hòa tan hoàn toàn 20 gam canxi cacbonat vào dd HCL 14,6%.hãy tính
a.khối lượng đ HCL 14,6% phải dùng
b.thể tích khí(đktc)thoát ra
c.nồng độ phần trăm chất tan trong dung dịch sau phản ứng
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a) \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\); \(n_{HCl}=\dfrac{200.14,6\%}{36,5}=0,8\left(mol\right)\)
PTHH: 2Al + 6HCl --> 2AlCl3 + 3H2
Xét tỉ lệ: \(\dfrac{0,2}{2}< \dfrac{0,8}{6}\) => Al hết, HCl dư
PTHH: 2Al + 6HCl --> 2AlCl3 + 3H2
0,2-->0,6---->0,2----->0,3
=> VH2 = 0,3.22,4 = 6,72 (l)
b) \(\left\{{}\begin{matrix}m_{AlCl_3}=0,2.133,5=26,7\left(g\right)\\m_{HCl\left(dư\right)}=\left(0,8-0,6\right).36,5=7,3\left(g\right)\end{matrix}\right.\)
=> mchất tan = 26,7 + 7,3 = 34 (g)
c) mdd sau pư = 5,4 + 200 - 0,3.2 = 204,8 (g)
\(\left\{{}\begin{matrix}C\%_{AlCl_3}=\dfrac{26,7}{204,8}.100\%=13,04\%\\C\%_{HCl\left(dư\right)}=\dfrac{7,3}{204,8}.100\%=3,56\%\end{matrix}\right.\)
\(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\\ pthh:2Al+6HCl\rightarrow2AlCl_3+3H_2\)
0,2 0,2 0,3
\(V_{H_2}=0,3.22,4=6,72L\\ m_{AlCl_3}=133,5.0,2=26,7g\\ m_{\text{dd}}=5,4+200-\left(0,3.2\right)=204,8g\\ C\%=\dfrac{26,7}{204,8}.100\%=13\%\)
\(a,n_{Fe}=\dfrac{11,2}{56}=0,2(mol)\\ PTHH:Fe+2HCl\to FeCl_2+H_2\\ \Rightarrow n_{HCl}=0,4(mol)\\ \Rightarrow m_{dd_{HCl}}=\dfrac{0,4.36,5}{14,6\%}=100(g)\\ b,n_{H_2}=0,2(mol)\\ \Rightarrow V_{H_2}=0,2.22,4=4,48(l)\\ c,n_{FeCl_2}=0,2(mol)\\ \Rightarrow C\%_{FeCl_2}=\dfrac{0,2.127}{11,2+100-0,2.2}.100\%\approx 22,93\%\)
a, \(m_{HCl}=200.14,6\%=29,2\left(g\right)\Rightarrow n_{HCl}=\dfrac{29,2}{36,5}=0,8\left(mol\right)\)
PTHH: Zn + 2HCl → ZnCl2 + H2
Mol: 0,4 0,8 0,4 0,4
\(V_{H_2}=0,4.22,4=8,96\left(l\right)\)
b, \(m_{Zn}=0,4.65=26\left(g\right)\)
c, mdd sau pứ = 26 + 200 - 0,4.2 = 225,2 (g)
\(C_{M_{ddZnCl_2}}=\dfrac{0,4.136.100\%}{225,2}=24,16\%\)
a, \(m_{HCl}=150.14,6\%=21,9\left(g\right)\Rightarrow n_{HCl}=\dfrac{21,9}{36,5}=0,6\left(mol\right)\)
PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
Theo PT: \(n_{Zn}=n_{ZnCl_2}=n_{H_2}=\dfrac{1}{2}n_{HCl}=0,3\left(mol\right)\)
\(\Rightarrow m_{Zn}=0,3.65=19,5\left(g\right)\)
b, \(V_{H_2}=0,3.22,4=6,72\left(l\right)\)
c, Ta có: m dd sau pư = 19,5 + 150 - 0,3.2 = 168,9 (g)
\(\Rightarrow C\%_{ZnCl_2}=\dfrac{0,3.136}{168,9}.100\%\approx24,16\%\)
1: \(n_{Zn}=\dfrac{3.25}{65}=0.05\left(mol\right)\)
a: \(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
0,05 0,1 0,05 0,05
\(m_{dd\left(HCl\right)}=0.1\cdot36.5=3.65\left(g\right)\)
b: \(V_{H_2}=0.05\cdot22.4=1.12\left(lít\right)\)
2)
H3PO4 (axit yếu) : axit photphoric
Zn3(PO4)2 (muối) : kẽm photphat
Fe2(SO4)3 (muối) : sắt (III) sunfat
SO2 (oxit axit) : lưu huỳnh đioxit
SO3 (oxit axit) : lưu huỳnh trioxit
P2O5 (oxit axit) : đi photpho pentaoxit
HCl(axit mạnh) : axit clohidric
Ca(HCO3)2 (muối axit) : canxi hidrocacbonat
Ca(H2PO4)2 (muối aixt) : canxi đihidrophotphat
Fe2O3 (oxit bazơ) : sắt (III) oxit
Cu(OH)2 (bazơ) : đống(II) hidroxit
NaH2PO4 (muối axit) : natri đihidrophotphat
Chúc bạn học tốt
\(n_{Zn}=\dfrac{26}{65}=0,4\left(mol\right)\)
Pt : \(Zn+2HCl\rightarrow ZnCl_2+H_2|\)
1 2 1 1
0,4 0,8 0,4 0,4
a) \(n_{H2}=\dfrac{0,4.1}{1}=0,4\left(mol\right)\)
\(V_{H2\left(dktc\right)}=0,4.22,4=8,96\left(l\right)\)
b) \(n_{HCl}=\dfrac{0,4.2}{1}=0,8\left(mol\right)\)
⇒ \(m_{HCl}=0,8.36,5=29,2\left(g\right)\)
\(m_{ddHCl}=\dfrac{29,2.100}{14,6}=200\left(g\right)\)
c) \(n_{ZnCl2}=\dfrac{0,4.1}{1}=0,4\left(mol\right)\)
⇒ \(m_{ZnCl2}=0,4.136=54,4\left(g\right)\)
\(m_{ddspu}=26+200-\left(0,4.2\right)=225,2\left(g\right)\)
\(C_{ZnCl2}=\dfrac{54,4.100}{225,2}=24,16\)0/0
Chúc bạn học tốt
a, \(n_{Zn}=\dfrac{19,5}{65}=0,3\left(mol\right)\)
\(m_{HCl}=200.14,6\%=29,2\left(g\right)\Rightarrow n_{HCl}=\dfrac{29,2}{36,5}=0,8\left(mol\right)\)
PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
Xét tỉ lệ: \(\dfrac{0,3}{1}< \dfrac{0,8}{2}\), ta được HCl dư.
