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Ta có: \(n_{Na_2O}=\dfrac{24,8}{62}=0,4\left(mol\right)\)
\(n_{HNO_3}=\dfrac{50,4}{63}=0,8\left(mol\right)\)
PT: \(Na_2O+2HNO_3\rightarrow2NaNO_3+H_2O\)
____0,4_____0,8_________0,8 (mol)
→ Pư vừa đủ.
\(\Rightarrow m_{NaNO_3}=0,8.85=68\left(g\right)\)
Bạn tham khảo nhé!
n H2SO4=\(\dfrac{10\%.490}{2+32+16.4}=0,5mol\)
n Al2O3 =\(\dfrac{10,2}{27.2+16.3}=0,1mol\)
\(Al_2O_3+3H_2SO_4->Al_2\left(SO_4\right)_3+3H_2O\)
bđ 0,1............0,5
pư 0,1............0,3..................0,1
spu 0 ................0,2................0,1
=> sau pư gồm H2SO4 dư , Al2(S04)3 và H2O
m H2SO4 dư = \(0,2.\left(2+32+16.3\right)=19,6g\)
m Al2(SO4)3 = \(0,1\left(27.2+32.3+16.4.3\right)=34,2g\)
m dd = \(490+10,2=500,2g\)
% Al2(SO4)3 = \(\dfrac{34,2}{500,2}.100\sim6,84\%\)
% H2SO4 dư = \(\dfrac{19,6}{500,2}.100\sim3,92\%\)
\(n_{Fe_2O_3}=\dfrac{3.2}{160}=0.02\left(mol\right)\)
\(n_{HCl}=\dfrac{2.19}{36.5}=0.06\left(mol\right)\)
\(Fe_2O_3+6HCl\rightarrow2FeCl_3+3H_2O\)
\(1...........6\)
\(0.02...........0.06\)
Lập tỉ lệ : \(\dfrac{0.02}{1}>\dfrac{0.06}{6}\Rightarrow Fe_2O_3dư\)
\(n_{Fe_2O_3\left(dư\right)}=0.02-\dfrac{0.06}{6}=0.01\left(mol\right)\)
\(m_{Fe_2O_3\left(dư\right)}=0.01\cdot160=1.6\left(g\right)\)
\(m_{FeCl_3}=0.02\cdot162.5=3.25\left(g\right)\)
\(m_{H_2O}=0.03\cdot18=0.54\left(g\right)\)
\(n_{Mg}=\dfrac{7,2}{24}=0,3\left(mol\right);n_{HCl}=\dfrac{29,2}{36,5}=0,8\left(mol\right)\\ Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\\ a,Vì:\dfrac{0,3}{1}< \dfrac{0,8}{2}\Rightarrow HCldư\\ n_{H_2}=n_{MgCl_2}=n_{Mg}=0,3\left(mol\right)\\ n_{HCl\left(dư\right)}=0,8-0,3.2=0,2\left(mol\right)\\ V_{H_2\left(đktc\right)}=0,3.22,4=6,72\left(l\right)\\ b,m_{MgCl_2}=0,3.95=28,5\left(g\right)\\ m_{HCl\left(dư\right)}=0,2.36,5=7,3\left(g\right)\)
a) \(n_{Mg}=\dfrac{7,2}{24}=0,3\left(mol\right)\)
\(n_{HCl}=\dfrac{29.2}{36,5}=0,8\left(mol\right)\)
PTHH : 2Mg + 2HCl -> 2MgCl + H2
Xét tỉ lệ \(\dfrac{0,3}{2}< \dfrac{0,8}{2}\)
=> HCl dư
=> \(V_{H_2}=0,075.22,4=1,68\left(l\right)\)
=> \(V_{MgCl}=0,15.22,4=3,36\left(l\right)\)
b) \(m_{H_2}=0,075.2=0,15\left(g\right)\\ m_{MgCl}=0,15.59,5=8,925\left(g\right)\)
\(n_{Ca}=\dfrac{8}{40}=0,2mol\\ 2Ca+O_2\xrightarrow[]{t^0}2CaO\\ n_{CaO}=n_{Ca}=0,2mol\\ n_{HCl}=\dfrac{18,25}{36,5}=0,5mol\\ CaO+2HCl\rightarrow CaCl_2+H_2O\\ \Rightarrow\dfrac{0,2}{1}< \dfrac{0,5}{2}\Rightarrow HCl.dư\\ n_{CaCl_2}=n_{CaO}=0,2mol\\ n_{HCl}=2n_{CaO}=0,4mol\\ m_{CaCl_2}=0,2.111=22,2g\\ m_{HCl.dư}=\left(0,5-0,4\right).36,5=3,65g\)
