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\(n_{O_2}=\dfrac{0.896}{22.4}=0.04\left(mol\right)\)
\(3Fe+2O_2\underrightarrow{^{^{t^0}}}Fe_3O_4\)
\(0.06......0.04.......0.02\)
\(m_{Fe}=0.06\cdot56=3.36\left(g\right)\)
\(m_{Fe_2O_3}=0.02\cdot232=4.64\left(g\right)\)
Bài 3 :
PTHH : \(6Fe+4O_2\left(t^o\right)->2Fe_3O_4\) (1)
\(n_{Fe_3O_4}=\dfrac{m}{M}=\dfrac{2,32}{56.3+16.4}=0,01\left(mol\right)\)
Từ (1) => \(3n_{Fe_3O_4}=n_{Fe}=0,03\left(mol\right)\)
=> \(m_{Fe}=n.M=1,68\left(g\right)\)
Từ (1) => \(2n_{Fe_3O_4}=n_{O_2}=0,02\left(mol\right)\)
=> \(V_{O_2\left(đktc\right)}=n.22,4=0,448\left(l\right)\)
Bài 4 :
PTHH : \(4P+5O_2\left(t^o\right)->2P_2O_5\) (1)
\(n_P=\dfrac{m}{M}=\dfrac{6,2}{31}=0,2\left(mol\right)\)
\(n_{O_2}=\dfrac{V}{22,4}=\dfrac{6,72}{32}=0,21\left(mol\right)\)
Có : \(n_P< n_{O_2}\left(0,2< 0,21\right)\)
-> P hết ; O2 dư
Từ (1) -> \(\dfrac{1}{2}n_P=n_{P_2O_5}=0,1\left(mol\right)\)
=> \(m_{P_2O_5}=n.M=14,2\left(g\right)\)
Bài 3:
\(n_{Fe_3O_4}=\dfrac{2,32}{232}=0,01\left(mol\right)\)
PTHH: 3Fe + 2O2 ---to→ Fe3O4
Mol: 0,03 0,02 0,01
\(m_{Fe}=0,03.56=1,68\left(g\right);V_{O_2}=0,02.22,4=0,448\left(l\right)\)
Bổ sung: Khí O2 được đo ở ĐKTC.
\(n_{Fe}=\dfrac{m_{Fe}}{M_{Fe}}=\dfrac{11,2}{56}=0,2\left(mol\right)\)
PTHH: \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
...........3.............2............1........
...........0,2..........0,4/3.......0,2/3......
a. \(V=V_{O_2\left(ĐKTC\right)}=n_{O_2}\cdot22,4=\dfrac{0,4}{3}\cdot22,4\approx2,99\left(l\right)\)
b. \(m=m_{Fe_3O_4}=n_{Fe_3O_4}\cdot M_{Fe_3O_4}=\dfrac{0,2}{3}\cdot232\approx15,47\left(g\right)\)
a.b.\(n_{Fe}=\dfrac{16,8}{56}=0,3\left(mol\right)\)
\(3Fe+2O_2\rightarrow\left(t^o\right)Fe_3O_4\)
0,3 0,2 0,1 ( mol )
\(m_{Fe_3O_4}=0,1.232=23,2\left(g\right)\)
\(V_{O_2}=0,2.22,4=4,48\left(l\right)\)
c. \(n_{O_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
\(3Fe+2O_2\rightarrow\left(t^o\right)Fe_3O_4\)
0,3 > 0,15 ( mol )
0,225 0,15 0,075 ( mol )
\(m_{Fe_3O_4}=0,075.232=17,4\left(g\right)\)
d. \(n_{H_2}=\dfrac{7,84}{22,4}=0,35\left(mol\right)\)
\(Fe_3O_4+4H_2\rightarrow\left(t^o\right)3Fe+4H_2O\)
