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a, PT: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
Giả sử: \(\left\{{}\begin{matrix}n_{C_2H_4}=x\left(mol\right)\\n_{C_2H_2}=y\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow x+y=\dfrac{1,344}{22,4}=0,06\left(1\right)\)
Ta có: \(n_{Br_2}=\dfrac{16}{160}=0,1\left(mol\right)\)
Theo PT: \(n_{Br_2}=n_{C_2H_4}+2n_{C_2H_2}=x+2y\left(mol\right)\)
⇒ x + 2y = 0,1 (2)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=0,02\left(mol\right)\\y=0,04\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,02}{0,06}.100\%\approx33,33\%\\\%\text{ }V_{C_2H_2}\approx66,67\%\end{matrix}\right.\)
b, Ta có: 1/2 hỗn hợp khí gồm: 0,01 mol C2H4 và 0,02 mol C2H2.
PT: \(C_2H_4+3O_2\underrightarrow{t^o}2CO_2+2H_2O\)
\(2C_2H_2+5O_2\underrightarrow{t^o}4CO_2+2H_2O\)
Theo PT: \(n_{CO_2}=2n_{C_2H_4}+2n_{C_2H_2}=0,06\left(mol\right)\)
\(CO_2+Ca\left(OH\right)_2\rightarrow CaCO_{3\downarrow}+H_2O\)
Theo PT: \(n_{CaCO_3}=n_{CO_2}=0,06\left(mol\right)\)
\(\Rightarrow m_{cr}=m_{CaCO_3}=0,06.100=6\left(g\right)\)
Bạn tham khảo nhé!
Bài 3
a) C2H4 + Br2 --> C2H4Br2
C2H2 + 2Br2 --> C2H2Br4
b) \(n_{Br_2}=\dfrac{5,6}{160}=0,035\left(mol\right)\)
Gọi số mol C2H4, C2H2 là a, b (mol)
=> \(a+b=\dfrac{0,56}{22,4}=0,025\) (1)
PTHH: C2H4 + Br2 --> C2H4Br2
a---->a
C2H2 + 2Br2 --> C2H2Br4
b---->2b
=> a + 2b = 0,035 (2)
(1)(2) => a = 0,015 (mol); b = 0,01 (mol)
=> \(\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,015}{0,025}.100\%=60\%\\\%V_{C_2H_2}=\dfrac{0,01}{0,025}.100\%=40\%\end{matrix}\right.\)
Bài 4:
a)
CH4 + 2O2 --to--> CO2 + 2H2O
2H2 + O2 --to--> 2H2O
b)
Gọi số mol CH4, H2 là a, b (mol)
=> \(a+b=\dfrac{11,2}{22,4}=0,5\) (1)
PTHH: CH4 + 2O2 --to--> CO2 + 2H2O
a-------------------->a--->2a
2H2 + O2 --to--> 2H2O
b--------------->b
=> \(2a+b=\dfrac{16,2}{18}=0,9\) (2)
(1)(2) => a = 0,4 (mol); b = 0,1 (mol)
=> \(\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{0,4}{0,5}.100\%=80\%\\\%V_{H_2}=\dfrac{0,1}{0,5}.100\%=20\%\end{matrix}\right.\)
c)
VCO2 = 0,4.22,4 = 8,96 (l)
a)
\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
b)
Gọi số mol C2H2, C2H4 là a, b
=> \(a+b=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
\(n_{Br_2}=\dfrac{22,4}{160}=0,14\left(mol\right)\)
PTHH:\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
a---->2a
\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
b--->b
=> 2a + b = 0,14
=> a = 0,04; b = 0,06
\(\left\{{}\begin{matrix}\%V_{C_2H_2}=\dfrac{0,04}{0,1}.100\%=40\%\\\%V_{C_2H_4}=\dfrac{0,06}{0,1}.100\%=60\%\end{matrix}\right.\)
Gọi số mol của C2H4 và C2H2 lần lượt là x và y mol
theo bài ra: x+y = 0,56/22,4 = 0,025 (mol)
Pt:
C2H4 + Br2 → C2H4Br2
