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a) Fe + 2HCl --> FeCl2 + H2
FeO + 2HCl --> FeCl2 + H2O
b) \(n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
PTHH: Fe + 2HCl --> FeCl2 + H2
______0,5<-1<------0,5<---0,5
=> mFe = 0,5.56 = 28 (g)
=> \(\left\{{}\begin{matrix}\%Fe=\dfrac{28}{100}.100\%=28\%\\\%FeO=100\%-28\%=72\%\end{matrix}\right.\)
c) \(n_{FeO}=\dfrac{72}{72}=1\left(mol\right)\)
PTHH: FeO + 2HCl --> FeCl2 + H2O
______1---->2
=> mHCl = (1+2).36,5 = 109,5 (g)
=> \(m_{ddHCl}=\dfrac{109,5.100}{30}=365\left(g\right)\)
=> \(V_{ddHCl}=\dfrac{365}{1,15}=317,39\left(ml\right)\)
PTHH: \(Mg+H_2SO_4\rightarrow MgSO_4+H_2\uparrow\)
a_______a________a______a (mol)
\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\)
b_______\(\dfrac{3}{2}\)b_________\(\dfrac{1}{2}\)b_____\(\dfrac{3}{2}\)b (mol)
a) Ta lập HPT: \(\left\{{}\begin{matrix}24a+27b=8,25\\a+\dfrac{3}{2}b=\dfrac{2,24}{22,4}=0,1\end{matrix}\right.\) \(\Leftrightarrow\) Hệ có nghiệm âm
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a) \(n_{H_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\left(1dm^3=1l\right)\)
PTHH: 2Al + 3H2SO4 → Al2(SO4)3 + 3H2
Mol: x 1,5x
PTHH: Mg + H2SO4 → MgSO4 + H2
Mol: y y
Ta có: \(\left\{{}\begin{matrix}27x+24y=7,8\\1,5x+y=0,4\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,2\\y=0,1\end{matrix}\right.\)
\(\%m_{Al}=\dfrac{0,2.27.100\%}{7,8}=69,23\%;\%m_{Mg}=100-69,23=30,77\%\)
b)
PTHH: 2Al + 3H2SO4 → Al2(SO4)3 + 3H2
Mol: 0,2 0,3 0,1
PTHH: Mg + H2SO4 → MgSO4 + H2
Mol: 0,1 0,1 0,1
\(V_{ddH_2SO_4}=\dfrac{0,3+0,1}{2}=0,2\left(l\right)=200\left(ml\right)\)
\(\Rightarrow m_{ddH_2SO_4}=1,12.200=224\left(g\right)\)
c) \(C_{M_{ddAl_2\left(SO_4\right)_3}}=\dfrac{0,1}{0,2}=0,5M\)
\(C_{M_{ddMgSO_4}}=\dfrac{0,1}{0,2}=0,5M\)
\(n_{H2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
Pt : \(Fe+2HCl\rightarrow FeCl_2+H_2|\)
1 2 1 1
0,2 0,4 0,2 0,2
\(Fe_2O_3+6HCl\rightarrow2FeCl_3+3H_2O|\)
1 6 2 3
0,2 1,2 0,4
\(n_{Fe}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)
⇒ \(m_{Fe}=0,2.56=11,2\left(g\right)\)
\(m_{Fe2O3}=27,2-11,2=16\left(g\right)\)
0/0Fe = \(\dfrac{11,2.100}{27,2}=41,18\)0/0
0/0Fe2O3 = \(\dfrac{16.100}{27,2}=58,82\)0/0
b) Có : \(m_{Fe2O3}=16\left(g\right)\)
\(n_{Fe2O3}=\dfrac{16}{160}=0,1\left(mol\right)\)
\(n_{HCl\left(tổng\right)}=0,4+1,2=1,6\left(mol\right)\)
\(V_{HCl}=\dfrac{1,6}{2}=0,8\left(l\right)\)
c) \(n_{FeCl2}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)
\(n_{FeCl3}=\dfrac{1,2.2}{6}=0,4\left(mol\right)\)
\(C_{M_{FeCl2}}=\dfrac{0,2}{0,8}=0,25\left(M\right)\)
\(C_{M_{FeCl3}}=\dfrac{0,4}{0,8}=0,5\left(M\right)\)
Chúc bạn học tốt
Gọi \(n_{Fe}=x\left(mol\right)\)\(;n_{Zn}=y\left(mol\right)\)
\(n_{H_2}=\dfrac{6,72}{22,4}=0,3mol\)
Ta có: \(\left\{{}\begin{matrix}56x+65y=18,6\\2x+2y=2n_{H_2}=0,6\end{matrix}\right.\)\(\Rightarrow\left\{{}\begin{matrix}x=0,1\\y=0,2\end{matrix}\right.\)
\(\%m_{Fe}=\dfrac{0,1\cdot56}{18,6}\cdot100\%=30,11\%\)
\(\%m_{Zn}=100\%-30,11\%=69,89\%\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
0,1 0,2
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,2 0,4
\(n_{HCl}=0,2+0,4=0,6mol\)
\(C_M=\dfrac{n}{V}=\dfrac{0,6}{0,2}=3M\)
a, \(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(FeO+2HCl\rightarrow FeCl_2+H_2O\)
Ta có: \(n_{H_2}=\dfrac{0,896}{22,4}=0,04\left(mol\right)\)
Theo PT: \(n_{Fe}=n_{H_2}=0,04\left(mol\right)\)
\(\Rightarrow\%m_{FeO}=\dfrac{5,84-0,04.56}{5,84}.100\%\approx61,64\%\)
b, Ta có: \(n_{FeO}=\dfrac{5,84-0,04.56}{72}=0,05\left(mol\right)\)
Theo PT: \(n_{HCl}=2n_{Fe}+2n_{FeO}=0,18\left(mol\right)\)
\(\Rightarrow V_{ddHCl}=\dfrac{0,18}{1}=0,18\left(l\right)=180\left(ml\right)\)
c, Theo PT: \(n_{FeCl_2}=n_{Fe}+n_{FeO}=0,09\left(mol\right)\)
Có: m dd HCl = 180.1,15 = 207 (g)
⇒ m dd sau pư = 5,84 + 207 - 0,04.2 = 212,76 (g)
\(\Rightarrow C\%_{FeCl_2}=\dfrac{0,09.127}{212,76}.100\%\approx5,37\%\)