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`#3107.101107`
1.
a.
Ta có:
\(\text{n}_{\text{KClO}_3}=\dfrac{\text{m}_{\text{KClO}_3}}{\text{M}_{\text{KClO}_3}}=\dfrac{122,5}{122,5}=1\text{ (mol)}\)
PTPỨ: \(\text{2KClO}_3\text{ }\)\(\underrightarrow{\text{ }t^0}\) \(\text{2KCl}+3\text{O}_2\)
Ta có: `2` mol \(\text{KClO}_3\) thu được `3` mol \(\text{O}_2\)
`=>` `1` mol \(\text{KClO}_3\) thu được `1,5` mol \(\text{O}_2\)
b.
\(\text{V}_{\text{O}_2}=\text{n}_{\text{O}_2}\cdot24,79=1,5\cdot24,79=37,185\left(l\right)\)
TTĐ:
\(m_{KClO_3}=122,5\left(g\right)\)
______________
a) PTHH?
b) \(V_{O_2}=?\left(l\right)\)
Giải
\(n_{KClO_3}=\dfrac{m}{M}=\dfrac{122,5}{122,5}=1\left(mol\right)\)
\(2KClO_3\underrightarrow{t^o}2KCl+3O_2\uparrow\)
1-> 1 : 1,5(mol)
\(V_{O_2}=n.22,4=1,5.22,4=33,6\left(l\right)\)
a) $2Al + 3Cl_2 \xrightarrow{t^o} 2AlCl_3$
b) $n_{Al} = \dfrac{5,4}{27} = 0,2(mol)$
Theo PTHH : $n_{Cl_2} = \dfrac{3}{2}n_{Al} = 0,3(mol)$
$\Rightarrow V_{Cl_2} = 0,3.24,79 = 7,437(lít)$
c) $n_{AlCl_3} = n_{Al} = 0,2(mol)$
$\Rightarrow m_{AlCl_3} = 0,2.133,5 = 26,7(gam)$
\(Câu.2:\\ 2KClO_3\rightarrow\left(t^o\right)2KCl+3O_2\\ n_{KClO_3}=\dfrac{14,7}{122,5}=0,12\left(mol\right)\\ n_{KCl}=n_{KClO_3}=0,12\left(mol\right);n_{O_2}=\dfrac{3}{2}.0,12=0,18\left(mol\right)\\ V_{O_2\left(đkc\right)}=0,18.24,79=4,4622\left(l\right)\\ m_{KCl}=74,5.0,12=8,94\left(g\right)\)
Câu 3:
\(n_{Al}=\dfrac{8,1}{27}=0,3\left(mol\right)\\ PTHH:2Al+6HCl\rightarrow2AlCl_3+3H_2\\ n_{H_2}=\dfrac{3}{2}.n_{Al}=\dfrac{3}{2}.0,3=0,45\left(mol\right)\\ 1,V_{H_2\left(đkc\right)}=24,79.0,45=11,1555\left(l\right)\\ 2,n_{HCl}=\dfrac{6}{2}.0,3=0,9\left(mol\right)\\ V_{ddHCl}=\dfrac{0,9}{1,5}=0,6\left(l\right)\\ 3,n_{AlCl_3}=n_{Al}=0,3\left(mol\right)\\ V_{ddsau}=V_{ddHCl}=0,6\left(l\right)\\ C_{MddAlCl_3}=\dfrac{0,3}{0,6}=0,5\left(M\right)\)
a, PT: \(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
Ta có: \(n_{KMnO_4}=\dfrac{31,6}{158}=0,2\left(mol\right)\)
Theo PT: \(n_{K_2MnO_4}=\dfrac{1}{2}n_{KMnO_4}=0,1\left(mol\right)\)
\(\Rightarrow m_{K_2MnO_4}=0,1.197=19,7\left(g\right)\)
b, Theo PT: \(n_{O_2}=\dfrac{1}{2}n_{KMnO_4}=0,1\left(mol\right)\)
\(\Rightarrow V_{O_2}=0,1.24,79=2,479\left(l\right)\)
c, PT: \(CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\)
Theo PT: \(\left\{{}\begin{matrix}n_{CO_2}=\dfrac{1}{2}n_{O_2}=0,05\left(mol\right)\\n_{H_2O}=n_{O_2}=0,1\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow V_{CO_2}=0,05.24,79=1,2395\left(l\right)\)
\(m_{H_2O}=0,1.18=1,8\left(g\right)\)
\(n_{KClO_3}=\dfrac{12,25}{122,5}=0,1\left(mol\right)\)
PTHH: 2KClO3 -to, MnO2-> 2KCl + 3O2
0,1--------------------->0,1--->0,15
=> \(\left\{{}\begin{matrix}V_{O_2}=0,15.24,79=3,7185\left(l\right)\\m_{KCl}=0,1.74,5=7,45\left(g\right)\end{matrix}\right.\)
\(n_P=\dfrac{3,1}{31}=0,1\left(mol\right)\)
PTHH: 4P + 5O2 --to--> 2P2O5
LTL: \(\dfrac{0,1}{4}< \dfrac{0,15}{5}\) => P có cháy hết
nFe = 16,8/56 = 0,3 (mol)
PTHH: 3Fe + 2O2 -> (t°) Fe3O4
Mol: 0,3 ---> 0,2
VO2 = 0,2 . 22,4 = 4,48 (l)
PTHH: 4P + 5O2 -> (t°) 2P2O5
Mol: 0,16 <--- 0,2
mP = 0,16 . 31 = 4,96 (g)
`2KClO_3->2KCl+3O_2`(to)
0,04-----------0,02-----0,06
`n_(KClO_3)=(4,9)/(122,5)=0,04mol`
=>`V_(O_2)=0,06.24,79=1,4847l`
c)
`4P+5O_2->2P_2O_5`(to)
0,048----0,06 mol
`=>m_P=0,048.31=1,488g`
Tớ làm xong rồi nhưng hình như cậu bị sai ấy nhỉ? Cậu chưa cần bằng KCl kìa.