x mol x mol x mol
C2H2 + 2 Br2 → C2H2Br4
y mol 2y mol y mol
Số mol n Br2 = x+2y = 5,6/160 = 0,035 9mol)
Giải hệ ta đc: x = 0,015 và y = 0,01
=> %V C2H4 = 0,015/0,025 = 60% ; %V C2H2 = 40%
\(Gọi : n_{C_2H_4} = a; n_{C_2H_2} = b\\ \Rightarrow a + b = \dfrac{5,6}{22,4} = 0,25(1)\\ C_2H_4 + Br_2 \to C_2H_4Br_2\\ C_2H_2 + 2Br_2 \to C_2H_2Br_4\\ n_{Br_2} = a + 2b = \dfrac{56}{160} =0,35(2)\\ (1)(2)\Rightarrow a = 0,15 ; b = 0,1\\ \Rightarrow \%V_{C_2H_4} = \dfrac{0,15}{0,25} .100\% = 60\%\\ \%V_{C_2H_2} = 100\% -60\% = 40\%\)
\(n_{Br_2}=\dfrac{m_{Br_2}}{M_{Br_2}}=\dfrac{16}{160}=0,1mol\)
\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
0,1 0,1 ( mol )
\(\%V_{C_2H_4}=\dfrac{0,1.22,4}{16,8}.100=13,33\%\)
\(\%V_{CH_4}=100\%-13,33\%=86,67\%\)
C2H4+Br2->C2H4Br2
0,05----0,05
n Br2=\(\dfrac{8}{160}\)=0,05 mol
=>%VC2H4=\(\dfrac{0,05.22,4}{5,6}.100=20\%\)
=>%VCH4=80%
c)CH4+2O2-to>CO2+2H2O
1.10-3----2.10-3 mol
C2H4+3O2-to>2CO2+2H2O
2,5.10-4-7,5.10-4 mol
n hh=\(\dfrac{0,028}{22,4}\)=1,25.10-3 mol
=>n C2H4=2,5.10-4 mol
=>n CH4=1.10-3 mol
=>VO2=(2.10-3+7,5.10-4).22,4=0,0616l
\(n_{Br_2}=\dfrac{8}{160}=0,05mol\)
\(\Rightarrow n_{etilen}=n_{Br_2}=0,05mol\)
\(n_{hh}=\dfrac{5,6}{22,4}=0,25mol\)
\(\Rightarrow n_{metan}=n_{hh}-n_{etilen}=0,25-0,05=0,2mol\)
a)\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
b)\(\%V_{metan}=\dfrac{0,2}{0,25}\cdot100\%=80\%\)
\(\%V_{etilen}=100\%-80\%=20\%\)
a) C2H4 + Br2 --> C2H4Br2
C2H2 + 2Br2 --> C2H2Br4
b) Gọi số mol C2H4, C2H2 là a, b (mol)
=> a + b = \(\dfrac{1,68}{22,4}=0,075\left(mol\right)\) (1)
\(n_{Br_2}=\dfrac{16}{160}=0,1\left(mol\right)\)
=> a + 2b = 0,1 (2)
(1)(2) => a = 0,05 (mol); b = 0,025 (mol)
=> \(\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,05}{0,075}.100\%=66,67\%\\\%V_{C_2H_2}=\dfrac{0,025}{0,075}.100\%=33,33\%\end{matrix}\right.\)
c)
PTHH: C2H4 + 3O2 --to--> 2CO2 + 2H2O
0,05--->0,15
2C2H2 + 5O2 --to--> 4CO2 + 2H2O
0,025-->0,0625
=> VO2 = (0,15 + 0,0625).22,4 = 4,76 (l)
a.b.\(n_{Br_2}=\dfrac{16}{160}=0,1mol\)
\(n_{hh}=\dfrac{1,68}{22,4}=0,075mol\)
Gọi \(\left\{{}\begin{matrix}n_{C_2H_2}=x\\n_{C_2H_4}=y\end{matrix}\right.\)
\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
x 2x ( mol )
\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
y y ( mol )
Ta có:
\(\left\{{}\begin{matrix}22,4x+22,4y=1,68\\2x+y=0,1\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}x=0,025\\y=0,05\end{matrix}\right.\)
\(\%V_{C_2H_2}=\dfrac{0,025}{0,075}.100=33,33\%\)
\(\%V_{C_2H_4}=100\%-33,33\%=66,67\%\)
c.
\(2C_2H_2+5O_2\rightarrow\left(t^o\right)4CO_2+2H_2O\)
0,025 0,0625 ( mol )
\(C_2H_4+3O_2\rightarrow\left(t^o\right)2CO_2+2H_2O\)
0,05 0,15 ( mol )
\(V_{O_2}=\left(0,0625+0,15\right).22,4=4,76l\)