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\(I,M_{hh}=M_{O_2}.0,3125=32.0,3125=10\left(\dfrac{g}{mol}\right)\\ Đặt:n_{N_2}=a\left(\%\right)\\ \Rightarrow\dfrac{28a+2\left(100\%-a\right)}{100\%}=10\\ \Leftrightarrow a\approx30,769\%=\%n_{N_2}=\%V_{N_2}\\ \Rightarrow\%V_{H_2}\approx69,231\%\\ II,Đặt:n_{N_2\left(thêm\right)}=k\left(mol\right)\\ n_{hh}=\dfrac{29,12}{22,4}=1,3\left(mol\right)\\ M_{hh.khí.mới}=M_{O_2}.0,46875=32.0,46875=15\left(\dfrac{g}{mol}\right)\\ \Leftrightarrow\dfrac{\left(k+0,13.0,30769\right).28+2.0,69231}{k+0,13}=15\\ \Leftrightarrow k=\left(ra.âm\right)\)
Nói chung làm được ý 1, anh thấy ý 2 ra âm. Em xem lại đề nha
Bài 1.
Gọi \(\left\{{}\begin{matrix}n_{N_2}=x\left(mol\right)\\n_{H_2}=y\left(mol\right)\end{matrix}\right.\)
\(\dfrac{d_{N_2,H_2}}{M_{O_2}}=0,3125\Rightarrow d_{N_2,H_2}=0,3125\cdot32=10\)
Sơ đồ chéo:
\(N_2\) 28 8
\(10\)
\(H_2\) 2 18
\(\Rightarrow\dfrac{N_2}{H_2}=\dfrac{x}{y}=\dfrac{8}{18}=\dfrac{4}{9}\)\(\Rightarrow9x-4y=0\left(1\right)\)
Mà \(x+y=\dfrac{29,12}{22,4}=1,3\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=0,4\\y=0,9\end{matrix}\right.\)
\(\%V_{N_2}=\dfrac{0,4}{0,4+0,9}\cdot100\%=30,77\%\)
\(\%V_{H_2}=100\%-30,77\%=69,23\%\)
\(a.\)
\(GS:\)
\(n_{hh}=1\left(mol\right)\)
\(Đặt:n_{N_2}=a\left(mol\right),n_{CO_2}=b\left(mol\right)\)
\(\Rightarrow a+b=1\left(1\right)\)
\(m_A=28a+44b=18\cdot2=36\left(2\right)\)
\(\left(1\right),\left(2\right):\)
\(a=b=0.5\)
\(\%m_{N_2}=\dfrac{0.5\cdot28}{0.5\cdot28+0.5\cdot44}\cdot100\%=38.89\%\)
\(\%m_{CO_2}=61.11\%\)
\(b.\)
\(\dfrac{n_{N_2}}{n_{CO_2}}=\dfrac{0.5}{0.5}=\dfrac{1}{1}\)
\(n_{N_2}=n_{CO_2}=\dfrac{1}{2}\cdot n_A=\dfrac{0.2}{2}=0.1\left(mol\right)\)
\(Đặt:n_{CO_2}=x\left(mol\right)\)
\(\overline{M}=\dfrac{0.1\cdot28+0.1\cdot44+44x}{0.2+x}=20\cdot2=40\left(\dfrac{g}{mol}\right)\)
\(\Rightarrow x=0.2\)
\(m_{CO_2\left(cầnthêm\right)}=0.2\cdot44=8.8\left(g\right)\)
a. Ta có: \(\overline{M_{hh}}=\dfrac{28.1+2.3}{1+3}=8,5\left(g\right)\)
=> \(d_{\dfrac{hh}{O_2}}=\dfrac{\overline{M_{hh}}}{M_{O_2}}=\dfrac{8,5}{32}=0,265626\left(lần\right)\)
b. Ta có: \(V_{N_2}=1.22,4=22,4\left(lít\right)\)
\(V_{H_2}=3.22,4=67,2\left(lít\right)\)
=> \(\%_{V_{N_2}}=\dfrac{22,4}{22,4+67,2}.100\%=25\%\)
\(\%_{V_{H_2}}=100\%-25\%=75\%\)
Ta có: \(m_{N_2}=1.28=28\left(g\right)\)
\(m_{H_2}=3.2=6\left(g\right)\)
=> \(\%_{m_{N_2}}=\dfrac{28}{28+6}.100\%=82,35\%\)
\(\%_{m_{H_2}}=100\%-82,35\%=17,65\%\)
Giả sử có 1 mol khí Cl2, 2 mol khí O2
a) \(\left\{{}\begin{matrix}\%V_{Cl_2}=\dfrac{1}{1+2}.100\%=33,33\%\\\%V_{O_2}=\dfrac{2}{1+2}.100\%=66,67\%\end{matrix}\right.\)
\(\left\{{}\begin{matrix}\%m_{Cl_2}=\dfrac{1.71}{1.71+2.32}.100\%=52,59\%\\\%m_{O_2}=\dfrac{2.32}{1.71+2.32}.100\%=47,41\%\end{matrix}\right.\)
b) \(\overline{M}=\dfrac{1.71+2.32}{1+2}=45\left(g/mol\right)\)
=> \(d_{A/H_2}=\dfrac{45}{2}=22,5\)
c) \(n_A=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
=> mA = 0,3.45 = 13,5 (g)
Có \(\left\{{}\begin{matrix}n_{H_2}+n_{C_2H_2}=\dfrac{17,92}{22,4}=0,8\\\dfrac{2.n_{H_2}+26.n_{C_2H_2}}{n_{H_2}+n_{C_2H_2}}=0,5.28=14\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}n_{H_2}=0,4\left(mol\right)\\n_{C_2H_2}=0,4\left(mol\right)\end{matrix}\right.\)
