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a, \(n_{HCl}=0,1.0,2=0,02\left(mol\right)=n_{H^+}=n_{Cl^-}\)
\(n_{H_2SO_4}=0,1.0,2=0,02\left(mol\right)=n_{SO_4^{2-}}\) \(\Rightarrow n_{H^+}=2n_{H_2SO_4}=0,04\left(mol\right)\)
\(n_{NaOH}=0,3.0,4=0,12\left(mol\right)=n_{Na^+}=n_{OH^-}\)
\(\Rightarrow\sum n_{H^+}=0,02+0,04=0,06\left(mol\right)\)
\(H^++OH^-\rightarrow H_2O\)
0,06__0,06 (mol)
⇒ nOH- dư = 0,12 - 0,06 = 0,06 (mol)
\(\Rightarrow\left\{{}\begin{matrix}\left[Cl^-\right]=\dfrac{0,02}{0,1+0,3}=0,05\left(M\right)\\\left[SO_4^{2-}\right]=\dfrac{0,02}{0,1+0,3}=0,05\left(M\right)\\\left[Na^+\right]=\dfrac{0,12}{0,1+0,3}=0,3\left(M\right)\\\left[OH^-\right]=\dfrac{0,06}{0,1+0,3}=0,15\left(M\right)\end{matrix}\right.\)
b, pH = 14 - (-log[OH-]) ≃ 13,176
a, \(n_{HCl}=0,2.0,1=0,02\left(mol\right)=n_{H^+}=n_{Cl^-}\)
\(n_{H_2SO_4}=0,2.0,15=0,03\left(mol\right)=n_{SO_4^{2-}}\) \(\Rightarrow n_{H^+}=2n_{H_2SO_4}=0,06\left(mol\right)\)
\(\Rightarrow\Sigma n_{H^+}=0,02+0,06=0,08\left(mol\right)\)
\(n_{Ba\left(OH\right)_2}=0,3.0,05=0,015\left(mol\right)=n_{Ba^{2+}}\)
\(\Rightarrow n_{OH^-}=2n_{Ba\left(OH\right)_2}=0,03\left(mol\right)\)
\(H^++OH^-\rightarrow H_2O\)
0,03___0,03 (mol) ⇒ nH+ dư = 0,05 (mol)
\(Ba^{2+}+SO_4^{2-}\rightarrow BaSO_4\)
0,015___0,015______0,015 (mol) ⇒ nSO42- dư = 0,015 (mol)
⇒ m = mBaSO4 = 0,015.233 = 3,495 (g)
\(\left[Cl^-\right]=\dfrac{0,02}{0,2+0,3}=0,04\left(M\right)\)
\(\left[H^+\right]=\dfrac{0,05}{0,2+0,3}=0,1\left(M\right)\)
\(\left[SO_4^{2-}\right]=\dfrac{0,015}{0,2+0,3}=0,03\left(M\right)\)
b, pH = -log[H+] = 1
a, \(n_{NaOH}=0,15.0,2=0,03\left(mol\right)=n_{Na^+}=n_{OH^-}\)
\(n_{KOH}=0,15.0,2=0,03\left(mol\right)=n_{K^+}=n_{OH^-}\)
⇒ ΣnOH- = 0,03 + 0,03 = 0,06 (mol)
\(n_{HCl}=0,25.0,4=0,1\left(mol\right)=n_{H^+}=n_{Cl^-}\)
\(H^++OH^-\rightarrow H_2O\)
0,06____0,06 (mol) ⇒ nH+ dư = 0,1 - 0,06 = 0,04 (mol)
\(\left[Na^+\right]=\left[K^+\right]=\dfrac{0,03}{0,15+0,25}=0,075\left(M\right)\)
\(\left[H^+\right]=\dfrac{0,04}{0,15+0,25}=0,1\left(M\right)\)
\(\left[Cl^-\right]=\dfrac{0,1}{0,15+0,25}=0,25\left(M\right)\)
b, pH = -log[H+] = 1
\(n_{Ba\left(OH\right)_2}=0,3.0,1=0,03\left(mol\right)\\ n_{HCl}=0,2.0,15=0,03\left(mol\right)\\ Ba\left(OH\right)_2+2HCl\rightarrow BaCl_2+2H_2O\\ Vì:\dfrac{n_{Ba\left(OH\right)_2\left(đề\right)}}{n_{Ba\left(OH\right)_2\left(PTHH\right)}}=\dfrac{0,03}{1}>\dfrac{n_{HCl\left(đề\right)}}{n_{HCl\left(PTHH\right)}}=\dfrac{0,03}{2}\\ \Rightarrow Ba\left(OH\right)_2dư\\ n_{Ba\left(OH\right)_2\left(p.ứ\right)}=\dfrac{n_{HCl}}{2}=\dfrac{0,03}{2}=0,015\\ n_{Ba\left(OH\right)_2\left(dư\right)}=0,03-0,015=0,015\left(mol\right)\\ \left[OH^-\right]=2.\left[Ba\left(OH\right)_2\left(dư\right)\right]=\dfrac{0,015}{0,3+0,2}=0,03\left(M\right)\\ \Rightarrow pH=14+log\left[OH^-\right]=14+log\left[0,03\right]\approx12,477\)
