Trung hòa 100 ml dung dịch H2SO4 1M bằng dung dịch KOH 5,6%; có khối lượng riêng là 1,045 g/ml thì cần bao nhiêu ml dung dịch KOH?
A. 200 ml.
B. 191,4 ml
C. 100 ml
D. 95,7 ml
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nH2SO4=0,02.1=0,02(ol)
a) PTHH: 2 NaOH + H2SO4 -> Na2SO4 + 2 H2O
0,04____________0,02____0,02(mol)
mNaOH=0,04.40= 1,6(g)
=>mddNaOH= (1,6.100)/20= 8(g)
b) PTHH: H2SO4 + 2 KOH -> K2SO4 + 2 H2O
0,2____________0,04(mol)
=>mKOH=0,04.56=2,24(g)
=>mddKOH= (2,24.100)/5,6=40(g)
=>VddKOH= mddKOH/DddKOH= 40/1,045=38,278(ml)
\(n_{H_2SO_4}=1.0,2=0,2(mol)\\ PTHH:2NaOH+H_2SO_4\to Na_2SO_4+2H_2O\\ a,n_{NaOH}=0,4(mol);n_{Na_2SO_4}=0,2(mol)\\ \Rightarrow \begin{cases} m_{Na_2SO_4}=0,2.142=28,4(g)\\ m_{dd_{NaOH}}=\dfrac{0,4.40}{20\%}=80(g) \end{cases}\\ b,2KOH+H_2SO_4\to K_2SO_4+2H_2O\\ \Rightarrow n_{KOH}=0,4(mol)\\ \Rightarrow m_{dd_{KOH}}=\dfrac{0,4.56}{5,6\%}=400(g)\\ \Rightarrow V_{dd_{KOH}}=\dfrac{400}{1,045}=382,78(ml)\)
Bước 1: nH2SO4 = VH2SO4 . CM H2SO4= 0,2 . 1 = 0,2mol
Bước 2:
PTHH: 2NaOH + H2SO4 → Na2SO4 + H2O
2 mol 1 mol
? mol 0,2mol
nNaOH=0,2.21=0,4mol.nNaOH=0,2.21=0,4mol.
m NaOH= n NaOH.MNaOH = 0,4 . (23 + 16 + 1) = 16g
Bước 3: C% = mNaOH : m dd NaOH => mdd NaOH = mNaOH : C% = 16 : 20% = 80g
a) $2NaOH + H_2SO_4 \to Na_2SO_4 + 2H_2O$
b)
n H2SO4 = 0,03.1 = 0,03(mol)
n NaOH = 2n H2SO4 = 0,06(mol)
=> CM NaOH = 0,06/0,05 = 1,2M
c) $H_2SO_4 + 2KOH \to K_2SO_4 + 2H_2O$
n KOH = 2n H2SO4 = 0,06(mol)
=> m KOH = 0,06.56 = 3,36 gam
=> m dd KOH = 3,36/5,6% = 60(gam)
=> V dd KOH = m/D = 60/1,045 = 57,42(ml)
\(n_{NaOH}=0.1\cdot0.1=0.01\left(mol\right)\)
\(n_{KOH}=0.1\cdot0.1=0.01\left(mol\right)\)
\(V=0.1+0.1=0.2\left(l\right)\)
\(\left[Na^+\right]=\dfrac{0.01}{0.2}=0.05\left(M\right)\)
\(\left[K^+\right]=\dfrac{0.01}{0.2}=0.05\left(M\right)\)
\(\left[OH^-\right]=\dfrac{0.01+0.01}{0.2}=0.1\left(M\right)\)
\(b.\)
\(pH=14+log\left[OH^-\right]=14+log\left(0.1\right)=13\)
\(c.\)
\(H^++OH^-\rightarrow H_2O\)
\(0.02........0.02\)
\(V_{dd_{H_2SO_4}}=\dfrac{0.02}{1}=0.02\left(l\right)\)
\(a.\)
\(n_{NaOH}=0.1\cdot0.1=0.01\left(mol\right)\)
\(n_{KOH}=0.1\cdot0.1=0.01\left(mol\right)\)
\(V=0.1+0.1=0.2\left(l\right)\)
\(\left[Na^+\right]=\dfrac{0.01}{0.2}=0.05\left(M\right)\)
\(\left[K^+\right]=\dfrac{0.01}{0.2}=0.05\left(M\right)\)
\(\left[OH^+\right]=\dfrac{0.01+0.01}{0.2}=0.1\left(M\right)\)
\(b.\)
\(pH=14+log\left(0.1\right)=13\)
\(c.\)
\(H^++OH^-\rightarrow H_2O\)
\(0.02.......0.02\)