\(n_{O_2}=\dfrac{51,2}{32}=1,6\left(mol\right)\)
PTHH: 2H2 + O2 --to--> 2H2O
0,4-->0,2
2C2H2 + 5O2 --to--> 4CO2 + 2H2O
0,4----->1------------>0,8
=> Y chứa \(\left\{{}\begin{matrix}CO_2:0,8\left(mol\right)\\O_{2\left(dư\right)}:0,4\left(mol\right)\end{matrix}\right.\)
=> \(\overline{M}_Y=\dfrac{0,8.44+0,4.32}{0,8+0,4}=40\left(g/mol\right)\)
\(\overline{M}_X=14\left(g/mol\right)\)
=> \(d_{X/Y}=\dfrac{14}{40}=0,35\)
a)
Gọi $n_{CO} = a ; n_{NO} = b$
Ta có :
$28a + 30b = (a + b). $\dfrac{103}{14}.4$
$\Rightarrow \dfrac{10}{7}a = \dfrac{4}{7}b$
$\Rightarrow \dfrac{a}{b} = \dfrac{2}{5}(1)$
b)
$28a + 30b = 20,6(2)$
Từ (1)(2) suy ra a = 0,2 ;b = 0,5
$n_{O_2} = 0,5(mol)$
2CO + O2 \(\xrightarrow{t^o}\) 2CO2
0,2..........0,1............0,2........(mol)
2NO + O2 \(\xrightarrow{t^o}\) 2NO2
0,5.........0,25...........0,5............(mol)
Sau phản ứng, B gồm :
CO2 : 0,2 mol
NO2 : 0,5 mol
O2 dư : 0,5 - 0,25 - 0,1 = 0,15(mol)
$n_{hh} = 0,2 + 0,5 + 0,15 = 0,85\ mol$
$\%n_{CO_2} = \dfrac{0,2}{0,85}.100\% = 23,53\%$
$\%n_{NO_2} = \dfrac{0,5}{0,85} .100\% = 58,82\%$
$\%n_{O_2\ dư} = 17,65\%$
Bảo toàn khối lượng : $m_B = m_A + m_{O_2} = 20,6 + 0,5.32 = 36,6(gam)$
$M_B = \dfrac{36,6}{0,85} = 43,06(g/mol)$
$d_{B/He} = \dfrac{43,06}{4} = 10,765$
a) \(M_A=\dfrac{103}{14}.4=\dfrac{206}{7}\)
Lập sơ đồ đường chéo :
=> \(\dfrac{n_{CO}}{n_{NO}}=\dfrac{30-\dfrac{206}{7}}{\dfrac{206}{7}-28}=\dfrac{2}{5}\)
b)Gọi x, y lần lượt là số mol CO, NO
=> \(\left\{{}\begin{matrix}28x+30y=20,6\\\dfrac{x}{y}=\dfrac{2}{5}\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}x=0,2\\y=0,5\end{matrix}\right.\)
\(n_{O_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
2CO + O2 → 2CO2
0,2---->0,1---->0,2
2NO + O2 → 2NO2
0,5---->0,25--->0,5
=> Hỗn hợp khí B gồm : \(\left\{{}\begin{matrix}O_{2\left(dư\right)}=0,5-\left(0,1+0,25\right)=0,15\left(mol\right)\\n_{CO_2}=0,2\left(mol\right)\\n_{NO_2}=0,5\left(mol\right)\end{matrix}\right.\)
=> \(M_B=\dfrac{0,15.32+0,2.44+0,5.46}{0,15+0,2+0,5}=\dfrac{732}{17}\)
dB/He= \(\dfrac{732}{17}:4=\dfrac{183}{17}\approx10,77\)
\(n_{hhA}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\Rightarrow m_{hhA}=0,2.30=6\left(g\right)\)
\(\Rightarrow\left\{{}\begin{matrix}x+y=0,2\\28x+32y=6\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,2-y\\28.\left(0,2-y\right)+32y=6\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,1\\y=0,1\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{N_2}=0,1.28=2,8\left(g\right)\\m_{O_2}=6-2,8=3,2\left(g\right)\end{matrix}\right.\)
Mình làm mẫu một ý nha:
a, Gọi hh SO2 và H2 là X; O2 và N2 là Y
\(\Rightarrow\left\{{}\begin{matrix}\left\{{}\begin{matrix}m_X=0,02.64+0,5.2=2,28\left(g\right)\\n_X=0,02+0,5=0,52\left(mol\right)\end{matrix}\right.\\\left\{{}\begin{matrix}m_Y=0,2.32+0,5.28=20,4\left(g\right)\\n_Y=0,2+0,5=0,7\left(mol\right)\end{matrix}\right.\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}M_X=\dfrac{2,28}{0,52}=4,4\left(\dfrac{g}{mol}\right)\\M_Y=\dfrac{20,4}{0,7}=29,1\left(\dfrac{g}{mol}\right)\end{matrix}\right.\)
\(\Rightarrow d_{X/Y}\)\(=\dfrac{4,4}{29,1}=0,15\)
bạn cho mình hỏi CH4 nặng hay nhẹ hơn không khí vậy ạ,cách tính sao ạ?
bạn chupj lại đc ko ạ