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\(n_{K_2CO_3}=\dfrac{4.14}{138}=0.03\left(mol\right)\)
\(n_{HCl}=0.2\cdot0.35=0.07\left(mol\right)\)
\(K_2CO_3+2HCl\rightarrow2KCl+CO_2+H_2O\)
\(0.03..........0.06.........0.06.......0.03\)
\(V_{CO_2}=0.03\cdot22.4=0.672\left(l\right)\)
\(n_{HCl\left(dư\right)}=0.07-0.06=0.01\left(mol\right)\)
\(C_{M_{HCl\left(dư\right)}}=\dfrac{0.01}{0.2}=0.05\left(M\right)\)
\(C_{M_{KCl}}=\dfrac{0.06}{0.2}=0.3\left(M\right)\)
a, PT: \(Fe+S\underrightarrow{t^o}FeS\)
Ta có: \(n_{Fe}=\dfrac{16,8}{56}=0,3\left(mol\right)\)
\(n_S=\dfrac{3,2}{32}=0,1\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{0,3}{1}>\dfrac{0,1}{1}\), ta được Fe dư.
Chất rắn A gồm Fe dư và FeS.
Theo PT: \(n_{Fe\left(pư\right)}=n_{FeS}=n_S=0,1\left(mol\right)\)
\(\Rightarrow n_{Fe\left(dư\right)}=0,2\left(mol\right)\)
PT: \(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(FeS+2HCl\rightarrow FeCl_2+H_2S\)
Theo PT: \(\left\{{}\begin{matrix}n_{H_2}=n_{Fe\left(dư\right)}=0,2\left(mol\right)\\n_{H_2S}=n_{FeS}=0,1\left(mol\right)\end{matrix}\right.\)
Ở cùng điều kiện nhiệt độ và áp suất, %V cũng là % số mol.
\(\Rightarrow\left\{{}\begin{matrix}\%V_{H_2}=\dfrac{0,2}{0,2+0,1}.100\%\approx66,67\%\\\%V_{H_2S}\approx33,33\%\end{matrix}\right.\)
b, Ta có: \(\Sigma n_{HCl\left(dadung\right)}=2n_{Fe}+2n_{FeS}=0,6\left(mol\right)\) (1)
PT: \(NaOH+HCl\rightarrow NaCl+H_2O\)
Ta có: \(n_{NaOH}=0,1.2=0,2\left(mol\right)\)
\(\Rightarrow n_{HCl\left(dư\right)}=n_{NaOH}=0,2\left(mol\right)\) (2)
Từ (1) và (2) \(\Rightarrow\Sigma n_{HCl}=0,8\left(mol\right)\)
\(\Rightarrow C_{M_{ddHCl}}=\dfrac{0,8}{0,5}=1,6\left(M\right)\)
Bạn tham khảo nhé!
\(n_{MnO_2}=\dfrac{69,6}{87}=0,8\left(mol\right)\)
nKOH = 0,5.4 = 2(mol)
PTHH: MnO2 + 4HCl --> MnCl2 + Cl2 + 2H2O
0,8------------------------>0,8
2KOH + Cl2 --> KCl + KClO + H2O
Xét tỉ lệ \(\dfrac{2}{2}>\dfrac{0,8}{1}\) => KOH dư, Cl2 hết
2KOH + Cl2 --> KCl + KClO + H2O
1,6<--0,8---->0,8---->0,8
=> \(\left\{{}\begin{matrix}n_{KOH\left(dư\right)}=2-1,6=0,4\left(mol\right)\\n_{KCl}=0,8\left(mol\right)\\n_{KClO}=0,8\left(mol\right)\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}C_{M\left(KOH\right)}=\dfrac{0,4}{0,5}=0,8M\\C_{M\left(KCl\right)}=\dfrac{0,8}{0,5}=1,6M\\C_{M\left(KClO\right)}=\dfrac{0,8}{0,5}=1,6M\end{matrix}\right.\)
\(a) n_{Fe_2O_3} = \dfrac{8}{160} = 0,05(mol)\\ Fe_2O_3 + 6HCl \to 2FeCl_3 + 3H_2O\\ n_{FeCl_3} = 2n_{Fe_2O_3} = 0,1(mol)\\ m_{FeCl_3} = 0,1.162,5 = 16,25(gam)\\ b) n_{HCl} = 6n_{Fe_2O_3} = 0,05.6 = 0,3(mol)\\ V_{dd\ HCl} = \dfrac{0,3}{0,5} = 0,6(lít)\\ c) C_{M_{FeCl_3}} = \dfrac{0,1}{0,5} = 0,2M\)
