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$a) 2Na + 2H_2O \to 2NaOH + H_2$
$b) $n_{H_2} = \dfrac{6,72}{22,4} = 0,3(mol)$
Theo PTHH : $n_{NaOH} = 2n_{H_2} = 0,6(mol)$
$C_{M_{NaOH}} = \dfrac{0,6}{0,3} = 2M$
c) $m_{NaOH} = 0,6.40 = 24(gam)$
Cách pha chế :
- Cân lấy 24 gam NaOH khan, nghiền nhỏ cho vào cốc có dung tích 500 ml có chia vạch
- Thêm từ từ nước vào cốc cho đến khi chạm vạch 300ml thì dừng, khuấy đều
a) \(n_{Na}=\dfrac{4,6}{23}=0,2\left(mol\right)\)
PTHH: 2Na + 2H2O ---> 2NaOH + H2 => ddA là NaOH
0,2----------------->0,2------>0,1
b) \(V_{H_2}=0,1.22,4=2,24\left(l\right)\)
c) \(C_{M\left(NaOH\right)}=\dfrac{0,2}{0,4}=0,5M\)
\(n_{NaOH}=0.2\cdot0.5=0.1\left(mol\right)\)
\(n_{CuSO_4}=0.1\cdot2=0.2\left(mol\right)\)
\(2NaOH+CuSO_4\rightarrow Na_2SO_4+Cu\left(OH\right)_2\)
\(0.1.............0.05...............0.05...........0.05\)
\(m_{Cu\left(OH\right)_2}=0.05\cdot98=4.9\left(g\right)\)
\(C_{M_{Na_2SO_4}}=\dfrac{0.05}{0.2+0.1}=0.167\left(M\right)\)
\(C_{M_{CuSO_4\left(dư\right)}}=\dfrac{0.2-0.05}{0.1}=1.5\left(M\right)\)
2NaOH + CuSO4 → Cu(OH)2 + Na2SO4
n NaOH = 0,2.5 = 1(mol)
n CuSO4 = 0,1.2 = 0,2(mol)
Ta có :
n NaOH / 2 = 0,5 > n CuSO4 / 1 = 0,2 => NaOH dư
n Cu(OH)2 = n CuSO4 = 0,2 mol
=> m A = 0,2.98 = 19,6 gam
n Na2SO4 = n CuSO4 = 0,2 mol
n NaOH pư = 2n CuSO4 = 0,4(mol)
V dd = 0,2 + 0,1 = 0,3(lít)
Suy ra:
CM Na2SO4 = 0,2/0,3 = 0,67M
CM NaOH = (1 - 0,4)/0,3 = 2M
\(a,C_{M\left(NaOH\right)}=\dfrac{0,3}{0,5}=0,6M\\ b,n_{NaOH}=\dfrac{24}{40}=0,6\left(mol\right)\\ C_{M\left(NaOH\right)}=\dfrac{0,6}{0,4}=1,5M\)
\(Na+H_2O->NaOH+\dfrac{1}{2}H_2\\ a.n_{Na}=\dfrac{m_1}{23}\left(mol\right)\\ m_{ddsau}=\dfrac{m_1}{23}+m_2-\dfrac{m_1}{46}=\dfrac{m_1}{46}+m_2\left(g\right)\\ C\%_B=\dfrac{\dfrac{40}{23}m_1}{\dfrac{m_1}{46}+m_2}\cdot100\%.\\ b.C_M=\dfrac{10dC\%}{M}=10\cdot1,2\cdot\dfrac{0,05}{40}=0,015\left(M\right)\)
\(Na+H_2O->NaOH+\dfrac{1}{2}H_2\\ a.n_{Na}=\dfrac{m_1}{23}\left(mol\right)\\ m_{ddsau}=m_1+m_2-\dfrac{m_1}{23}=\dfrac{22}{23}m_1+m_2\left(g\right)\\ C\%_B=\dfrac{\dfrac{40}{23}m_1}{\dfrac{22}{23}m_1+m_2}\cdot100\%.\\ b.C_M=\dfrac{10dC\%}{M}=10\cdot1,2\cdot\dfrac{0,05}{40}=0,015\left(M\right)\)
a, \(n_{NaOH}=0,2.1=0,2\left(mol\right)\)
\(m_{NaOH}=0,2.40=8\left(g\right)\)
b, \(n_{H_2SO_4}=2.0,1=0,2\left(mol\right)\)
\(c,C\%=\dfrac{6}{200}.100\%=3\%\)
\(m_{NaCl}=\dfrac{200.8}{100}=16\left(g\right)\)
a.\(n_{NaOH}=\dfrac{8}{40}=0,2mol\)
\(V_{dd}=\dfrac{120}{1,2}=100ml=0,1l\)
\(C_{M_{NaOH}}=\dfrac{0,2}{0,1}=2M\)
b.\(n_{NaOH}=\dfrac{21,6}{40}=0,54mol\)
\(V_{dd}=\dfrac{180}{1,2}=150ml=0,15l\)
\(C_{M_{NaOH}}=\dfrac{0,54}{0,15}=3,6M\)
a, \(2Na+2H_2O\rightarrow2NaOH+H_2\)
b, \(n_{Na}=\dfrac{4,6}{23}=0,2\left(mol\right)\)
Theo PT: \(n_{NaOH}=n_{Na}=0,2\left(mol\right)\Rightarrow m_{NaOH}=0,2.40=8\left(g\right)\)
c, \(C_{M_{NaOH}}=\dfrac{0,2}{0,2}=1\left(M\right)\)