Theo PT: \(n_{H_2}=n_{Zn}=0,3\left(mol\right)\Rightarrow V_{H_2}=0,3.22,4=6,72\left(l\right)\)
b, \(n_{ZnCl_2}=n_{Zn}=0,3\left(mol\right)\Rightarrow m_{ZnCl_2}=0,3.136=40,8\left(g\right)\)
c, \(n_{HCl\left(pư\right)}=2n_{Zn}=0,6\left(mol\right)\Rightarrow n_{HCl\left(dư\right)}=0,2\left(mol\right)\)
Ta có: m dd sau pư = 19,5 + 200 - 0,3.2 = 218,9 (g)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{HCl}=\dfrac{0,2.36,5}{218,9}.100\%\approx3,33\%\\C\%_{ZnCl_2}=\dfrac{40,8}{218,9}.100\%\approx18,64\%\end{matrix}\right.\)
\(a)n_{Zn}=\dfrac{19,5}{65}=0,3mol\\ n_{HCl}=\dfrac{200.14,6}{100.36,5}=0,8mol\\ Zn+2HCl\rightarrow ZnCl_2+H_2\\ \Rightarrow\dfrac{0,3}{1}< \dfrac{0,8}{2}\Rightarrow HCl.dư\\ n_{H_2}=n_{ZnCl_2}=n_{Zn}=0,3mol\\ V_{H_2}=0,3.22,4=6,72l\\ b)m_{ZnCl_2}=0,3.136=40,8g\\ c)n_{HCl.pư}=0,3.2=0,6mol\\ C_{\%ZnCl_2}=\dfrac{40,8}{200+19,5-0,3.2}\cdot100=18,64\%\\ C_{\%HCl.dư}=\dfrac{\left(0,8-0,6\right).36,5}{200+19,5-0,3.2}\cdot100=3,33\%\)
a) $CaSO_3 + 2HCl \to CaCl_2 + SO_2 + H_2O$
b)
$n_{SO_2} = n_{CaSO_3} = \dfrac{12}{120} = 0,1(mol)$
$m_{SO_2} = 0,1.64 = 6,4(gam)$
c)
$n_{HCl} = 2n_{SO_2} = 0,2(mol)$
$\Rightarrow m_{dd\ HCl} = \dfrac{0,2.36,5}{14,6\%} = 50(gam)$
d)
$m_{dd\ sau\ pư} = m_{CaSO_3} + m_{dd\ HCl} - m_{SO_2} = 12 + 50 - 6,4 = 55,6(gam)$
$C\%_{CaCl_2} = \dfrac{0,1.111}{55,6}.100\% = 19,96\%$
Ta có: \(n_{CaSO_3}=\dfrac{12}{120}=0,1\left(mol\right)\)
a. PTHH: CaSO3 + 2HCl ---> CaCl2 + H2O + SO2
b. Theo PT: \(n_{SO_2}=n_{CaSO_3}=0,1\left(mol\right)\)
=> \(m_{SO_2}=0,1.64=6,4\left(g\right)\)
c. Theo PT: \(n_{HCl}=2.n_{CaSO_3}=2.0,1=0,2\left(mol\right)\)
=> \(m_{HCl}=0,2.36,5=7,3\left(g\right)\)
Ta có: \(C_{\%_{HCl}}=\dfrac{7,3}{m_{dd_{HCl}}}.100\%=14,6\%\)
=> \(m_{dd_{HCl}}=50\left(g\right)\)
d. Ta có: \(m_{dd_{CaCl_2}}=12+50-0,1.64=55,6\left(g\right)\)
Theo PT: \(n_{CaCl_2}=n_{SO_2}=0,1\left(mol\right)\)
=> \(m_{CaCl_2}=0,1.111=11,1\left(g\right)\)
=> \(C_{\%_{CaCl_2}}=\dfrac{11,1}{55,6}.100\%=19,96\%\)
Ta có: \(n_{CaCO_3}=\dfrac{20}{100}=0,2\left(mol\right)\)
PT: \(CaCO_3+2HCl\rightarrow CaCl_2+CO_2+H_2O\)
______0,2_______0,4_____0,2____0,2 (mol)
a, \(m_{ddHCl}=\dfrac{0,4.36,5}{14,6\%}=100\left(g\right)\)
b, \(V_{CO_2}=0,2.22,4=4,48\left(l\right)\)
c, m dd sau pư = 20 + 100 - 0,2.44 = 111,2 (g)
\(\Rightarrow C\%_{CaCl_2}=\dfrac{0,2.111}{111,2}.100\%\approx19,96\%\)