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\(n_{H_2}=\dfrac{2.24}{22.4}=0.1\left(mol\right)\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(0.1.......0.2......................0.1\)
Chất rắn X : Cu
\(m_{Zn}=0.1\cdot65=6.5\left(g\right)\Rightarrow m_{Cu}=19.3-6.5=12.8\left(g\right)\)
\(n_{Cu}=\dfrac{12.8}{64}=0.2\left(mol\right)\)
\(C_{M_{HCl}}=\dfrac{0.2}{0.2}=1\left(M\right)\)
\(2Cu+O_2\underrightarrow{^{^{t^o}}}2CuO\)
\(0.2........0.1\)
\(m_{tăng}=m_{O_2}=0.1\cdot32=3.2\left(g\right)\)
a) PTHH: \(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
\(ZnO+2HCl\rightarrow ZnCl_2+H_2O\)
b) Ta có: \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)=n_{Zn}\) \(\Rightarrow n_{ZnO}=\dfrac{20-0,1\cdot65}{81}=\dfrac{1}{6}\left(mol\right)\)
\(\Rightarrow n_{ZnCl_2}=n_{Zn}+n_{ZnO}=\dfrac{4}{15}\left(mol\right)\)
Mặt khác: \(m_{H_2}=0,1\cdot2=0,2\left(g\right)\)
\(\Rightarrow m_{dd}=m_{hh}+m_{ddHCl}-m_{H_2}=119,8\left(g\right)\) \(\Rightarrow C\%_{ZnCl_2}=\dfrac{\dfrac{4}{15}\cdot136}{119,8}\cdot100\%\approx30,27\%\)
c) Giả sử khí là SO2
PTHH: \(Zn+H_2SO_{4\left(đ\right)}\xrightarrow[]{t^o}ZnSO_4+SO_2\uparrow+H_2O\)
Theo PTHH: \(n_{SO_2}=n_{Zn}=0,1\left(mol\right)\) \(\Rightarrow V_{SO_2}=0,1\cdot22,4=2,24\left(l\right)\)
a/ Fe + 2HCl \(\rightarrow\) FeCl2 + H2
nH2 = \(\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
Theo PTHH: nH2 = nFe = 0,15 (mol) \(\Rightarrow m_{Fe}=0,15.56=8,4\left(g\right)\)
\(\Rightarrow m_{Cu}=11-8,4=2,6\left(g\right)\)
\(\Rightarrow\%m_{Fe}=\dfrac{8,4}{11}.100\%\approx76,4\%\)
\(\Rightarrow\%m_{Cu}=100-76,4\approx23,6\%\)
b/ Theo PTHH ta có: nHCl = 2nFe = 2.0,15 = 0,3 (mol)
\(\Rightarrow V_{ddHCl}=\dfrac{0,3}{2}=0,15\left(M\right)\)
c/ mHCl = 36,5 . 0,3 = 10,95(g)
\(\Rightarrow C\%_{HCl}=\dfrac{m_{HCl}}{m_{ddHCl}}.100\%=\dfrac{10,95}{200}.100\%=5,475\%\)
a, PT: \(Fe+2HCl\rightarrow FeCl_2+H_2\)
Ta có: \(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
Theo PT: \(n_{Fe}=n_{H_2}=0,15\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{0,15.56}{11}.100\%\approx76,36\%\\\%m_{Cu}\approx23,64\%\end{matrix}\right.\)
b, Theo PT: \(n_{HCl}=2n_{H_2}=0,3\left(mol\right)\)
\(\Rightarrow V_{ddHCl}=\dfrac{0,3}{2}=0,15\left(l\right)\)
c, \(C\%_{HCl}=\dfrac{0,3.36,5}{200}.100\%=5,475\%\)
a) \(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
PTHH: Fe + 2HCl --> FeCl2 + H2
____0,15<--0,3<--------------0,15
=> mFe = 0,15.56 = 8,4 (g)
=> \(\left\{{}\begin{matrix}\%Fe=\dfrac{8,4}{21,2}.100\%=39,62\%\\\%Cu=\dfrac{21,2-8,4}{21,2}.100\%=60,38\%\end{matrix}\right.\)
b) mHCl = 0,3.36,5 = 10,95(g)
=> \(m_{ddHCl}=\dfrac{10,95.100}{3,65}.100\%=300\left(g\right)\)
a) Fe + 2HCl --> FeCl2 + H2
b) \(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
PTHH: Fe + 2HCl --> FeCl2 + H2
_____0,15<-0,3<----0,15<---0,15
\(\left\{{}\begin{matrix}\%Fe=\dfrac{0,15.56}{12}.100\%=70\%\%\\\%Cu=100\%-70\%=30\%\end{matrix}\right.\)
c) mHCl = 0,3.36,5 = 10,95 (g)
=> \(m_{dd}=\dfrac{10,95.100}{10}=109,5\left(g\right)\)
d) mdd = 12 + 109,5 - 0,15.2 = 121,2 (g)
\(C\%\left(FeCl_2\right)=\dfrac{0,15.127}{121,2}.100\%=15,718\%\)
C1:
nH2= 0,15(mol)
PTHH: Fe + 2 HCl-> FeCl2 + H2
0,15_____0,3______0,15___0,15(mol)
-> mFe= 0,15.56=8,4(g)
-> mCuO= 10-8,4=1,6(g)
b) -> nCuO= 0,02(mol)
PTHH: CuO +2 HCl -> CuCl2 + H2O
0,02_________0,04(mol)
c) nHCl (tổng)= 0,34(mol)
=> CMddHCl= 0,34/0,2=1,7(M)
C2:
a) Mg +2 HCl -> MgCl2 + H2
nH2= 0,2(mol) -> nMg= nMgCl2= nH2=0,2(mol); nHCl=0,4(mol)
mMg= 0,2.24=4,8(g) -> mCu= 5,2(g)
=> %mMg=(4,8/10).100=48%
=>%mCu= 100%-48%=52%
b) mMgCl2= 0,2.95=19(g)
mHCl=0,4.36,5=14,6(g) -> mddHCl= ?? Không cho C% sao tính ta