Nồng độ mol/lít các ion trong dd A:
\(\left[OH^-\left(dư\right)\right]=0,06\left(M\right)\left(nt\right)\\\left[Cl^-\right]=2.\left[BaCl_2\right]=2.\left(\dfrac{0,015}{0,5}\right)=0,06\left(M\right)\\ \left[Ba^{2+}\right]=0,03+ 0,03=0,06\left(M\right)\)
a, \(n_{H^+}=0,025.0,2=0,005\left(mol\right)\)
\(n_{OH^-}=0,01.2.0,3=0,006\left(mol\right)\)
\(\Rightarrow n_{OH^-dư}=0,001\left(mol\right)\)
\(\Rightarrow\left[OH^-\right]_{dư}=\dfrac{0,001}{1}=10^{-3}\)
\(\Rightarrow\left[H^+\right]=10^{-11}\)
\(\Rightarrow pH=11\)
b, \(n_{Fe^{2+}}=n_{SO_4^{2-}}=0,02.0,1=0,002\left(mol\right)\)
\(n_{Ba^{2+}}=0,01.0,3=0,003\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{BaSO_4\downarrow}=n_{SO_4^{2-}}=0,002\left(mol\right)\\n_{Fe\left(OH\right)_2\downarrow}=n_{OH^-dư}=0,001\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow m_{\downarrow}=0,002.233+0,001.90=0,556\left(g\right)\)
nH+=0,04 mol nOH-=0,03 mol
H+ + OH- --------> H20
0,04 0,03
0,03 0,03 0,03
0,01
a/ [H+] du=0,01/0,2=0,05 M
[SO42-]=0,01/0,2=0,05 M
[K+]=0,01/0,2=0,05 M
[Ba2+]=0,01/0,2=0,05M
b/ nH+ du=0,01/0,2=0,05 M
pH=-log(0,05)=1,3
c/ khoi luong chat ran thu duoc sau phan ung la
mcr= mSO42- + mK+ + mBa2+
=0,01.96+0,01.39+0,01.137
=2,72g
ta có : \(\Sigma n_{H^+}=n_{HCl}+2n_{H_2SO_4}=0,04\left(mol\right)\)
\(\Sigma n_{OH^-}=n_{KOH}+2n_{Ba\left(OH\right)_2}=0,03\left(mol\right)\)
\(n_{SO_4^{2-}}=0,01\left(mol\right)\) ; \(n_{Ba^{2+}}=0,01\left(mol\right)\)
a, PT : \(H^++OH^-\rightarrow H_2O\)
0,03 0,03 0,03 (mol)
\(\Rightarrow n_{H^+}dư=0,01\left(mol\right)\)
đến đây tự tính đc nha. dùng ct \(CM=\dfrac{n}{V}\)
b, \(PH=-log[H^+]=-log\left(\dfrac{0,01}{0,2}\right)\simeq1,3\)
c, \(Ba^{2+}+SO_4^{2-}\rightarrow BaSO_4\downarrow\)
0,01 0,01 0,01 (mol)\(mcr=m\downarrow+m_{K^+}=m_{BaSO_4}+m_{K+}=\left(0,01\times233\right)+\left(0,01\times39\right)=2,72\left(g\right)\)
a) trong 100 ml dung dịch HCl và H2SO4
CM[H+]=[Cl-]=0,02 M
[SO4 2-]=0,01M
[H+] =2.0,01=0,02 M
trong 100ml dung dịch KOH và Ba(OH)2
[K+]=[OH-]=0,01M
[Ba2+]=0,01M
[OH-]=0,02M
b)n(H+)=0,02+0,02=0,04mol
n(OH-)=0,01+0,02=0,03mol
khi trộn : H+ + OH- =>H2O
0,03<--0,03
=> nH+ dư=0,01mol
=> [H+]=0,05M
=> pH=-lg(0,05)=1,3
nH+=0,06 mol nOH-=0,02 mol
H+ + OH- ---> H2O
0,06 0,02
0,02 0,02 0,02
0,04
[H+] du=0,04/0,5=0,08 M
[Na+]=0,02/0,5=0,04M
[Cl-]=0,06/0,5=0,12M
pH= -log(0,08)=1,09