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a)
$Fe + 2HCl \to FeCl_2 + H_2$
$FeO +2 HCl \to FeCl_2 + H_2O$
b)
Theo PTHH :
$n_{Fe} = n_{H_2} = \dfrac{4,48}{22,4} = 0,2(mol)$
$\%m_{Fe} = \dfrac{0,2.56}{20}.100\% = 56\%$
$\%m_{FeO} = 100\% - 56\% = 44\%$
c) $n_{FeO} = \dfrac{11}{90}(mol)$
$n_{HCl} = 2n_{Fe} + 2n_{FeO} = \dfrac{29}{45}(mol)$
$m_{dd\ HCl} = \dfrac{ \dfrac{29}{45}.36,5}{7,3\%} = 322,22(gam)$
a, \(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(FeO+2HCl\rightarrow FeCl_2+H_2O\)
Ta có: \(n_{H_2}=\dfrac{0,896}{22,4}=0,04\left(mol\right)\)
Theo PT: \(n_{Fe}=n_{H_2}=0,04\left(mol\right)\)
\(\Rightarrow\%m_{FeO}=\dfrac{5,84-0,04.56}{5,84}.100\%\approx61,64\%\)
b, Ta có: \(n_{FeO}=\dfrac{5,84-0,04.56}{72}=0,05\left(mol\right)\)
Theo PT: \(n_{HCl}=2n_{Fe}+2n_{FeO}=0,18\left(mol\right)\)
\(\Rightarrow V_{ddHCl}=\dfrac{0,18}{1}=0,18\left(l\right)=180\left(ml\right)\)
c, Theo PT: \(n_{FeCl_2}=n_{Fe}+n_{FeO}=0,09\left(mol\right)\)
Có: m dd HCl = 180.1,15 = 207 (g)
⇒ m dd sau pư = 5,84 + 207 - 0,04.2 = 212,76 (g)
\(\Rightarrow C\%_{FeCl_2}=\dfrac{0,09.127}{212,76}.100\%\approx5,37\%\)
nH2=0,1(mol)
PTHH: Mg + 2 HCl -> MgCl2 + H2
0,1__________0,2___________0,1(mol)
MgO + 2 HCl -> MgCl2 + H2O
0,05____0,1___0,05(mol)
mMg=0,1. 24= 2,4(g) -> mMgO=4,4-2,4= 2(g) -> nMgO=0,05((mol)
b) %mMg= (2,4/4,4).100=54,545%
=> %mMgO=45,455%
c) nHCl=0,3(mol) -> mHCl=0,3.36,5=10,95(g)
=> mddHCl=(10,95.100)/7,3=150(g)
a, PT: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(FeO+2HCl\rightarrow FeCl_2+H_2O\)
b, Ta có: \(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
Theo PT: \(n_{Al}=\dfrac{2}{3}n_{H_2}=0,2\left(mol\right)\)
\(\Rightarrow m_{Al}=0,2.27=5,4\left(g\right)\)
⇒ mFeO = 12,6 - 5,4 = 7,2 (g)
c, Phần này đề cho dd NaOH dư hay vừa đủ bạn nhỉ?
d, Cho hh vào dd H2SO4 đặc nguội thì có khí thoát ra.
PT: \(2FeO+4H_2SO_{4\left(đ\right)}\rightarrow Fe_2\left(SO_4\right)_3+SO_2+4H_2O\)
Ta có: \(n_{FeO}=\dfrac{7,2}{72}=0,1\left(mol\right)\)
Theo PT: \(n_{SO_2}=\dfrac{1}{2}n_{FeO}=0,05\left(mol\right)\)
\(\Rightarrow V_{SO_2}=0,05.22,4=1,12\left(l\right)\)
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Bài 1:
Ta có: \(n_{H_2}=\dfrac{0,4}{2}=0,2\left(mol\right)\)
Bảo toàn Hidro: \(n_{HCl}=2n_{H_2}=0,4\left(mol\right)\) \(\Rightarrow m_{HCl\left(p.ứ\right)}=0,4\cdot36,5=14,6\left(g\right)\)
Bảo toàn khối lượng: \(m_{muối}=m_{KL}+m_{HCl\left(p.ứ\right)}-m_{H_2}=24,7\left(g\right)\)
a) Fe + 2HCl --> FeCl2 + H2
FeO + 2HCl --> FeCl2 + H2O
b) \(n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
PTHH: Fe + 2HCl --> FeCl2 + H2
______0,5<-1<------0,5<---0,5
=> mFe = 0,5.56 = 28 (g)
=> \(\left\{{}\begin{matrix}\%Fe=\dfrac{28}{100}.100\%=28\%\\\%FeO=100\%-28\%=72\%\end{matrix}\right.\)
c) \(n_{FeO}=\dfrac{72}{72}=1\left(mol\right)\)
PTHH: FeO + 2HCl --> FeCl2 + H2O
______1---->2
=> mHCl = (1+2).36,5 = 109,5 (g)
=> \(m_{ddHCl}=\dfrac{109,5.100}{30}=365\left(g\right)\)
=> \(V_{ddHCl}=\dfrac{365}{1,15}=317,39\left(ml\right)\)