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a, \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
b, \(n_{Al}=\dfrac{8,1}{27}=0,3\left(mol\right)\)
Theo PT: \(n_{H_2}=\dfrac{3}{2}n_{Al}=0,45\left(mol\right)\Rightarrow V_{H_2}=0,45.22,4=10,08\left(l\right)\)
c, Ta có: m dd sau pư = 8,1 + 200 - 0,45.2 = 207,2 (g)
Theo PT: \(n_{AlCl_3}=n_{Al}=0,3\left(mol\right)\)
\(\Rightarrow C\%_{AlCl_3}=\dfrac{0,3.133,5}{207,2}.100\%\approx19,33\%\)
\(n_{Fe}=\dfrac{8,4}{56}=0,15mol\)
a)\(Fe+2HCl\rightarrow FeCl_2+H_2\)
0,15 0,3 0,15 0,15
\(V_{H_2}=0,15\cdot22,4=3,36l\)
b)\(m_{H_2}=0,15\cdot2=0,3g\)
\(BTKL:m_{ddFeCl_2}=8,4+100-0,3=108,1g\)
\(m_{ctFeCl_2}=0,15\cdot127=19,05g\)
\(C\%=\dfrac{m_{ctFeCl_2}}{m_{ddFeCl_2}}\cdot100\%=\dfrac{19,05}{108,1}\cdot100\%=17,62\%\)
a) \(n_{Al}=\dfrac{10,8}{27}=0,4\left(mol\right)\)
PTHH: 2Al + 3H2SO4 --> Al2(SO4)3 + 3H2
0,4-->0,6---------->0,2------->0,6
=> \(C_{M\left(dd.H_2SO_4\right)}=\dfrac{0,6}{0,15}=4M\)
b) VH2 = 0,6.22,4 = 13,44 (l)
c) \(C_{M\left(Al_2\left(SO_4\right)_3\right)}=\dfrac{0,2}{0,15}=\dfrac{4}{3}M\)
\(n_{Al}=\dfrac{10,8}{27}=0,4\left(mol\right)\\
pthh:2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
0,4 0,6 0,2 0,6
\(C_M_{H_2SO_4}=\dfrac{0,6}{0,15}=4M\\ V_{H_2}=0,622,4=13,44L\)
\(C_M=\dfrac{0,2}{0,15}=1,3M\)
a) \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\); \(n_{HCl}=\dfrac{200.14,6\%}{36,5}=0,8\left(mol\right)\)
PTHH: 2Al + 6HCl --> 2AlCl3 + 3H2
Xét tỉ lệ: \(\dfrac{0,2}{2}< \dfrac{0,8}{6}\) => Al hết, HCl dư
PTHH: 2Al + 6HCl --> 2AlCl3 + 3H2
0,2-->0,6---->0,2----->0,3
=> VH2 = 0,3.22,4 = 6,72 (l)
b) \(\left\{{}\begin{matrix}m_{AlCl_3}=0,2.133,5=26,7\left(g\right)\\m_{HCl\left(dư\right)}=\left(0,8-0,6\right).36,5=7,3\left(g\right)\end{matrix}\right.\)
=> mchất tan = 26,7 + 7,3 = 34 (g)
c) mdd sau pư = 5,4 + 200 - 0,3.2 = 204,8 (g)
\(\left\{{}\begin{matrix}C\%_{AlCl_3}=\dfrac{26,7}{204,8}.100\%=13,04\%\\C\%_{HCl\left(dư\right)}=\dfrac{7,3}{204,8}.100\%=3,56\%\end{matrix}\right.\)
\(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\\ pthh:2Al+6HCl\rightarrow2AlCl_3+3H_2\)
0,2 0,2 0,3
\(V_{H_2}=0,3.22,4=6,72L\\ m_{AlCl_3}=133,5.0,2=26,7g\\ m_{\text{dd}}=5,4+200-\left(0,3.2\right)=204,8g\\ C\%=\dfrac{26,7}{204,8}.100\%=13\%\)
\(n_{Zn}=\dfrac{13}{65}=0,2mol\)
\(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)
0,2 0,2 0,2 0,2
a)\(V_{H_2}=0,2\cdot22,4=4,48l\)
b)\(m_{ZnSO_4}=0,2\cdot161=32,2g\)
\(m_{ddZnSO_4}=30+200-0,2\cdot2=229,6g\)
\(C\%=\dfrac{m_{ct}}{m_{dd}}\cdot100\%=\dfrac{32,2}{229,6}\cdot100\%=14,02\%\)
c)\(n_{CuO}=\dfrac{24}{80}=0,3mol\)
\(CuO+H_2\rightarrow Cu+H_2O\)
0,3 0,2 0,2
\(m_{rắn}=m_{Cu}=0,2\cdot64=12,8g\)
nZn=1365=0,2molnZn=1365=0,2mol
Zn+H2SO4→ZnSO4+H2Zn+H2SO4→ZnSO4+H2
0,2 0,2 0,2 0,2
a)VH2=0,2⋅22,4=4,48lVH2=0,2⋅22,4=4,48l
b)mH2SO4=0,2⋅98=19,6gmH2SO4=0,2⋅98=19,6g
C%=mctmdd⋅100%=19,6200⋅100%=9,8%C%=mctmdd⋅100%=19,6200⋅100%=9,8%
c)nCuO=2480=0,3molnCuO=2480=0,3mol
CuO+H2→Cu+H2OCuO+H2→Cu+H2O
0,3 0,2 0,2
mrắn=mCu=0,2⋅64=12,8g.