a, \(Fe+2HCl\rightarrow FeCl_2+H_2\)
Ta có: \(n_{Fe}=\dfrac{14}{56}=0,25\left(mol\right)\)
Theo PT: \(\left\{{}\begin{matrix}n_{HCl}=2n_{Fe}=0,5\left(mol\right)\\n_{H_2}=n_{Fe}=0,25\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow V_{H_2}=0,25.24,79=6,1975\left(l\right)\)
\(a=C_{M_{HCl}}=\dfrac{0,5}{0,1}=5\left(M\right)\)
b, Theo PT: \(n_{FeCl_2}=n_{Fe}=0,25\left(mol\right)\)
Ta có: \(n_{AgNO_3}=0,4.1,3=0,52\left(mol\right)\)
PT: \(2AgNO_3+FeCl_2\rightarrow Fe\left(NO_3\right)_2+2AgCl_{\downarrow}\)
______0,5______0,25______0,25________0,5 (mol)
\(AgNO_3+Fe\left(NO_3\right)_2\rightarrow Fe\left(NO_3\right)_3+Ag_{\downarrow}\)
0,02______0,02________0,02________0,02 (mol)
⇒ m = mAgCl + mAg = 0,5.143,5 + 0,02.108 = 73,91 (g)
- Dd sau pư gồm: Fe(NO3)3: 0,02 (mol) và Fe(NO3)2: 0,25 - 0,02 = 0,23 (mol)
\(\Rightarrow\left\{{}\begin{matrix}C_{M_{Fe\left(NO_3\right)_3}}=\dfrac{0,02}{0,1+0,4}=0,04\left(M\right)\\C_{M_{Fe\left(NO_3\right)_2}}=\dfrac{0,23}{0,1+0,4}=0,46\left(M\right)\end{matrix}\right.\)
\(Fe+2HCl->FeCl_2+H_2\\ a.V=\dfrac{14}{56}\cdot22,4=5,6\left(L\right)\\ a=\dfrac{\dfrac{14}{56}\cdot2}{0,1}=5\left(M\right)\\ b.n_{AgNO_3}=0,4\cdot1,3=0,52mol\\ FeCl_2+AgNO_3->Fe\left(NO_3\right)_2+AgCl\\ Fe\left(NO_3\right)_2+AgNO_3->Ag+Fe\left(NO_3\right)_3\\ m=0,25\cdot143,5+0,25\cdot108=62,875\left(g\right)\\ C_{M\left(AgNO_3\right)}=\dfrac{0,02}{0,5}=0,04M\\ C_{M\left(Fe\left(NO_3\right)_3\right)}=\dfrac{0,25}{0,5}=0,5M\)
`1)`
`n_{Al}={2,7}/{27}=0,1(mol)`
`2Al+3H_2SO_4->Al_2(SO_4)_3+3H_2`
`0,1->0,15->0,05->0,15(mol)`
`V_{dd\ H_2SO_4}={0,15}/1=0,15(l)=150(ml)`
`->V=150`
`V'=V_{H_2}=0,15.22,4=3,36(l)`
`C_{M\ X}=C_{M\ Al_2(SO_4)_3}={0,05}/{0,15}=1/3M`
`2)`
`n_{Fe}={2,8}/{56}=0,05(mol)`
`Fe+2HCl->FeCl_2+H_2`
`0,05->0,1->0,05->0,05(mol)`
`V_{dd\ HCl}={0,1}/1=0,1(l)=100(ml)`
`->V=100`
`V_{H_2}=0,05.22,4=1,12(l)`
`C_{M\ FeCl_2}={0,05}/{0,1}=0,5M`
\(a) n_{Na_2CO_3} = \dfrac{2,12}{106} = 0,02(mol) ; n_{HCl} = 0,5.0,1 = 0,05(mol)\\ Na_2CO_3 + 2HCl \to 2NaCl + CO_2 + H_2O\\ Vì :2n_{Na_2CO_3} = 0,04 < n_{HCl} = 0,05\ nên\ HCl\ \text{dư}\\ n_{CO_2} = n_{Na_2CO_3} = 0,02(mol)\\ V_{CO_2} = 0,02.22,4 = 0,448(lít)\\ b) n_{HCl\ dư} = n_{HCl\ ban\ đầu} - 2n_{Na_2CO_3} = 0,05 -0,02.2 = 0,01(mol)\\ n_{NaCl} = 2n_{Na_2CO_3} = 0,02.2 = 0,04(mol)\\ C_{M_{HCl}} = \dfrac{0,01}{0,5} = 0,02M\\ C_{M_{NaCl}} = \dfrac{0,04}{0,5} = 0,08M\)