 (g)
nFe = 11,2/56 = 0,2 (mol)
PTHH: Fe + 2HCl -> FeCl2 + H2
Mol: 0,2 ---> 0,4 ---> 0,2 ---> 0,2
VH2 = 0,2 . 22,4 = 4,48 (l)
PTHH: CuO + H2 -> (to) Cu + H2O
Mol: 0,2 <--- 0,2 ---> 0,2
mCu = 0,2 . 64 = 12,8 (g)
a, \(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
_____0,2____0,4___________0,2 (mol)
\(\Rightarrow m_{HCl}=0,4.36,5=14,6\left(g\right)\)
b, \(V_{H_2}=0,2.24,79=4,958\left(l\right)\)
c, \(Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)
____________0,2__2/15 (mol)
\(\Rightarrow m_{Fe}=\dfrac{2}{15}.56=\dfrac{112}{15}\left(g\right)\)
Số mol của 13 gam Zn:
\(n_{Zn}=\dfrac{m}{M}=\dfrac{13}{65}=0,2\left(mol\right)\)
PTHH: \(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
1 : 2 : 1 : 1 (g)
0,2\(\rightarrow\) 0,4 : 0,2 : 0,2 (mol)
a,Khối lượng của 0,4 mol HCl:
\(m_{HCl}=n.M=0,4.36,5=14,6\left(g\right)\)
b, Thể tích khí H2:
\(V_{H_2}=n.24,79=0,2.24,79=4,958\left(l\right)\)
\(3H_2+Fe_2O_3\underrightarrow{t^o}2Fe+3H_2O\)
Khối lượng của \(\dfrac{2}{15}\) mol Fe:
\(n_{Fe}=\dfrac{m}{M}=\dfrac{2}{\dfrac{15}{56}}\approx7,5\left(g\right)\)
\(n_{Mg}=\dfrac{3,6}{24}=0,15\left(mol\right)\)
PTHH: Mg + 2HCl ---> MgCl2 + H2
0,15--------------->0,15---->0,15
CuO + H2 --to--> Cu + H2O
0,15------->0,15
=> \(\left\{{}\begin{matrix}m_{MgCl_2}=0,15.95=14,25\left(g\right)\\V_{H_2}=0,15.24,79=3,7195\left(l\right)\\m_{Cu}=0,15.64=9,6\left(g\right)\end{matrix}\right.\)
\(n_{Mg}=\dfrac{3,6}{24}=0,15\left(mol\right)\\
pthh:Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)
0,15 0,15 0,15
\(m_{MgCl_2}=0,15.95=14,25\left(g\right)\\
V_{H_2}=0,3.22,4=3,36\left(L\right)\\
pthh:CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
0,3 0,3 0,3
\(m_{Cu}=0,3.64=19,2\left(g\right)\)
\(a\)) \(PTHH:Zn+2HCl\underrightarrow{t^o}ZnCl_2+H_2\)
0,25 0,5 0,25 0,25
b) nZn=\(\dfrac{m}{M}=\dfrac{16,25}{65}=0,25\left(mol\right)\)
\(V_{H_2}=n.22,4=0,25.22,4=5,6\left(l\right)\)
c) \(m_{HCl}=n.M=0,5.36,5=18,25\left(g\right)\)
nMg = 6/24 = 0,25 (mol)
PTHH: Mg + 2HCl -> MgCl2 + H2
nH2 = 0,25 (mol(
VH2 = 0,25 . 24,79 = 6,1975 (l)
CuO + H2 -> (t°) Cu + H2O
nCu = 0,25 (mol)
mCu = 0,25 . 64 = 16 (g)
a) Mg + H2SO4 --> MgSO4 + H2
b) \(n_{Mg}=\dfrac{14,4}{24}=0,6\left(mol\right)\)
PTHH: Mg + H2SO4 --> MgSO4 + H2
0,6--->0,6------->0,6----->0,6
=> \(m_{H_2SO_4}=0,6.98=58,8\left(g\right)\)
c)
PTHH: 2H2 + O2 --to--> 2H2O
0,6-->0,3
=> VO2 = 0,3.24,79 = 7,437 (l)
=> Vkk = 7,437.5 = 37,185 (l)
\(n_{Mg}=\dfrac{7,2}{24}=0,3\left(mol\right)\)
PTHH:
Mg + 2HCl ---> MgCl2 + H2
0,3-->0,6----------------->0,3
=> \(\left\{{}\begin{matrix}V_{H_2}=24,79.0,3=7,437\left(l\right)\\m_{HCl}=0,6.36,5=21,9\left(g\right)\end{matrix}\right.\)
\(n_{CuO}=\dfrac{12}{80}=0,15\left(mol\right)\)
PTHH: CuO + H2 --to--> Cu + H2O
LTL: 0,15 < 0,3 => H2 dư, vậy H2 khử hết CuO
a, \(n_{Mg}=\dfrac{7,2}{24}=0,3\left(mol\right)\)
Mg + 2HCl -----> MgCl2 + H2
0,3 0,6 0,3
\(V_{H_2}=0,3.22,4=6,72\left(l\right)\)
b, \(m_{HCl}=0,6.36,5=21,9\left(g\right)\)
c, \(n_{CuO}=\dfrac{12}{80}=0,15\left(mol\right)\)
CuO + H2 -----> Cu + H2O
Ta có: \(\dfrac{0,15}{1}< \dfrac{0,3}{1}\) ⇒ CuO hết, H2 dư