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Gọi số mol của C2H4 và C2H2 lần lượt là x và y mol
theo bài ra: x+y = 0,56/22,4 = 0,025 (mol)
Pt:
C2H4 + Br2 → C2H4Br2
x mol x mol x mol
C2H2 + 2 Br2 → C2H2Br4
y mol 2y mol y mol
Số mol n Br2 = x+2y = 5,6/160 = 0,035 9mol)
Giải hệ ta đc: x = 0,015 và y = 0,01
=> %V C2H4 = 0,015/0,025 = 60% ; %V C2H2 = 40%
a, \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
b, Ta có: \(n_{C_2H_4}+n_{C_2H_2}=\dfrac{0,56}{22,4}=0,025\left(mol\right)\) (1)
Theo PT: \(n_{Br_2}=n_{C_2H_4}+2n_{C_2H_2}=\dfrac{5,6}{160}=0,035\left(mol\right)\) (2)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{C_2H_4}=0,015\left(mol\right)\\n_{C_2H_2}=0,01\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{C_2H_4}=0,015.28=0,42\left(g\right)\\m_{C_2H_2}=0,01.26=0,26\left(g\right)\end{matrix}\right.\)
c, \(CaC_2+2H_2O\rightarrow Ca\left(OH\right)_2+C_2H_2\)
Theo PT: \(n_{CaC_2}=n_{C_2H_2}=0,01\left(mol\right)\Rightarrow m_{CaC_2}=0,01.64=0,64\left(g\right)\)
Bài 3
a) C2H4 + Br2 --> C2H4Br2
C2H2 + 2Br2 --> C2H2Br4
b) \(n_{Br_2}=\dfrac{5,6}{160}=0,035\left(mol\right)\)
Gọi số mol C2H4, C2H2 là a, b (mol)
=> \(a+b=\dfrac{0,56}{22,4}=0,025\) (1)
PTHH: C2H4 + Br2 --> C2H4Br2
a---->a
C2H2 + 2Br2 --> C2H2Br4
b---->2b
=> a + 2b = 0,035 (2)
(1)(2) => a = 0,015 (mol); b = 0,01 (mol)
=> \(\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,015}{0,025}.100\%=60\%\\\%V_{C_2H_2}=\dfrac{0,01}{0,025}.100\%=40\%\end{matrix}\right.\)
Bài 4:
a)
CH4 + 2O2 --to--> CO2 + 2H2O
2H2 + O2 --to--> 2H2O
b)
Gọi số mol CH4, H2 là a, b (mol)
=> \(a+b=\dfrac{11,2}{22,4}=0,5\) (1)
PTHH: CH4 + 2O2 --to--> CO2 + 2H2O
a-------------------->a--->2a
2H2 + O2 --to--> 2H2O
b--------------->b
=> \(2a+b=\dfrac{16,2}{18}=0,9\) (2)
(1)(2) => a = 0,4 (mol); b = 0,1 (mol)
=> \(\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{0,4}{0,5}.100\%=80\%\\\%V_{H_2}=\dfrac{0,1}{0,5}.100\%=20\%\end{matrix}\right.\)
c)
VCO2 = 0,4.22,4 = 8,96 (l)
PT: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
Ta có: \(n_{C_2H_4}+n_{C_2H_2}=\dfrac{0,56}{22,4}=0,025\left(mol\right)\left(1\right)\)
Theo PT: \(n_{Br_2}=n_{C_2H_4}+n_{C_2H_2}=\dfrac{6,4}{160}=0,04\left(mol\right)\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{C_2H_4}=0,01\left(mol\right)\\n_{C_2H_2}=0,015\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,01.22,4}{0,56}.100\%=40\%\\\%V_{C_2H_2}=60\%\end{matrix}\right.\)
a, PT: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
Giả sử: \(\left\{{}\begin{matrix}n_{C_2H_4}=x\left(mol\right)\\n_{C_2H_2}=y\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow x+y=\dfrac{1,344}{22,4}=0,06\left(1\right)\)
Ta có: \(n_{Br_2}=\dfrac{16}{160}=0,1\left(mol\right)\)
Theo PT: \(n_{Br_2}=n_{C_2H_4}+2n_{C_2H_2}=x+2y\left(mol\right)\)
⇒ x + 2y = 0,1 (2)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=0,02\left(mol\right)\\y=0,04\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,02}{0,06}.100\%\approx33,33\%\\\%\text{ }V_{C_2H_2}\approx66,67\%\end{matrix}\right.\)
b, Ta có: 1/2 hỗn hợp khí gồm: 0,01 mol C2H4 và 0,02 mol C2H2.
