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\(PTHH:3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
\(Áp.dụng.ĐLBTKL,ta.có:m_{Fe}+m_{O_2}=m_{Fe_3O_4}\\ \Rightarrow m_{O_2}=m_{Fe_3O_4}-m_{Fe}=23,2-16,8=6,4\left(g\right)\\ \Rightarrow n_{O_2}=\dfrac{m}{M}=\dfrac{6,4}{32}=0,2\left(mol\right)\\ \Rightarrow V_{O_2}=n.22,4=0,2.22,4=4,48\left(l\right)\)
3Fe+2O2->Fe3O4
nFe3O4=23,2/232=0,1 mol
=>nO2=0,1x2=0,2 mol
VO2=0,2x22,4=4,48 l
\(a,3Fe+2O_2\rightarrow\left(t^o\right)Fe_3O_4\\ n_{Fe}=\dfrac{16,8}{56}=0,3\left(kmol\right)\\ n_{O_2}=\dfrac{2}{3}.0,3=0,2\left(kmol\right)\\ V_{O_2\left(\text{đ}ktc\right)}=0,2.1000.22,4=4480\left(l\right)\\ n_{Fe_3O_4}=\dfrac{1}{3}.0.3=0,1\left(kmol\right)\\ m_{Fe_3O_4}=232.0,1=23,2\left(kg\right)\)
`a)PTHH`
`Fe + 2HCl -> FeCl_2 + H_2`
`0,125` `0,25` `0,125` `0,125` `(mol)`
`n_[HCl]=[5/100 .182,5]/[36,5]=0,25(mol)`
`b)m_[Fe]=0,125.56=7(g)`
`V_[H_2]=0,125.22,4=2,8(l)`
`c)m_[HCl]=0,25.36,5=9,125(g)`
`m_[FeCl_2]=0,125.127=15,875(g)`
`d)C%_[FeCl_2]=[15,875]/[7+182,5-0,125.2] .100~~8,39%`
Fe+2HCl->FeCl2+H2
0,125--0,25---0,125-0,125
m HCl=9,125 g=>n HCl=\(\dfrac{9,125}{26,5}\)=0,25 mol
=>m Fe=0,125.56=7g
=>VH2=0,125.22,4=2,8l
=>C%FeCl2=\(\dfrac{0,125.127}{7+182,5-0,25}\).100=8,388%
\(a) Fe + 2HCl \to FeCl_2\\ b) n_{HCl} = \dfrac{182,5.5\%}{36,5} = 0,25(mol)\\ n_{FeCl_2} = n_{H_2} = n_{Fe} = \dfrac{1}{2}n_{HCl} = 0,125(mol)\\ \Rightarrow m_{Fe} = 0,125.56 = 7(gam) ; V = 0,125.22,4 = 2,8(lít)\\ c) m_{dd\ sau\ phản\ ứng} = m_{Fe} + m_{dd\ HCl} - m_{H_2} = 7 + 182,5 - 0,125.2 = 189,25(gam)\\ C\%_{FeCl_2} = \dfrac{0,125.127}{189,25}.100\% = 8,39\%\)
a)
\(2Cu + O_2 \xrightarrow{t^o} 2CuO\)
b)
\(n_{CuO} = n_{Cu} = \dfrac{6,4}{64} = 0,1(mol)\\ \Rightarrow m_{CuO} = 0,1.80 = 8(gam)\)
c)
\(n_{O_2} = \dfrac{1}{2}n_{Cu} = 0,05(mol)\\ 2KMnO_4 \xrightarrow{t^o} K_2MnO_4 + MnO_2 + O_2\\ m_{KMnO_4} = 2n_{O_2} = 0,05.2 = 0,1.158 = 15,8(gam)\)
d)
\(V_{không\ khí} = 5V_{O_2} = 0,05.22,4.5 = 5,6(lít)\)
Ta co pthh
3Fe + 2O2-to\(\rightarrow\) Fe3O4
Theo de bai ta co
nFe=\(\dfrac{33,6}{56}=0,6mol\)
Theo pthh
nO2=\(\dfrac{2}{3}nFe=\dfrac{2}{3}.0,6=0,4mol\)
\(\Rightarrow VO2_{\left(dktc\right)}\)=0,4.22,4=8,96 l
Theo pthh
nFe3O4=\(\dfrac{1}{3}nFe=\dfrac{1}{3}.0,6=0,2mol\)
\(\Rightarrow mFe3O4=0,2.232=46,4g\)
A
A