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Bảo toàn e :
nO2 = 2 .nH2 = 2 . 2,24 /22,4 = 0,2 (mol)
=> khối lượng oxit = 14,51+ 0,2 . 32 = 20,91 (g)
PT: \(2K+2H_2O\rightarrow2KOH+H_2\)
\(Ba+2H_2O\rightarrow Ba\left(OH\right)_2+H_2\)
\(4K+O_2\underrightarrow{t^o}2K_2O\)
\(2Ba+O_2\underrightarrow{t^o}2BaO\)
Giả sử: \(\left\{{}\begin{matrix}n_K=x\left(mol\right)\\n_{Ba}=y\left(mol\right)\end{matrix}\right.\)
Theo PT: \(\Sigma n_{H_2}=\dfrac{1}{2}n_K+n_{Ba}=\dfrac{1}{2}x+y\left(mol\right)\)
Mà: \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
\(\Rightarrow\dfrac{1}{2}x+y=0,1\Rightarrow\dfrac{1}{4}x+\dfrac{1}{2}y=0,05\left(1\right)\)
Theo PT: \(\Sigma n_{O_2}=\dfrac{1}{4}n_K+\dfrac{1}{2}n_{Ba}=\dfrac{1}{4}x+\dfrac{1}{2}y\left(mol\right)\)
\(\Rightarrow\Sigma n_{O_2}=0,05\left(mol\right)\)
Theo ĐLBT KL: \(a=m_{oxit}=m_X+m_{O_2}=14,51+0,05.32=16,11\left(g\right)\)
Bạn tham khảo nhé!
\(a,n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\\ PTHH:2K+2H_2O\rightarrow2KOH+H_2\uparrow\\ Theo.pt:n_K=2n_{H_2}=2.0,1=0,2\left(mol\right)\\ m_K=0,2.39=7,8\left(g\right)\\ m_{K_2O}=17,2-7,8=9,4\left(g\right)\\ b,n_{CuO\left(bđ\right)}=\dfrac{12}{80}=0,15\left(mol\right)\\ PTHH:CuO+H_2\underrightarrow{t^o}Cu+H_2O\\ LTL:0,15>0,1\Rightarrow Cu.dư\)
Gọi nCuO (pư) = a (mol)
=> nCu = a (mol)
mchất rắn sau pư = 80(0,15 - a) + 64a = 10,8
=> a = 0,075 (mol)
=> nH2 (pư) = 0,075 (mol)
\(H=\dfrac{0,075}{0,1}=75\%\)
\(n_{H_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\\ \left\{{}\begin{matrix}n_{Fe}=a\left(mol\right)\\n_{Al}=b\left(mol\right)\end{matrix}\right.\left(a,b>0\right)\\ Fe+2HCl\rightarrow FeCl_2+H_2\\ a.......2a........a...........a\left(mol\right)\\ 2Al+6HCl\rightarrow2AlCl_3+3H_2\\ b.........3b.........b........1,5b\left(mol\right)\\ \rightarrow\left\{{}\begin{matrix}56a+27b=22,2\\a+1,5b=0,6\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,3\\b=0,2\end{matrix}\right.\\ \%m_{FeCl_2}=\dfrac{0,3.127}{0,3.127+0,2.133,5}.100\approx58,796\%\\ \%m_{AlCl_3}\approx41,204\%\)
\(A: M, Fe\\ A+H_2SO_4 \to ASO_4+H_2\\ n_{H_2}=\frac{5,376}{22,4}=0,24(mol)\\ n_A=n_{H_2}=0,24(mol)\\ M_A=\frac{12}{0,24}=50(g/mol)\\ A+2HCl \to ACl_2+H_2\\ n_A=\frac{1}{2}.n_{HCl}=\frac{1}{2}.0,24=0,12(mol)\\ M_A=\frac{3,6}{0,12}=30(g/mol)\\ 30< A <50\\ a/ \\\Rightarrow A: Ca\\ b/ \\ Fe+H_2SO_4 \to FeSO_4+H_2\\ Ca+H_2SO_4 \to CaSO_4+H_2\\ n_{Fe}=a(mol)\\ n_{Ca}=b(mol)\\ m_{hh}=56a+40b=12(1)\\ n_{H_2}=a+b=0,24(mol)(2)\\ (1)(2)\\ a=0,15\\ b=0,09\\ \%m_{Fe}=\frac{0,15.56}{12}.100\%=70\%\\ \%m_{Ca}=100\%-70\%=30\% \)
Quy hỗn hợp X về : \(\left\{{}\begin{matrix}Na:x\left(mol\right)\\Ba:y\left(mol\right)\\O:z\left(mol\right)\end{matrix}\right.\)
BTe ta được : \(x+2y=2z+0,05.2\left(1\right)\)
BTKL : \(23x+137y+16z=21,9\left(2\right)\)
\(y=\dfrac{20,52}{171}=0,12\left(mol\right)\)
\(\Leftrightarrow\left\{{}\begin{matrix}x=0,14\\z=0,14\end{matrix}\right.\)
\(n_{NaOH}=0,14\Leftrightarrow a=0,14.40=5.6\left(g\right)\)
Bạn xem lại khối lượng của P2O5 nhé (Bài 1)
cs j sai à bn. đề đúng mà