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Theo gt ta có: $n_{Fe_3O_4}=0,05(mol)$
$Fe_3O_4+4H_2\rightarrow 3Fe+4H_2O$
Ta có: $n_{H_2}=0,05.4=0,2(mol)\Rightarrow V_{H_2}=4,48(l)$
\(m_{Cu}=12g\Rightarrow n_{Cu}=\dfrac{12}{64}=0,1875mol\)
\(\Rightarrow m_{Fe}=m_{kl}-m_{Cu}=24-12=12g\Rightarrow n_{Fe}=\dfrac{3}{14}mol\)
\(CuO+H_2\rightarrow Cu+H_2O\)
\(\dfrac{12}{64}\) \(\dfrac{12}{64}\)
\(Fe_2O_3+3H_2\rightarrow2Fe+3H_2O\)
\(\dfrac{9}{28}\) \(\dfrac{3}{14}\)
\(\Rightarrow\Sigma n_{H_2}=\dfrac{12}{64}+\dfrac{9}{28}=\dfrac{57}{112}mol\)
\(\Rightarrow V_{H_2}=\dfrac{57}{112}\cdot22,4=11,4l\)
a)
\(Mg + H_2SO_4 \to MgSO_4 + H_2\\ n_{H_2} = n_{Mg} = \dfrac{3,6}{24} = 0,15(mol)\\ b)\\ CuO + H_2 \xrightarrow{t^o} Cu + H_2O\\ n_{Cu} = n_{H_2} = 0,15(mol)\\ \Rightarrow m_{Cu} = 0,15.64 = 9,6(gam)\)
\(a.n_{CuO}=\dfrac{40}{80}=0,5\left(mol\right)\\ n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\\ PTHH:CuO+H_2\underrightarrow{t^o}Cu+H_2O\\ Vì:\dfrac{0,15}{1}< \dfrac{0,5}{1}\\ \rightarrow CuOdư\\ n_{CuO\left(p.ứ\right)}=n_{Cu}=n_{H_2}=0,15\left(mol\right)\\ \rightarrow n_{CuO\left(dư\right)}=0,5-0,15=0,35\left(mol\right)\\ m_{CuO\left(DƯ\right)}=0,35.80=28\left(g\right)\\ b.m_{Cu}=0,35.64=22,4\left(g\right)\\ c.m_{hh_{rắn}}=m_{Cu}+m_{CuO\left(dư\right)}=22,4+28=50,4\left(g\right)\)
Bài 1.
\(n_{CuO}=\dfrac{48}{80}=0,6mol\)
\(CuO+H_2\rightarrow\left(t^o\right)Cu+H_2O\)
0,6 0,6 0,6 ( mol )
\(m_{Cu}=0,6.64=38,4g\)
\(V_{H_2}=0,6.22,4=13,44l\)
Bài 2.
\(n_{H_2}=\dfrac{5,6}{22,4}=0,25mol\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
0,25 0,5 0,25 ( mol )
\(m_{Fe}=0,25.56=14g\)
\(m_{HCl}=0,5.36,5=18,25g\)
\(CuO + H_2 \xrightarrow{t^o} Cu + H_2O\\ n_{H_2} = n_{CuO} = \dfrac{16}{80} = 0,2(mol)\\ \Rightarrow V_{H_2} = 0,2.22,4 = 4,48(lít)\)
Theo gt ta có: $n_{CuO}=0,2(mol)$
$CuO+H_2\rightarrow Cu+H_2O$
Ta có: $n_{H_2}=n_{CuO}=0,2(mol)\Rightarrow V_{H_2}=4,48(mol)$