a) Fe2O3 + 6HCl --> 2FeCl3 + 3H2O
\(n_{Fe_2O_3}=\dfrac{3,2}{160}=0,02\left(mol\right)\)
\(n_{HCl}=\dfrac{2,19}{36,5}=0,06\left(mol\right)\)
Xét tỉ lệ \(\dfrac{0,02}{1}>\dfrac{0,06}{6}\) => Fe2O3 dư, HCl hết
PTHH: Fe2O3 + 6HCl --> 2FeCl3 + 3H2O
0,01<--0,06------->0,02---->0,03
=> \(m_{Fe_2O_3\left(dư\right)}=\left(0,02-0,01\right).160=1,6\left(g\right)\)
b) \(m_{FeCl_3}=0,02.162,5=3,25\left(g\right)\)
\(m_{H_2O}=0,03.18=0,54\left(g\right)\)
\(n_{Zn}=\dfrac{8,125}{65}=0,125\left(mol\right)\\ m_{HCl}=\dfrac{100.18,25}{100}=18,25\left(g\right)\\
n_{HCl}=\dfrac{18,25}{36,5}=0,5\\ pthh:Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
0,125 0,125 (mol )
\(\Rightarrow V_{H_2}=0,125.22,4=2,8\left(l\right)\\
\)
\(C\%=\dfrac{8,125}{8,125+18,25}.100\%=30,8\%\)
Bài 18:
Ta có: \(n_{Zn}=\dfrac{8,125}{65}=0,125\left(mol\right)\)
\(m_{HCl}=100.18,25\%=18,25\left(g\right)\Rightarrow n_{HCl}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\)
a, PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
b, Xét tỉ lệ: \(\dfrac{0,125}{1}< \dfrac{0,5}{2}\), ta được HCl dư.
Theo PT: \(n_{H_2}=n_{Zn}=0,125\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,125.22,4=2,8\left(g\right)\)
\(m_{H_2}=0,125.2=0,25\left(g\right)\)
c, Theo PT: \(\left\{{}\begin{matrix}n_{ZnCl_2}=n_{Zn}=0,125\left(mol\right)\\n_{HCl\left(pư\right)}=2n_{Zn}=0,25\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{HCl\left(dư\right)}=0,25\left(mol\right)\)
Có: m dd sau pư = 8,125 + 100 - 0,25 = 107,875 (g)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{ZnCl_2}=\dfrac{0,125.136}{107,875}.100\%\approx15,76\%\\C\%_{HCl\left(dư\right)}=\dfrac{0,25.36,5}{107,875}.100\%\approx8,46\%\end{matrix}\right.\)
Bạn tham khảo nhé!
\(n_{Al}=\dfrac{5.4}{27}=0.2\left(mol\right)\)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(0.2.........................0.2.......0.3\)
\(m_{AlCl_3}=0.2\cdot133.5=26.7\left(g\right)\)
\(n_{CuO}=\dfrac{32}{160}=0.2\left(mol\right)\)
\(CuO+H_2\underrightarrow{^{t^0}}Cu+H_2O\)
\(1..........1\)
\(0.2........0.3\)
\(LTL:\dfrac{0.2}{1}< \dfrac{0.3}{1}\Rightarrow H_2dư\)
\(n_{Cu}=0.2\left(mol\right)\)
\(m_{Cu}=0.2\cdot64=12.8\left(g\right)\)
Em xem lại đề vì chất rắn chỉ có Cu không có CuO nhé !
Sửa đề : 24.8 (g) Na2O
\(n_{Na_2O}=\dfrac{24.8}{62}=0.4\left(mol\right)\)
\(n_{HNO_3\left(dư\right)}=\dfrac{50.4}{63}=0.8\left(mol\right)\)
\(Na_2O+2HNO_3\rightarrow2NaNO_3+H_2O\)
\(0.4............0.8..............0.8...........0.4\)
\(m_{NaNO_3}=0.8\cdot85=68\left(g\right)\)
\(m_{H_2O}=0.4\cdot18=7.2\left(g\right)\)