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Theo đề bài ta có : ⎧⎪ ⎪ ⎪⎨⎪ ⎪ ⎪⎩VddH2O4=601,2=50(ml)nNaOH=20.20100.40=0,1(mol){VddH2O4=601,2=50(ml)nNaOH=20.20100.40=0,1(mol)
nFe = 1,68/56 = 0,03 mol
a) Ta có PTHH :
2NaOH + H2SO4 -> Na2SO4 + 2H2O
0,1mol......0,05mol
=> CMH2SO4 = 0,05/0,05=1(M)
1.
\(PTHH:2CH_3COOH+Mg\rightarrow\left(CH_3COO\right)_2Mg+H_2\)
\(n_{Mg}=\frac{7,2}{24}=0,3\left(mol\right)\)
\(m_{CH3COOH}=\frac{120.20}{100}=24\left(g\right)\Rightarrow n_{CH3COOH}=0,4\left(mol\right)\)
Theo PT:
\(n_{\left(CH3COO\right)2Mg}=\frac{1}{2}n_{CH3COOH}=0,2\left(mol\right)\)
\(\Rightarrow m_{\left(CH3COO\right)2Mg}=28,4\left(g\right)\)
\(\Rightarrow m_{dd_{spu}}=7,2+120-0,4=126,8\left(g\right)\)
\(\Rightarrow C\%_{CH3COOMg}=22,3\%\)
2.
\(PTHH:CH_3COOH+NaOH\rightarrow CH_3COONa+H_2O\)
Ta có :
\(m_{CH3COH}=\frac{15.120}{100}=18\left(g\right)\Rightarrow n_{CH3COOH}=0,3\left(mol\right)\)
\(m_{NaOH}=\frac{20.100}{100}=20g\left(g\right)\)
\(\Rightarrow n_{NaOH}=0,5\left(mol\right)\)
Theo PT thì NaOH dư
\(n_{CH3COONa}=n_{CH3COOH}=0,3\left(mol\right)\)
\(\Rightarrow m_{CH3COONa}=24,6\left(g\right)\)
\(m_{dd\left(spu\right)}=120+100=220\left(g\right)\)
\(\Rightarrow C\%_{CH3COONa}=11,2\%\)
3.
\(n_{CaO}=\frac{14}{56}=0,25\left(mol\right)\)
\(m_{CH3COOH}=\frac{200.18}{100}=36\left(g\right)\)
\(\Rightarrow n_{CH3COOH}=\frac{36}{60}=0,6\left(mol\right)\)
\(PTHH:2CH_3COOH+CaO\rightarrow\left(CH_3COO\right)_2Ca+H_2O\)
Lập tỉ lệ: \(\frac{0,25}{1}< \frac{0,6}{2}\)
\(\Rightarrow\) CaO hết. CH3COOH dư
\(n_{CH3COOH_{dư}}=0,6-0,25.2=0,1\left(mol\right)\)
\(m_{dd\left(thu.duoc\right)}=14+200=214\left(g\right)\)
\(C\%_{\left(CH3COO\right)2Na}=\frac{0,25.158}{214}.100\%=18,46\%\)
\(C\%_{CH3COOH_{dư}}=\frac{0,1.60}{214}.100\%=2,8\%\)
4.
\(m_{Na2CO3}=\frac{42,4.10}{100}=4,24\left(g\right)\)
\(n_{Na2CO3}=\frac{4,24}{106}=0,04\left(mol\right)\)
\(n_{CO2}=\frac{0,448}{22,4}=0,02\left(mol\right)\)
\(PTHH:2CH_2COOH+Na_2CO_3\rightarrow2CH_3COONa+H_2O+CO_2\)
_______0,04 ___________ 0,02 ____________ 0,04 __________ 0,02
Sau phản ứng Na2CO3 dư.
\(n_{Na2CO3_{dư}}=0,04-0,02=0,02\left(mol\right)\)
\(m_{dd\left(CH3COOH\right)}=\frac{2,4.100}{5}.100\%=48\left(g\right)\)
\(m_{dd\left(Spu\right)}=m_{dd\left(Na2CO3\right)}+m_{dd_{Axit}}-m_{CO2}\)
\(=42,4+48-0,02.44=89,52\left(g\right)\)
\(m_{CH3COOH}=0,04.60=2,4\left(g\right)\)
\(C\%_{Na2CO3\left(dư\right)}=\frac{0,02.106}{89,52}.100\%=2,37\%\)
\(C\%_{CH3COONa}=\frac{0,04.82}{89,52}.100\%=3,66\%\)
PTHH: \(Na_2O\) + \(H_2O\) ----->2NAOH
a. \(m_{_{ }ddNaOH}\) = \(m_{H_2O}\) = 187,6g
ACDT: \(m_{ct}\) = \(\frac{m_{dd}.C\%}{100}\) => \(m_{NaOH}\) = \(\frac{187,6.8}{100}\) = 15,008g
b. PTHH: \(NaOH\) + \(HNO_3\) ----> \(NaNO_3\) + \(H_2O\)
ADCT: \(m_{ct}=\frac{m_{dd}.C\%}{100}\) ---> \(m_{HNO_3}\) = \(\frac{187,6.15}{100}\) = 28,14(g)
=> \(n_{HNO_3}\) = \(\frac{28,14}{63}\) = 0,4(mol)
Theo PT: \(n_{NANO_3}\) = \(n_{HNO_3}\) =0,4 (mol)
=> \(m_{NaNO_3}=\) 0,4 x 85 = 34(g)
\(C\%_{NaNO_3}\) = \(\frac{34}{187,6}\)x100% = 18,2%
(Ko bít mik làm có đúng ko nữa!!!! )
Câu a bổ sung bạn nhé!!!!!
\(n_{NaOH}=\frac{15,008}{40}=0,3752\left(mol\right)\)
Theo PT: \(n_{Na_2O}=2n_{NaOH}=2.0,3752=0,7504\left(mol\right)\)
ADCT: m = n.M => \(m_{Na_2O}\) = 0.7504.62 = 46.5248 (g)
CH3COOH + Mg ---> CH3COOMg + 1/2H2
(mol) 0,026 0,026 0,013
a) nCH3COOMg = 2,13 : 83 = 0,026 mol
=> C\(_M\)CH3COOH = 0,026 : 0,02 = 1,3 M
b) V\(_{H2}\)= 0,013 . 22,4 = 0,2912(lit)
c) CH3COOH + NaOH ----> CH3COONa + H2O
ai giải dùm em được hong :'( gấp quá