PT: \(C_2H_4+3O_2\underrightarrow{t^o}2CO_2+2H_2O\)
\(2C_2H_2+5O_2\underrightarrow{t^o}4CO_2+2H_2O\)
Theo PT: \(n_{CO_2}=2n_{C_2H_4}+2n_{C_2H_2}=0,06\left(mol\right)\)
\(CO_2+Ca\left(OH\right)_2\rightarrow CaCO_{3\downarrow}+H_2O\)
Theo PT: \(n_{CaCO_3}=n_{CO_2}=0,06\left(mol\right)\)
\(\Rightarrow m_{cr}=m_{CaCO_3}=0,06.100=6\left(g\right)\)
Bạn tham khảo nhé!
\(Gọi : n_{C_2H_4} = a; n_{C_2H_2} = b\\ \Rightarrow a + b = \dfrac{5,6}{22,4} = 0,25(1)\\ C_2H_4 + Br_2 \to C_2H_4Br_2\\ C_2H_2 + 2Br_2 \to C_2H_2Br_4\\ n_{Br_2} = a + 2b = \dfrac{56}{160} =0,35(2)\\ (1)(2)\Rightarrow a = 0,15 ; b = 0,1\\ \Rightarrow \%V_{C_2H_4} = \dfrac{0,15}{0,25} .100\% = 60\%\\ \%V_{C_2H_2} = 100\% -60\% = 40\%\)
C2H4+Br2->C2H4Br2
x----------x---------x
C2H2+2Br2->C2H2Br4
y--------2y------------y
=>\(\left\{{}\begin{matrix}x+y=\dfrac{0,896}{22,4}\\160x+320y=8\end{matrix}\right.\)
=>x=0,03 mol, y=0,01 mol
=>%VC2H4=\(\dfrac{0,03.22,4}{0,896}\).100=75%
=>%VC2H2=25%
\(\left\{{}\begin{matrix}C_2H_4:x\left(mol\right)\\C_2H_2:y\left(mol\right)\end{matrix}\right.\)⇒ x + y = \(\dfrac{6,72}{22,4}=0,3\left(1\right)\)
\(C_2H_4 + Br_2 \to C_2H_4Br_2\\ C_2H_2 + 2Br_2 \to C_2H_2Br_4\)
Theo PTHH :
x + 2y = \(\dfrac{64}{160} = 0,4(2)\)
Từ (1)(2) suy ra: x = 0,2 ; y = 0,1
Vậy :
\(\%V_{C_2H_4} = \dfrac{0,2}{0,3}.100\% = 66,67\%\\ \%V_{C_2H_2} = 100\% - 66,67\% = 33,33\%\)
\(n_{CO_2}=0.3\left(mol\right)\)
\(Đặt:n_{C_2H_2}=a\left(mol\right),n_{C_2H_4}=b\left(mol\right)\)
\(n_{Br_2}=\dfrac{64}{160}=0.4\left(mol\right)\)
\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
\(\left\{{}\begin{matrix}a+b=0.3\\2a+b=0.4\end{matrix}\right.\)
\(\Leftrightarrow\left\{{}\begin{matrix}a=0.1\\b=0.2\end{matrix}\right.\)
\(\%V_{C_2H_2}=\dfrac{0.1}{0.3}\cdot100\%=33.33\%\)
\(\%V_{C_2H_4}=66.67\%\)
Bài 1 :
\(n_{hỗn.hợp.khí}=\dfrac{0,56}{22,4}=0,025\left(mol\right)\)
\(n_{Br2}=\dfrac{5,6}{160}=0,035\left(mol\right)\)
a) Pt : \(C_2H_4+Br_2\rightarrow C_2H_4Br_2|\)
1 1 1
a 1a
\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4|\)
1 2 1
b 2b
Ta có hệ phương trình :
a + b = 0,025
1a + 2b = 0,035
⇒ \(\left\{{}\begin{matrix}a=0,015\\b=0,01\end{matrix}\right.\)
b) 0/0VC2H4 = \(\dfrac{0,015.100}{0,025}=60\)0/0
0/0VC2H2 = \(\dfrac{0,01.100}{0,025}=40\)0/0
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