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Câu 1.
\(CH_3COOH+NaOH\rightarrow CH_4\uparrow+Na_2CO_3\)
\(2CH_4\xrightarrow[LLN]{1500^oC}C_2H_2+2H_2\uparrow\)
\(C_2H_2+H_2\underrightarrow{t^o,xtPd}C_2H_4\)
a)\(C_2H_4+HBr\rightarrow C_2H_5Br\)
b)\(C_2H_4+HCl\underrightarrow{as}C_2H_5Cl\)
Bài 4:
\(n_{Ba\left(OH\right)_2}=1.0,1=0,1\left(mol\right)\\ n_{HCl}=1.0,1=0,1\left(mol\right)\\ Ba\left(OH\right)_2+2HCl\rightarrow BaCl_2+2H_2O\\ Vì:\dfrac{0,1}{2}< \dfrac{0,1}{1}\Rightarrow Ba\left(OH\right)_2dư\\ n_{BaCl_2}=n_{Ba\left(OH\right)_2\left(p.ứ\right)}=\dfrac{0,1}{2}=0,05\left(mol\right)\\ n_{Ba\left(OH\right)_2\left(dư\right)}=0,1-0,05=0,05\left(mol\right)\\ \left[OH^-\left(dư\right)\right]=\left[Ba\left(OH\right)_2\left(dư\right)\right]=\dfrac{0,05}{0,1+0,1}=0,25\left(M\right)\\ \left[Cl^-\right]=2.\left[BaCl_2\right]=2.\dfrac{0,05}{0,1+0,2}=0,5\left(M\right)\\ \left[Ba^{2+}\right]=\dfrac{0,25+0,5}{2}=0,375\left(M\right)\)
Câu 3:
\(n_{CO_2}=\dfrac{0,44}{44}=0,01\left(mol\right)\)
\(n_{H_2O}=\dfrac{0,18}{18}=0,01\left(mol\right)\)
Bảo toàn C: nC(A) = 0,01 (mol)
Bảo toàn H: nC(A) = 2.0,01 = 0,02 (mol)
=> \(n_O=\dfrac{0,3-0,01.12-0,02.1}{16}=0,01\left(mol\right)\)
nC : nH : nO = 0,01 : 0,02 : 0,01 = 1:2:1
=> CTHH: (CH2O)n
Có\(n_{O_2}=\dfrac{0,32}{32}=0,01\left(mol\right)=>M_A=\dfrac{0,3}{0,01}=30\left(g/mol\right)\)
=> n = 1
=> CTHH: CH2O
Câu 4:
\(n_{NO_2}=\dfrac{5,152}{22,4}=0,23\left(mol\right)\)
PTHH: Cu + 4HNO3 --> Cu(NO3)2 + 2NO2 + 2H2O
_____a---------------------------------->2a
Fe + 6HNO3 --> Fe(NO3)3 + 3NO2 + 3H2O
b---------------------------------->3b
=> \(\left\{{}\begin{matrix}64a+56b=5,36\\2a+3b=0,23\end{matrix}\right.=>\left\{{}\begin{matrix}a=0,04\\b=0,05\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}\%Cu=\dfrac{0,04.64}{5,36}.100\%=47,76\%\\\%Fe=\dfrac{0,05.56}{5,36}.100\%=52,24\%\end{matrix}\right.\)