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\(m_{bìnhtăng}=m_{anken}=m_{etilen}=1,4g\)
\(\Rightarrow n_{C_2H_4}=\dfrac{1,4}{28}=0,05mol\)
\(n_{hh}=\dfrac{4,48}{22,4}=0,2mol\)
\(\Rightarrow n_{metan}=n_{hh}-n_{eilen}=0,2-0,05=0,15mol\)
\(\%V_{metan}=\dfrac{0,15}{0,2}\cdot100\%=75\%\)
\(\%V_{etilen}=100\%-75\%=25\%\)
\(a)\\ C_2H_4 + Br_2 \to C_2H_4Br_2\\ n_{C_2H_4} = n_{Br_2} = \dfrac{80.10\%}{160} = 0,05(mol)\\ \Rightarrow \%m_{C_2H_4} = \dfrac{0,05.28}{2}.100\% = 70\%\\ \%m_{CH_4} = 100\% - 70\% = 30\%\)
\(b)\) Sản phẩm : Đibrom etan
\(n_{C_2H_4Br_2} = n_{Br_2} = 0,05(mol)\\ \Rightarrow m_{C_2H_4Br_2} = 0,05.188 = 9,4\ gam\)
a, nBr2 = 8/160 = 0,05 (mol)
PTHH: C2H4 + Br2 -> C2H4Br2
Mol: 0,05 <--- 0,05 <--- 0,05
Vhh khí = 2,8/22,4 = 0,125 (mol)
%VC2H4 = 0,05/0,125 = 40%
%CH4 = 100% - 40% = 60%
b, nCH4 = 0,125 - 0,05 = 0,075 (mol)
PTHH: C2H4 + 3O2 -> (t°) 2CO2 + 2H2O
Mol: 0,05 ---> 0,15
CH4 + 2O2 -> (t°) CO2 + 2H2O
Mol: 0,075 ---> 0,15
Vkk = (0,15 + 0,15) . 5 . 22,4 = 33,6 (l)
PTHH: \(CH_4+2O_2\xrightarrow[]{t^o}CO_2+2H_2O\)
Ta có: \(n_{CO_2}=\dfrac{1,68}{22,4}=0,075\left(mol\right)=n_{CH_4}\)
Đặt \(\left\{{}\begin{matrix}n_{C_2H_4}=a\left(mol\right)\\n_{C_2H_2}=b\left(mol\right)\end{matrix}\right.\) \(\Rightarrow a+b=\dfrac{5,04}{22,4}-0,075=0,15\) (1)
PTHH: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
Theo PTHH: \(28a+26b=4,1\) (2)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}a=n_{C_2H_4}=0,1\left(mol\right)\\b=n_{C_2H_2}=0,05\left(mol\right)\end{matrix}\right.\)
Mặt khác: \(n_{hh}=\dfrac{5,04}{22,4}=0,225\left(mol\right)\) \(\Rightarrow\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{0,075}{0,225}\cdot100\%\approx33,33\%\\\%V_{C_2H_4}=\dfrac{0,1}{0,225}\cdot100\%\approx44,44\%\\\%V_{C_2H_2}=22,23\%\end{matrix}\right.\)
a) nC2H4Br2=47/188=0,25(mol)
n(CH4,C2H4)=11,2/22,4=0,5(mol)
PTHH: C2H4 + Br2 -> C2H4Br2
0,25<----------0,25<---------0,25(mol)
mBr2(p.ứ)=0,25 x 160= 40(g)
b) V(C2H4,đktc)=0,25 x 22,4= 5,6(l)
=> %V(C2H4)=(5,6/11,2).100=50%
=>%V(CH4)=100% - 50%= 50%
a)
PTHH: C2H2+2Br2 --> C2H2Br4
b) \(n_{C_2H_2}=\dfrac{36}{26}=\dfrac{18}{13}\left(mol\right)\)
=> \(V_{C_2H_2}=\dfrac{18}{13}.22,4=\dfrac{2016}{65}\left(l\right)\)
\(n_{CH_4}=\dfrac{42-36}{16}=0,375\left(mol\right)\)
=> \(V_{CH_4}=0,375.22,4=8,4\left(l\right)\)
c) \(\left\{{}\begin{matrix}\%V_{C_2H_2}=\dfrac{\dfrac{2016}{65}}{\dfrac{2016}{65}+8,4}.100\%=78,69\%\\\%V_{CH_4}=\dfrac{8,4}{\dfrac{2016}{65}+8,4}.100\%=21,31\%\end{matrix}\right.\)
1. \(n_{Br_2}=0,4.0,5=0,2\left(mol\right)\)
PT: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
Theo PT: \(n_{C_2H_4}=n_{Br_2}=0,2\left(mol\right)\Rightarrow V_{C_2H_4}=0,2.22,4=4,48\left(l\right)\)
2. \(n_{C_2H_4Br_2}=\dfrac{9,4}{188}=0,05\left(mol\right)\)
PT: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
Theo PT: \(n_{C_2H_4}=n_{C_2H_4Br_2}=0,05\left(mol\right)\)
\(\Rightarrow\%V_{C_2H_4}=\dfrac{0,05.22,4}{1,4}.100\%=80\%\)
\(\Rightarrow\%V_{CH_4}=100-80=20\%\)
Bài 1 :
\(CH_4 + 2O_2 \xrightarrow{t^o} CO_2 + 2H_2O\\ CO_2 + Ca(OH)_2 \to CaCO_3 + H_2O\\ n_{CaCO_3} = n_{CO_2} = n_{CH_4} = \dfrac{5,6}{22,4} = 0,25(mol)\\ m_{CaCO_3} = 0,25.100 = 25(gam)\)
\(n_{hh}=\dfrac{4.48}{22.4}=0.2\left(mol\right)\)
\(n_{Br_2}=\dfrac{16}{160}=0.1\left(mol\right)\)
\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
\(0.1.........0.1\)
\(n_{CH_4}=0.2-0.1=0.1\left(mol\right)\)
\(\%V_{C_2H_4}=\%V_{CH_4}=\dfrac{0.1}{0.2}\cdot100\%=50\%\)
Em cung cấp thông tin đề câu b lại nhé !
e viết nhầm khí 4,48 hỗn hợp A