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\(M_X=2,5.16=40\)(g/mol)
\(\rightarrow\dfrac{V_{CO_2}}{V_{O_2}}=\dfrac{n_{CO_2}}{n_{O_2}}=\dfrac{40-32}{44-40}=2\)
Mà \(V_{CO_2}+V_{O_2}=30\left(L\right)\)
\(\rightarrow V_{CO_2}=20\left(L\right);V_{O_2}=10\left(L\right)\)
\(\rightarrow M_Y=\dfrac{20.44+10.32+32V}{V+20+10}=2,25.16=36\)
\(\rightarrow V=30\left(L\right)\)
\(M_{hh}=22,4.2=44,8\left(g/mol\right);n_{hh}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\\ \Rightarrow m_{hh}=0,25.44,8=11,2\left(g\right)\)
Đặt \(n_{O_2\left(th\text{ê}m\right)}=a\left(mol\right)\left(a>0\right)\)
\(M_{hh\left(m\text{ới}\right)}=20.2=40\left(g/mol\right)\)
Ta có: \(\left\{{}\begin{matrix}m_{hh\left(m\text{ới}\right)}=11,2+32a\left(g\right)\\n_{hh\left(m\text{ới}\right)}=0,25+a\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow M_{hh\left(m\text{ới}\right)}=\dfrac{11,2+32a}{0,25+a}=40\Leftrightarrow a=0,15\left(mol\right)\left(TM\right)\)
\(\Rightarrow V_{O_2}=0,15.22,4=3,36\left(l\right)\)
a) \(M_X=19.2=38\left(g/mol\right)\)
`=>` \(d_{X/kk}=\dfrac{38}{29}=1,310345\)
b) \(m_X=0,4.38=15,2\left(g\right)\)
Gọi \(\left\{{}\begin{matrix}n_{O_2}=x\left(mol\right)\\n_{CO_2}=y\left(mol\right)\end{matrix}\right.\)
`=>` \(\left\{{}\begin{matrix}32x+44y=15,2\\x+y=0,4\end{matrix}\right.\Leftrightarrow x=y=0,2\)
\(m_Y=0,1.28+15,2=18\left(g\right)\)
`=>` \(\left\{{}\begin{matrix}\%m_{N_2}=\dfrac{0,1.28}{18}.100\%=15,56\%\\\%m_{O_2}=\dfrac{0,2.32}{18}.100\%=35,56\%\\\%m_{CO_2}=100\%-15,56\%-35,56\%=48,88\%\end{matrix}\right.\)
b) \(M_{hh}=4.10=40\left(g/mol\right)\)
Gọi \(n_{NO_2}=a\left(mol\right)\)
`=>` \(\left\{{}\begin{matrix}m_{hh}=18+46a\left(g\right)\\n_{hh}=0,5+0,1+a=0,6+a\left(mol\right)\end{matrix}\right.\)
`=>` \(M_{hh}=\dfrac{m_{hh}}{n_{hh}}=\dfrac{18+46a}{0,6+a}=40\)
`=> a = 1`
`=> V_{NO_2(đktc)} = 1.22,4 = 22,4 (l)`
$\%m_{O_2(X)}=\dfrac{1,6}{1,6+4,4}.100\%=26,67\%$
$n_{CO_2}=\dfrac{4,4}{44}=0,1(mol);n_{O_2}=\dfrac{1,6}{16}=0,05(mol)$
$\Rightarrow \%V_{O_2(X)}=\dfrac{0,05}{0,05+0,1}.100\%=33,33\%$
$C+O_2\xrightarrow{t^o}CO_2$
Theo PT: $n_C=n_{O_2(p/ứ)}=n_{CO_2}=0,1(mol)$
$\Rightarrow n_{O_2(dùng)}=0,1+0,05=0,15(mol)$
$m_C=0,1.12=1,2(g);V_{O_2(dùng)}=0,15.22,4=3,36(lít)$
$\to m=1,2;V=3,36$
Gọi $n_{O_2} = 1(mol) \to n_{N_2} = 3(mol)$
Ta có :
$M_Y = \dfrac{32.1 + 28.3}{1 + 3} = 29(g/mol)$
Vì $M_{CO} = M_{C_2H_4} = 28$ nên $M_Z = 28$
Ta có :
$d_{Y/Z} = \dfrac{29}{28} = 1,036$