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\(n_{Zn}=\dfrac{13}{65}=0.2\left(mol\right)\)
\(n_{HCl}=\dfrac{182.5\cdot10}{100\cdot36.5}=0.5\left(mol\right)\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(0.2......0.4..........0.2........0.2\)
\(n_{HCl\left(dư\right)}=0.5-0.4=0.1\left(mol\right)\)
\(m_{HCl\left(dư\right)}=0.1\cdot36.5=3.65\left(g\right)\)
\(V_{H_2}=0.2\cdot22.4=4.48\left(l\right)\)
\(m_{\text{dung dịch sau phản ứng}}=13+182.5-0.2\cdot2=195.1\left(g\right)\)
\(C\%_{HCl\left(dư\right)}=\dfrac{3.65}{195.1}\cdot100\%=1.87\%\)
\(C\%_{ZnCl_2}=\dfrac{0.2\cdot136}{195.1}\cdot100\%=13.94\%\)
\(n_{Zn}=\dfrac{13}{65}=0,2mol\)
\(n_{HCl}=\dfrac{18,25}{36,5}=0,5mol\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,2 0,5 0 0
0,2 0,4 0,2 0,2
0 0,1 0,2 0,2
Sau phản ứng, axit HCl còn dư và dư \(m=0,1\cdot36,5=3,65g\)
\(m_{ZnCl_2}=0,2\cdot136=27,2g\)
\(V_{H_2}=0,2\cdot22,4=4,48l\)
\(n_{H_2}=\dfrac{4.48}{22.4}=0.2\left(mol\right)\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(0.2.......0.4.......................0.2\)
\(m_{Zn}=0.2\cdot65=13\left(g\right)\)
\(C\%_{HCl}=\dfrac{0.4\cdot36.5}{200}\cdot100\%=7.3\%\)
\(n_{CuO}=\dfrac{24}{80}=0.3\left(mol\right)\)
\(CuO+H_2\underrightarrow{^{t^0}}Cu+H_2O\)
\(1..........1\)
\(0.3.........0.2\)
\(LTL:\dfrac{0.3}{1}>\dfrac{0.2}{1}\Rightarrow CuOdư\)
\(m_{CuO\left(dư\right)}=\left(0.3-0.2\right)\cdot64=6.4\left(g\right)\)
\(n_{Zn}=\dfrac{6.5}{65}=0.1\left(mol\right)\)
\(n_{HCl}=\dfrac{100\cdot14.6\%}{36.5}=0.4\left(mol\right)\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(1........2\)
\(0.1......0.4\)
\(LTL:\dfrac{0.1}{1}< \dfrac{0.4}{2}\Rightarrow HCldư\)
\(V_{H_2}=0.1\cdot22.4=2.24\left(l\right)\)
\(m_{\text{dung dịch sau phản ứng}}=6.5+100-0.1\cdot2=106.3\left(g\right)\)
\(C\%ZnCl_2=\dfrac{0.1\cdot136}{106.3}\cdot100\%=12.79\%\)
\(C\%HCl\left(dư\right)=\dfrac{\left(0.4-0.2\right)\cdot36.5}{106.3}\cdot100\%=6.87\%\%\)
\(n_{Zn}=\dfrac{8,125}{65}=0,125\left(mol\right)\\ m_{HCl}=\dfrac{100.18,25}{100}=18,25\left(g\right)\\
n_{HCl}=\dfrac{18,25}{36,5}=0,5\\ pthh:Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
0,125 0,125 (mol )
\(\Rightarrow V_{H_2}=0,125.22,4=2,8\left(l\right)\\
\)
\(C\%=\dfrac{8,125}{8,125+18,25}.100\%=30,8\%\)
Bài 18:
Ta có: \(n_{Zn}=\dfrac{8,125}{65}=0,125\left(mol\right)\)
\(m_{HCl}=100.18,25\%=18,25\left(g\right)\Rightarrow n_{HCl}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\)
a, PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
b, Xét tỉ lệ: \(\dfrac{0,125}{1}< \dfrac{0,5}{2}\), ta được HCl dư.