0,075 < 0,35 ( mol )
0,075 0,3 ( mol )
Chất dư là H2
\(m_{H_2\left(dư\right)}=\left(0,35-0,3\right).2=0,1\left(g\right)\)
a) \(n_{Fe}=\dfrac{3,36}{56}=0,06\left(mol\right)\)
PTHH: 3Fe + 2O2 --to--> Fe3O4
0,06->0,04------->0,02
=> mFe3O4 = 0,02.232 = 4,64 (g)
b) VO2 = 0,04.22,4 = 0,896 (l)
\(a,n_{Fe}=\dfrac{14}{56}=0,25(mol)\\ n_{O_2}=\dfrac{8,96}{22,4}=0,4(mol)\\ PTHH:3Fe+2O_2\xrightarrow{t^o}Fe_3O_4\\ \text {Vì }\dfrac{n_{Fe}}{3}<\dfrac{n_{O_2}}{2}\text {nên sau phản ứng } O_2\text { dư}\)
\(\text {Theo PT: }n_{O_2}=\dfrac{2}{3}n_{Fe}=0,17(mol)\\ \Rightarrow n_{O_2(dư)}=0,4-0,17\approx0,23(mol)\\ b,n_{Fe_3O_4}=\dfrac{1}{3}n_{Fe}\approx0,08(mol)\\ \Rightarrow m_{Fe_3O_4}=0,08.232=18,56(g) \)
nFe=14/56=0,25
nO2=8,96/22,4=0,4
3Fe+2O2----->Fe3O4
0,25/3<0,4/2 =>Fe hết và O2 dư và dư 0,2 mol
mFe3O4=1/12*232=19,3g
\(a,PTHH:3Fe+2O_2\rightarrow^{t^o}Fe_3O_4\\ b,n_{Fe_3O_4}=\dfrac{23,2}{232}=0,1\left(mol\right)\\ \Rightarrow n_{O_2}=2n_{Fe_3O_4}=0,2\left(mol\right)\\ \Rightarrow V_{O_2\left(đktc\right)}=0,2\cdot22,4=4,48\left(l\right)\\ c,n_{Fe}=3n_{Fe_3O_4}=0,3\left(mol\right)\\ \Rightarrow m=m_{Fe}=0,3\cdot56=16,8\left(g\right)\)
PTHH: \(2KMnO_4\xrightarrow[]{t^o}K_2MnO_4+MnO_2+O_2\)
\(n_{KMnO_4}=\dfrac{m_{KMnO_4}}{M_{KMnO_4}}=\dfrac{15,8}{158}=0,1\left(mol\right)\)
a. Theo PTHH: \(n_{O_2}=\dfrac{1}{2}n_{KMnO_4}=\dfrac{1}{2}0,1=0,05\left(mol\right)\)
\(\Rightarrow V_{O_2}=n_{O_2}.22,4=0,05.22,4=1,12\left(l\right)\)
b. PTHH: \(3Fe+2O_2\xrightarrow[]{t^o}Fe_3O_4\)
\(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
Ta có: \(\dfrac{1}{n_{O_2}}=\dfrac{1}{0,05}\)
\(\dfrac{1}{n_{Fe}}=\dfrac{1}{0,1}\)
\(\Rightarrow\dfrac{1}{n_{O_2}}>\dfrac{1}{n_{Fe}}\)
Vậy Fe dư
Theo PTHH: \(n_{Fe_3O_4}=\dfrac{0,1.1}{3}=\dfrac{1}{30}\left(mol\right)\)
\(\Rightarrow m_{Fe_3O_4}=n_{Fe_3O_4}.M_{Fe_3O_4}=\dfrac{1}{30}.232\approx7,73g\)
\(n_{O_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)
PTHH: 3Fe + 2O2 --to--> Fe3O4
0,6<--0,4
=> mFe = 0,6.56 = 33,6(g)
\(n_{O_2}=\dfrac{8.96}{22.4}=0.4\left(mol\right)\)
\(3Fe+2O_2\underrightarrow{^{^{t^0}}}Fe_3O_4\)
\(0.6......0.4\)
\(m_{Fe}=0.6\cdot56=33.6\left(g\right)\)