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số oxh của Fe cả quá trình k đổi..bảo toàn e =>nCaC03=nC02=n0=n02/2=0,05 mol
nFe = 33,6 : 56 = 0,6 (mol)
pthh : 3Fe + 2O2 -t--> Fe3O4
0,6--> 0,4------->0,2 (mol)
=> vO2 = 0,4.22,4 = 8,96 (mol)
=> mFe3O4 = 0,2.232 = 46,4 (g)
pthh : 2KClO3 -t--> 2KClO3 + 3O2
0,267<-----------------------0,4(mol)
mKClO3= 0,267 .122,5 = 32,67 (g)
a, \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
b, Ta có: \(n_{Fe}=\dfrac{50,4}{56}=0,9\left(mol\right)\)
Theo PT: \(n_{O_2}=\dfrac{2}{3}n_{Fe}=0,6\left(mol\right)\Rightarrow V_{O_2}=0,6.22,4=13,44\left(l\right)\)
c, \(n_{Fe_3O_4}=\dfrac{1}{3}n_{Fe}=0,3\left(mol\right)\Rightarrow m_{Fe_3O_4}=0,3.232=69,6\left(g\right)\)
d, \(2KClO_3\underrightarrow{t^o}2KCl+3O_2\)
Theo PT: \(n_{KClO_3}=\dfrac{2}{3}n_{O_2}=0,4\left(mol\right)\Rightarrow m_{KClO_3}=0,4.122,5=49\left(g\right)\)
\(n_{Fe}=\dfrac{m}{M}=\dfrac{50,4}{56}=0,9\left(mol\right)\)
\(a.PTHH:3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
3 2 1
0,9 0,6 0,3
\(b.V_{O_2}=n.24,79=0,6.24,79=14,874\left(l\right)\)
\(c.m_{Fe_3O_4}=n.M=0,3.\left(56.3+16.4\right)=69,6\left(g\right)\)
\(d.V_{O_2}=14,874\left(l\right)\\ \Rightarrow n_{O_2}=\dfrac{V}{24,79}=\dfrac{14,874}{24,79}=0,6\left(mol\right)\\ PTHH:2KClO_3\underrightarrow{t^o}2KCl+3O_2\)
2 2 3
0,6 0,6 0,9
\(m_{KClO_3}=n.M=0,6.\left(39+35,5+16.3\right)=55,5\left(g\right).\)
nFe= 0,03(mol)
a) PTHH: 3 Fe +2 O2 -to-> Fe3O4
nFe3O4= nFe/3= 0,03/3=0,01(mol)
=> mFe3O4=232.0,01=2,32(g)
b) nO2= 2/3 . nFe3O4= 2/3 . 0,03=0,02(mol)
=>V(O2,đktc)=0,02.22,4=0,448(l)
d) V(kk,đktc)=5.V(O2,đktc)= 5.0,448=2,24(l)
PTHH: \(2KMnO_4\xrightarrow[]{t^o}K_2MnO_4+MnO_2+O_2\)
\(n_{KMnO_4}=\dfrac{m_{KMnO_4}}{M_{KMnO_4}}=\dfrac{15,8}{158}=0,1\left(mol\right)\)
a. Theo PTHH: \(n_{O_2}=\dfrac{1}{2}n_{KMnO_4}=\dfrac{1}{2}0,1=0,05\left(mol\right)\)
\(\Rightarrow V_{O_2}=n_{O_2}.22,4=0,05.22,4=1,12\left(l\right)\)
b. PTHH: \(3Fe+2O_2\xrightarrow[]{t^o}Fe_3O_4\)
\(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
Ta có: \(\dfrac{1}{n_{O_2}}=\dfrac{1}{0,05}\)
\(\dfrac{1}{n_{Fe}}=\dfrac{1}{0,1}\)
\(\Rightarrow\dfrac{1}{n_{O_2}}>\dfrac{1}{n_{Fe}}\)
Vậy Fe dư
Theo PTHH: \(n_{Fe_3O_4}=\dfrac{0,1.1}{3}=\dfrac{1}{30}\left(mol\right)\)
\(\Rightarrow m_{Fe_3O_4}=n_{Fe_3O_4}.M_{Fe_3O_4}=\dfrac{1}{30}.232\approx7,73g\)
\(n_{Fe}=\dfrac{12.6}{56}=0.225\left(mol\right)\)
\(n_{O_2}=\dfrac{4.2}{22.4}=0.1875\left(mol\right)\)
\(3Fe+2O_2\underrightarrow{^{^{t^0}}}Fe_3O_4\)
\(3.........2\)
\(0.225......0.1875\)
Lập tỉ lệ : \(\dfrac{0.225}{3}< \dfrac{0.1875}{2}\Rightarrow O_2dư\)
\(m_{O_2\left(dư\right)}=\left(0.1875-0.225\cdot\dfrac{2}{3}\right)\cdot32=1.2\left(g\right)\)
\(m_{Fe_3O_4}=\dfrac{0.225}{3}\cdot232=17.4\left(g\right)\)
\(n_{Fe}=\dfrac{m}{M}=\dfrac{5,6}{56}=0,1\left(mol\right)\\ PTHH:3Fe+2O_2-^{t^o}>Fe_3O_4\)
tỉ lệ: 3 : 2 : 1
n(mol) 0,1--->`1/15` -->`1/30`
\(m_{Fe_3O_4}=n\cdot M=\dfrac{1}{30}\cdot\left(56\cdot3+16\cdot4\right)=\approx7,73\left(g\right)\\ V_{O_2\left(dktc\right)}=n\cdot22,4=\dfrac{1}{15}\cdot22,4=\approx1,5\left(l\right)\)
nFe3O4 = 23.2/232 = 0.1 mol
3Fe + 2O2 -to-> Fe3O4
0.3____0.2_______0.1
mFe = 0.3*56 = 16.8 g
VO2 = 0.2*22.4 = 4.48 (l)
Vkk = 5VO2 = 22.4 (l)
a/ \(4FeS_2\left(\frac{388000}{11}\right)+11O_2\left(97000\right)\rightarrow2Fe_2O_3\left(\frac{194000}{11}\right)+8SO_2\left(\frac{776000}{11}\right)\)
\(m_{FeS_2}=5600000.0,75=4200000\)
\(\Rightarrow n_{FeS_2}=\frac{4200000}{120}=35000\)
\(n_{O_2}=\frac{3104000}{32}=97000\)
Ta thấy: \(\frac{35000}{4}>\frac{97000}{11}\) nên O2 phản ứng hết
\(m_{Fe_2O_3}=\frac{194000}{11}.160=2821818,18\)
b/ \(SO_2\left(\frac{776000}{11}\right)+Ca\left(OH\right)_2\rightarrow CaSO_3\left(\frac{776000}{11}\right)+H_2O\)
\(m_{CaSO_3}=\frac{776000}{11}.120=8465454,55\)