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a) \(n_{Fe}=\dfrac{3,36}{56}=0,06\left(mol\right)\)
PTHH: 3Fe + 2O2 --to--> Fe3O4
0,06->0,04------->0,02
=> mFe3O4 = 0,02.232 = 4,64 (g)
b) VO2 = 0,04.22,4 = 0,896 (l)
\(n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\)
PTHH: Fe2O3 + 3H2 --to--> 2Fe + 3H2O
0,1 0,3 0,2
\(V_{H_2}=0,3.22,4=6,72\left(l\right)\)
\(n_{O_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
PTHH: 3Fe + 2O2 --to--> Fe3O4
LTL: \(\dfrac{0,2}{3}>\dfrac{0,1}{2}\rightarrow\) Fe dư
Theo pthh: \(n_{Fe\left(pư\right)}=\dfrac{3}{2}n_{O_2}=\dfrac{3}{2}.0,1=0,15\left(mol\right)\)
\(\rightarrow m_{Fe\left(dư\right)}=\left(0,2-0,15\right).56=2,8\left(g\right)\)
a.\(n_{Fe_2O_3}=\dfrac{16}{160}=0,1mol\)
\(Fe_2O_3+3H_2\rightarrow\left(t^o\right)2Fe+3H_2O\)
0,1 0,3 0,2 ( mol )
\(V_{H_2}=0,3.22,4=6,72l\)
b.\(n_{O_2}=\dfrac{2,24}{22,4}=0,1mol\)
\(3Fe+2O_2\rightarrow\left(t^o\right)Fe_3O_4\)
\(\dfrac{0,2}{3}\) > \(\dfrac{0,1}{2}\) ( mol )
0,15 0,1 ( mol )
Chất dư là Fe
\(m_{Fe\left(dư\right)}=\left(0,2-0,15\right).56=2,8g\)
\(n_{Fe}=\dfrac{8,4}{56}=0,15\left(mol\right)\\ pthh:3Fe+2O_2\underrightarrow{t^o}Fe_3O_{\text{4}}\)
0,15 0,1 0,05
\(m_{Fe_2O_4}=0,05.232=11,6\left(g\right)\\
V_{O_2}=0,1.11,4=2,24\left(l\right)\\
pthh:2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\uparrow\)
0,2 0,1
\(m_{KMnO_4}=0,2.158=31,6\left(g\right)\)
\(n_{Fe}=\dfrac{8,4}{56}=0,15\left(mol\right)\\ pthh:3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
0,15 0,1 0,05
\(m_{Fe_3O_{\text{ 4}}}=0,05.232=11,6\left(g\right)\\ V_{O_2}=0,1.22,4=2,24\left(l\right)\\ pthh:2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
0,1 0,05
\(m_{KMnO_4}=0,1.158=15,8\left(g\right)\)
a) 3Fe + 2O2 Fe3O4
b) nFe = \(\dfrac{8,4}{56}\)= 0,15 mol
nFe3O4 = \(\dfrac{11,6}{232}\) = 0,05 mol
Ta thấy \(\dfrac{nFe}{3}\)= \(\dfrac{nFe_3O_4}{1}\)=> Fe phản ứng hết
<=> nO2 cần dùng = \(\dfrac{2nFe}{3}\)= 0,1 mol
<=> mO2 cần dùng = 0,1.32 = 3,2 gam
c) Oxi chiếm thể tích bằng 1/5 thể tích không khí.
Mà V O2 = 0,1.22,4 = 2,24 lít => V không khí = 2,24 . 5 = 11,2 lít
\(n_{Fe}=\dfrac{22,4}{56}=0,4\left(mol\right)\)
\(PTHH:3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\\ Mol:0,4\rightarrow\dfrac{4}{15}\rightarrow\dfrac{2}{15}\)
\(\rightarrow\left\{{}\begin{matrix}V_{O_2}=\dfrac{4}{15}.22,4=\dfrac{448}{75}\left(l\right)\rightarrow V_{kk}=\dfrac{448}{75}.5=\dfrac{448}{15}\left(l\right)\\m_{Fe_3O_4}=\dfrac{2}{15}.232=\dfrac{464}{15}\left(g\right)\end{matrix}\right.\)
2KClO3 --to--> 2KCl + 3O2
\(\dfrac{8}{45}\) \(\dfrac{4}{15}\)
\(m_{KClO_3}=\dfrac{8}{45}.122,5=\dfrac{196}{9}\left(g\right)\)
a, \(n_{Fe}=\dfrac{22,4}{56}=0,4\left(mol\right)\)
PTHH: 3Fe + 2O2 ---to---> Fe3O4
Mol: 0,4 \(\dfrac{0,8}{3}\) \(\dfrac{0,4}{3}\)
b, \(V_{O_2}=\dfrac{0,8}{3}.22,4=5,973\left(l\right)\)
c, \(V_{kk}=\dfrac{448}{75}.5=29,867\left(l\right)\)
d, \(m_{Fe_3O_4}=\dfrac{0,4}{3}.232=30,93\left(g\right)\)
e,
PTHH: 2KClO3 ---to---> 2KCl + 3O2
Mol: \(\dfrac{0,16}{9}\) \(\dfrac{0,8}{3}\)
\(m_{KClO_3}=\dfrac{0,16}{9}.122,5=2,178\left(g\right)\)
\(n_{Fe}=\dfrac{33,6}{56}=0,6mol\)
\(3Fe+2O_2\rightarrow\left(t^o\right)Fe_3O_4\)
0,6 0,4 0,2 ( mol )
\(V_{kk}=0,4.22,4.5=44,8l\)
\(m_{Fe_3O_4}=0,2.232=46,4g\)
a) nFe= 8,4/56 = 0,15(mol)
PTHH: 3 Fe + 2 O2 -to-> Fe3O4
0,15_______0,1_____0,05(mol)
b) mFe3O4= 232. 0,05= 11,6(g)