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a)\(n_{CuSO_4}=0,4.0,5=0,2\left(mol\right)\)
\(PTHH:CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)
Mol: 0,2 0,4 0,2
⇒ \(m_{Cu\left(OH\right)_2}=0,2.98=19,6\left(g\right)\)
b)\(C_{M\left(ddNaOH\right)}=\dfrac{0,4}{0,3}=1,3\left(M\right)\)
c)\(PTHH:Cu\left(OH\right)_2\underrightarrow{t^o}CuO+H_2O\)
Mol: 0,2 0,2
=> mCuO = 0,2.80 = 16 (g)
\(a,2NaOH+MgSO_4\rightarrow Mg\left(OH\right)_2+Na_2SO_4\\ n_{NaOH}=0,5.1=0,5\left(mol\right)\\ b,n_{Mg\left(OH\right)_2}=\dfrac{0,5}{2}=0,25\left(mol\right)=n_{Na_2SO_4}\\ m_{kt}=m_{Mg\left(OH\right)_2}=58.0,25=14,5\left(g\right)\\ c,V_{ddX}=V_{ddNaOH}+V_{ddMgSO_4}=0,5+0,5=1\left(l\right)\\ C_{MddNa_2SO_4}=\dfrac{0,25}{1}=0,25\left(M\right)\)
a)
$FeCl_3 + 3NaOH \to Fe(OH)_3 + 3NaCl$
$2Fe(OH)_3 \xrightarrow{t^o} Fe_2O_3 + 3H_2O$
$n_{FeCl_3} = 0,3.2 = 0,6(mol)$
Theo PTHH : $n_{Fe_2O_3} = \dfrac{1}{2}n_{FeCl_3} = 0,3(mol)$
$\Rightarrow m_{Fe_2O_3} = 0,3.160 = 48(gam)$
b) Sau phản ứng, $V_{dd} = 0,3 + 0,3 = 0,6(lít)$
$n_{NaCl} = 3n_{FeCl_3} = 1,8(mol) \Rightarrow C_{M_{NaCl}} = \dfrac{1,8}{0,6} = 3M$
\(n_{CuSO_4}=\dfrac{15,2}{160}=0,095mol\\ CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)
0,095 0,19 0,095 0,095
\(m_{rắn}=m_{Cu\left(OH\right)_2}=0,095.98=9,31g\\ V_{ddNaOH}=\dfrac{0,19}{2}=0,095l\\ b)C_{M_{Na_2SO_4}}=\dfrac{0,095}{0,04+0,095}\approx0,7M\\ c)Cu\left(OH\right)_2\xrightarrow[t^0]{}CuO+H_2O\)
0,095 0,095
\(m_{rắn}=m_{CuO}=0,095.80=7,6g\)
\(a,PTHH:3NaOH+FeCl_3\rightarrow3NaCl+Fe\left(OH\right)_3\downarrow\\ 2Fe\left(OH\right)_3\rightarrow^{t^o}Fe_2O_3+3H_2O\uparrow\\ b,n_{FeCl_3}=1,5\cdot0,2=0,3\left(mol\right)\\ \Rightarrow n_{NaOH}=3n_{FeCl_3}=0,9\left(mol\right)\\ \Rightarrow V_{dd_{NaOH}}=\dfrac{0,9}{2}=0,45\left(l\right)\)
Theo đề: \(\left\{{}\begin{matrix}X:Fe\left(OH\right)_3\\A:NaCl\\Y:Fe_2O_3\end{matrix}\right.\)
Theo PT: \(n_{NaCl}=3n_{FeCl_3}=0,9\left(mol\right)\)
\(\Rightarrow C_{M_{NaCl}}=\dfrac{0,9}{0,45+0,2}\approx1,4M\)
\(c,\) Theo PT: \(n_{Fe\left(OH\right)_3}=n_{FeCl_3}=0,3\left(mol\right);n_{Fe_2O_3}=\dfrac{1}{2}n_{Fe\left(OH\right)_3}=0,15\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}m_X=m_{Fe\left(OH\right)_3}=0,3\cdot107=32,1\left(g\right)\\m_Y=m_{Fe_2O_3}=0,15\cdot160=24\left(g\right)\end{matrix}\right.\)
(1)Fe + CuSO4 \(\rightarrow\) FeSO4 + Cu
(2)Fe + 2HCl \(\rightarrow\) FeCl2 + H2
(3)FeSO4 + 2NaOH \(\rightarrow\) Fe(OH)2 + Na2SO4
a) rắn A có Fe dư và Cu
Cho vào HCl dư rắn ko phản ứng là Cu
Theo (1) : nCu = n\(Cu SO_4\) = 1.0,01 = 0,01 (mol)
\(\rightarrow\) mCu = 0,01 . 64 =0,64 (g)
b) Dd B là FeSO4
Theo (1) : n\(Fe SO_4\) = n\(Cu SO_4\) = 0,01 (mol)
Theo (3) nNaOH = 2n\(Fe SO_4\) = 2.0,01 = 0,02 (mol)
VNaOH = 0,02 : 1 = 0,02 (l)
Ciao_
\(n_{AlCl_3}=0.2\cdot1=0.2\left(mol\right)\)
\(n_{NaOH}=0.5V\left(mol\right)\)
\(n_{Al_2O_3}=\dfrac{5.1}{102}=0.05\left(mol\right)\)
\(2Al\left(OH\right)_3\underrightarrow{^{^{t^0}}}Al_2O_3+3H_2O\)
\(0.1...............0.05\)
TH1 : Al(OH)3 không bị hòa tan.
\(AlCl_3+3NaOH\rightarrow Al\left(OH\right)_3+3NaCl\)
\(0.1...........0.3................0.1\)
\(\Leftrightarrow V=\dfrac{0.3}{0.5}=0.6\left(l\right)\)
TH2 : Al(OH)3 bị hòa tan một phần
\(AlCl_3+3NaOH\rightarrow Al\left(OH\right)_3+3NaCl\)
\(0.2...........0.6................0.2\)
\(NaOH+Al\left(OH\right)_3\rightarrow NaAlO_2+2H_2O\)
\(0.5V-0.6...0.5V-0.6\)
\(n_{Al\left(OH\right)_3}=0.2+0.5V-0.6=0.1\left(mol\right)\)
\(\Rightarrow V=1\left(l\right)\)
\(n_{FeCl_3}=0,5.1=0,5mol\)
FeCl3+3NaOH\(\rightarrow\)Fe(OH)3+3NaCl
2Fe(OH)3\(\overset{t^0}{\rightarrow}\)Fe2O3+3H2O
\(n_{NaOH}=3n_{FeCl_3}=1,5mol\)
\(V_{NaOH}=\dfrac{n}{C_M}=\dfrac{1,5}{0,5}=3l\)
\(C_{M_{NaCl}}=\dfrac{n}{v}=\dfrac{1,5}{0,05+3}=0,225M\)
\(n_{Fe_2O_3}=\dfrac{1}{2}n_{Fe\left(OH\right)_3}=\dfrac{1}{2}n_{FeCl_3}=0,25mol\)
M=\(m_{Fe_2O_3}=0,25.160=40g\)