\(V_{H_2SO_4}=\dfrac{0.02}{1}=0.02\left(l\right)\)
a) Ta có: \(n_{NaOH}=0,1\cdot0,1=n_{KOH}=0,01\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{OH^-}=0,02\left(mol\right)\\n_{Na^+}=n_{K^+}=0,01\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}\left[OH^-\right]=\dfrac{0,02}{0,2}=0,1\left(M\right)\\\left[Na^+\right]=\left[K^+\right]=\dfrac{0,01}{0,2}=0,05\left(M\right)\end{matrix}\right.\)
b) Ta có: \(pH=14+log\left[OH^-\right]=13\)
c) PT ion: \(OH^-+H^+\rightarrow H_2O\)
Theo PT ion: \(n_{H^+}=n_{OH^-}=0,02\left(mol\right)\)
\(\Rightarrow n_{H_2SO_4}=0,01\left(mol\right)\) \(\Rightarrow V_{ddH_2SO_4}=\dfrac{0,01}{1}=0,01\left(l\right)=10\left(ml\right)\)
Tìm thể tích dung dịch KOH
- Phương trình hoá học :
H 2 SO 4 + 2KOH → K 2 SO 4 + 2 H 2 O
- Số mol KOH tham gia phản ứng :
n KOH = 2 n H 2 SO 4 = 0,02 x 2 = 0,04 mol
- Khối lượng KOH tham gia phản ứng : mKOH = 0,04 x 56 = 2,24 (gam).
- Khối lượng dung dịch KOH cần dùng :
m dd KOH = 2,24x100/5,6 = 40 gam
- Thể tích dung dịch KOH cần dùng:
V dd KOH = 40/1,045 ≈ 38,278 ml
a,b)\(n_{H_2SO_4}=0,2\) theo PT \(2n_{H_2SO_4}=n_{NaOV}=0,4\Rightarrow m_{NaOV}=0,4.4016kg\)
\(H_2SO_4+2NaOH\rightarrow H_2Na_2SO_4+H_2\)
\(m_{ddNaOH}=\dfrac{16}{2}=80g\)
c)\(n_{KOH}=2_{n_{H_2SO_4}}=0,4\Rightarrow m_{KOH}=0,3.56-22,4g\)
\(\Rightarrow m_{KOH\left(dd\right)}=\dfrac{22,4}{0,056}=400\Rightarrow V=\dfrac{400}{1,045}=182,8\left(ml\right)\)
a, \(H_2SO_4+2NaOH\rightarrow Na_2SO_4+2H_2O\) \(\left(1\right)\)
b, Đổi \(20ml=0,02l\)
\(n_{H_2SO_4}=0,02.1=0,02\left(mol\right)\)
Thep phương trình \(\left(1\right)\) ta được:
\(n_{NaOH}=2n_{H_2SO_4}=2.0,02=0,04\left(mol\right)\\ \Rightarrow m_{NaOH}=0,04.40=1,6\left(g\right)\\ \Rightarrow m_{dd NaOH}=\dfrac{1,6}{20}.100=8\left(g\right)\)
c, \(H_2SO_4+2KOH\rightarrow K_2SO_4+2H_2O\) \(\left(2\right)\)
Theo phương trình \(\left(2\right)\):
\(n_{KOH}=2n_{H_2SO_4}=2.0,02=0,04\left(mol\right)\\ \Rightarrow m_{KOH}=0,04.56=2,24\left(g\right)\\ \Rightarrow m_{dd KOH}=\dfrac{2,24}{5,6}.100=40\left(g\right)\\ \Rightarrow V_{dd KOH}=\dfrac{40}{1.045}=38,3\left(ml\right)\)
a) \([OH^-]=\left[KOH\right]=1,5M\)
b) Để trung hòa dung dịch A: \(n_{\left[OH^-\right]}=n_{\left[H^+\right]}\)
\(\Rightarrow0,15=0,5\cdot V_{HCl}\Rightarrow V_{HCl}=0,3l=300ml\)
$2KOH + H_2SO_4 \to K_2SO_4 + 2H_2O$
$n_{KOH} = 2n_{H_2SO_4} = 0,1.2 = 0,2(mol)$
$m_{KOH} = 0,2.56 = 11,2(gam)$
$m_{dd\ KOH} = \dfrac{11,2}{5,6\%} = 200(gam)$
$V_{dd\ KOH} = \dfrac{m}{D} = \dfrac{200}{1,045} = 191,4(ml)$