Theo PT: \(n_{H_2}=n_{Zn}=0,125\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,125.22,4=2,8\left(g\right)\)
\(m_{H_2}=0,125.2=0,25\left(g\right)\)
c, Theo PT: \(\left\{{}\begin{matrix}n_{ZnCl_2}=n_{Zn}=0,125\left(mol\right)\\n_{HCl\left(pư\right)}=2n_{Zn}=0,25\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{HCl\left(dư\right)}=0,25\left(mol\right)\)
Có: m dd sau pư = 8,125 + 100 - 0,25 = 107,875 (g)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{ZnCl_2}=\dfrac{0,125.136}{107,875}.100\%\approx15,76\%\\C\%_{HCl\left(dư\right)}=\dfrac{0,25.36,5}{107,875}.100\%\approx8,46\%\end{matrix}\right.\)
Bạn tham khảo nhé!
a) PTHH: \(BaCO_3+2HCl\rightarrow BaCl_2+H_2O+CO_2\uparrow\)
Ta có: \(\left\{{}\begin{matrix}n_{BaCO_3}=\dfrac{68,95}{197}=0,35\left(mol\right)\\n_{HCl}=0,25\cdot3,2=0,8\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,35}{1}< \dfrac{0,8}{2}\) \(\Rightarrow\) Axit còn dư
\(\Rightarrow n_{HCl\left(dư\right)}=0,8-0,35\cdot2=0,1\left(mol\right)\) \(\Rightarrow m_{HCl\left(dư\right)}=0,1\cdot36,5=3,65\left(g\right)\)
b+c) Theo PTHH: \(\left\{{}\begin{matrix}n_{CO_2}=n_{BaCl_2}=0,35\left(mol\right)\\n_{HCl\left(dư\right)}=0,1\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{CO_2}=0,35\cdot22,4=7,84\left(l\right)\\C_{M_{BaCl_2}}=\dfrac{0,35}{0,25}=1,4\left(M\right)\\C_{M_{HCl\left(dư\right)}}=\dfrac{0,1}{0,25}=0,4\left(M\right)\end{matrix}\right.\)
PTHH: \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\uparrow\)
Ta có: \(\left\{{}\begin{matrix}n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\\n_{H_2SO_4}=\dfrac{29,4}{98}=0,3\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,2}{1}< \dfrac{0,3}{1}\) \(\Rightarrow\) Zn p/ứ hết, H2SO4 còn dư
\(\Rightarrow\left\{{}\begin{matrix}n_{H_2SO_4\left(dư\right)}=0,1\left(mol\right)\\n_{H_2}=0,2\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{H_2SO_4}=0,1\cdot98=9,8\left(g\right)\\V_{H_2}=0,2\cdot22,4=4,48\left(l\right)\end{matrix}\right.\)
a. \(Mg+2HCl\rightarrow MgCl_2+H_2\)
b. \(n_{Mg}=\dfrac{2.4}{24}=0.1mol\)
\(mct_{HCl}=\dfrac{500\times36.5}{100}=182.5g\Rightarrow n_{HCl}=\dfrac{182.5}{36.5}=5mol\)
Ta có: \(\dfrac{0.1}{1}< \dfrac{5}{2}\Rightarrow\) HCl dư
nHCl phản ứng = 0.2 mol => nHCl dư = 5 - 0.2 = 4.8 mol
mHCl dư = \(4.8\times36.5=175.2g\)
c. \(V_{H_2}=0.1\times22.4=2.24l\)
d. mdd sau phản ứng = \(2.4+500-0.1\times2=502.2g\)
\(C\%_{MgCl_2}=\dfrac{0.1\times95\times100}{502.2}=1.89\%\)
nZn = 13/65 = 0,2 (mol)
mHCl = 182,5 . 10% = 18,25 (g)
nHCl = 18,25/36,5 = 0,25 (mol)
PTHH: Zn + 2HCl -> ZnCl2 + H2
LTL: 0,2 < 0,5/2 => HCl dư
nH2 = nZnCl2 = nZn = 0,2 (mol)
VH2 = 0,2 . 22,4 = 4,48 (l)
mH2 = 0,2 . 2 = 0,4 (g)
Chất tan: ZnCl2 và HCl dư
nHCl (p/ư) = 0,2 . 2 = 0,4 (mol)
mHCl (dư) = (0,5 - 0,4) . 36,5 = 3,65 (g)
mZnCl2 = 136 . 0,2 = 27,2 (g)
mdd (sau p/ư) = 182,5 + 13 - 0,4 = 195,1 (g)
C%HCl = 3,65/195,1 = 1,87%
C%ZnCl2 = 27,2/195,1 = 13,94%