a) Pt: \(Fe+2HCl\rightarrow FeCl_2+H_2\)
b) nFe = \(\dfrac{11,2}{56}=0,2mol\)
Theo pt: nH2 = nFe = 0,2 mol
=> VH2 = 0,2.22,4 = 4,48lit
c) Theo pt: nHCl = 2nFe = 0,4 mol
=> mHCl = 0,4.36,5 = 14,6 g
=> C% = \(\dfrac{14,6}{73}.100\%=20\%\)
a) Pt:
b) nFe = \(\dfrac{11,2}{56}=0,2mol\)
Theo pt: nH2 = nFe = 0,2 mol
=> VH2 = 0,2.22,4 = 4,48lit
c) Theo pt: nHCl = 2nFe = 0,4 mol
=> mHCl = 0,4.36,5 = 14,6 g
=> \(C\%=\dfrac{14,6}{73}.100\%=20\%\)
nAl= 0,04(mol)
PTHH: 2 Al + 3 H2SO4 -> Al2(SO4)3 + 3 H2
0,04___________0,06___0,02_____0,06(mol)
a) V(H2, đktc)=0,06.22,4=1,344(l)
b) VddH2SO4= 0,06/2=0,03(l)=30(ml)
c) VddAl2(SO4)3=VddH2SO4=0,03(l)
=>CMddAl2(SO4)3=0,02/0,03=2/3(M)
\(n_{Al}=\dfrac{1.08}{27}=0.04\left(mol\right)\)
\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
\(0.04......0.06.............0.02...........0.06\)
\(V_{H_2}=0.06\cdot22.4=1.344\left(l\right)\)
\(V_{dd_{H_2SO_4}}=\dfrac{0.06}{2}=0.03\left(l\right)\)
\(C_{M_{Al_2\left(SO_4\right)_3}}=\dfrac{0.02}{0.03}=\dfrac{2}{3}\left(M\right)\)
a)
2K + 2H2O --> 2KOH + H2
dd A là dd bazo nên quỳ tím đổi màu xanh
b)
\(n_K=\dfrac{3,9}{39}=0,1\left(mol\right)\)
PTHH: 2K + 2H2O --> 2KOH + H2
0,1----------->0,1---->0,05
=> VH2 = 0,05.22,4 = 1,12 (l)
c) mdd = 3,9 + 36,2 - 0,05.2 = 40 (g)
=> \(C\%=\dfrac{0,1.56}{40}.100\%=14\%\)
\(n_K=\dfrac{3,9}{39}=0,1\left(mol\right)\\
n_{H_2O}=\dfrac{36,2}{18}=2\left(mol\right)\\
pthh:2K+2H_2O\rightarrow2KOH+H_2\\
ltl:\dfrac{0,1}{2}< \dfrac{2}{2}\)
=> nước dư
a) dd A là bazo => làm QT chuyển xanh
\(2K+2H_2O\rightarrow2KOH+H_2\)
0,1 0,1
\(V_{H_2}=0,1.22,4=2,24L\)
PTHH: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\)
Ta có: \(n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\)
\(\Rightarrow n_{H_2SO_4}=0,15\left(mol\right)=n_{H_2}\) \(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,15\cdot22,4=3,36\left(l\right)\\C\%_{H_2SO_4}=\dfrac{0,15\cdot98}{100}\cdot100\%=14,7\%\end{matrix}\right.\)
\(a,n_{Al}=\dfrac{m}{M}=\dfrac{2,7}{27}=0,1\left(mol\right)\\ PTHH:2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\\ \left(mol\right)....0,1\rightarrow..0,15...........0,05..........0,15\\ b,V_{H_2}=n.22,4=0,15.22,4=3,36\left(l\right)\\ c,m_{ctH_2SO_4}=n.M=0,15.98=14,7\left(g\right)\\ C\%=\dfrac{m_{ct}}{m_{dd}}.100\%=\dfrac{14,7}{100}.100\%=14,7\%\)