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nno3=\(\dfrac{m}{M}=\dfrac{189}{63}=3\left(mol\right)\)
nkoh=\(\dfrac{m}{M}=\dfrac{112}{56}=2\left(mol\right)\)
pthh: HNO3 + KOH \(\rightarrow\) HNO3 + H2O 1.
2HNO3 + Ba(OH)2 \(\rightarrow\) Ba(NO3)2 + 2H2O 2.
Theo pthh 1 : nno3 =nkoh=2(mol)
\(n_{hno3dư_{ }}=1\left(mol\right)\)
Theo pthh 2 : nba(oh)2=nhno3=1(mol)
\(\Rightarrow m_{ba\left(ọh\right)_{2_{ }}=n.M=1.171=171\left(g\right)}\)
\(\Rightarrow m_{ddBa\left(oh\right)_2}=\dfrac{m_{ct}.100\%}{C\%}=\dfrac{117.100\%}{25}=468\left(g\right)\)
PTHH: \(KOH+HNO_3\rightarrow KNO_3+H_2O\)
\(Ba\left(OH\right)_2+2HNO_3\rightarrow Ba\left(NO_3\right)_2+2H_2O\)
Ta có: \(\left\{{}\begin{matrix}n_{KOH}=\dfrac{112}{56}=2\left(mol\right)\\n_{HNO_3}=\dfrac{189}{63}=3\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\) HNO3 dư 1 mol
\(\Rightarrow n_{Ba\left(OH\right)_2}=0,5\left(mol\right)\) \(\Rightarrow m_{ddBa\left(OH\right)_2}=\dfrac{0,5\cdot171}{25\%}=342\left(g\right)\)
\(n_{Na_2CO_3}=0,1.1=0,1\left(mol\right)\)
a. \(Na_2CO_3+Ba\left(OH\right)_2\rightarrow BaCO_3+2NaOH\)
0,1 0,1 0,1 0,2
b. \(m_{kt}=m_{BaCO_3}=0,1.197=19,7\left(g\right)\)
c. \(C\%_{Ba\left(OH\right)_2}=\dfrac{0,1.171.100}{200}=8,55\%\)
d. \(BaCO_3+2HCl\rightarrow BaCl_2+H_2O+CO_2\)
0,1 0,2
=> \(a=m_{dd.HCl}=\dfrac{0,2.36,5.100}{30}=\dfrac{73}{3}\left(g\right)\)
a) nHNO3=189/63=3(mol); nKOH= 112/56=2(mol)
PTHH: KOH + HNO3 -> KNO3 + H2O
Ta có: 3/1 > 2/1
-> KOH hết, HNO3 (dư)
nHNO3(p.ứ)= nKOH=2(mol) -> nHNO3(dư)=3-2=1(mol)
2 HNO3 + Ba(OH)2 -> Ba(NO3)2 + 2 H2O
1________0,5(mol)
b) => mBa(OH)2= 171.0,5= 85,5(g)
\(n_{KOH}=0,5.0,2=0,1\left(mol\right)\\ a,PTHH:2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O\\ b,n_{H_2SO_4}=n_{K_2SO_4}=\dfrac{n_{KOH}}{2}=\dfrac{0,1}{2}=0,05\left(mol\right)\\ V_{ddH_2SO_4}=\dfrac{0,05}{2}=0,025\left(l\right)\\ c,K_2SO_4+Ba\left(OH\right)_2\rightarrow2KOH+BaSO_4\downarrow\\ n_{Ba\left(OH\right)_2}=n_{BaSO_4}=n_{K_2SO_4}=0,05\left(mol\right)\\ m_{ddBa\left(OH\right)_2}=\dfrac{0,05.171.100}{5}=171\left(g\right)\\ m_{BaSO_4}=233.0,05=11,6\left(g\right)\)
PTHH: \(Ba\left(OH\right)_2+H_2SO_4\rightarrow BaSO_4\downarrow+2H_2O\)
Ta có: \(n_{Ba\left(OH\right)_2}=0,5\cdot1=0,5\left(mol\right)=n_{BaSO_4}=n_{H_2SO_4}\)
\(\Rightarrow\left\{{}\begin{matrix}m_{ddH_2SO_4}=\dfrac{0,5\cdot98}{15\%}\approx326,7\left(g\right)\\m_{BaSO_4}=0,5\cdot233=116,5\left(g\right)\end{matrix}\right.\)
\(n_{Ba\left(OH\right)_2}=0,5\cdot1=0,5mol\)
a)\(Ba\left(OH\right)_2+H_2SO_4\rightarrow BaSO_4\downarrow+2H_2O\)
0,5 0,5 0,5
b) \(m_{H_2SO_4}=0,5\cdot98=49\left(g\right)\)
\(\Rightarrow m_{ddH_2SO_4}=\dfrac{49}{15}\cdot100=326,67\left(g\right)\)
c) \(m_{BaSO_4}=0,5\cdot233=116,5\left(g\right)\)
a.
\(Na_2CO_3+Ba\left(OH\right)_2\rightarrow BaCO_3+2NaOH\)
b.
\(n_{BaCO_3}=n_{Na_2CO_3}=0,2.1=0,2\left(mol\right)\\ m_{kt}=197.0,2=39,4\left(g\right)\)
c.
\(n_{Ba\left(OH\right)_2}=n_{Na_2CO_3}=0,2\left(mol\right)\\ C\%_{Ba\left(OH\right)_2}=\dfrac{0,2.171.100\%}{200}=17,1\%\)
nHNO3= 3(mol) nKOH=2 (mol)
HNO3 + KOH -> KNO3+H2O
Trc pu 3 2
(.) pư 2 2
sau pư 1 0
HNO3+ Ba(OH)2 -> Ba(NO3)2+H2O
THEO PT 1 1
THEO ĐB 1 1
==> mdd Ba(OH)2= \(\dfrac{171.100\%}{25\%}=684\left(g\right)\)
Ba(OH)2+ CuCL2-> BaCL2+ Cu(OH)2
1 1
==> mket tua = mCu(OH)2= 1.98=98 (g)
mk cx ko chắc là đúng thông cảm nha