Tính nồng độ mol của 250 ml dung dịch có hòa tan 9,8 gam H2SO4.
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`C1:`
`2NaOH+H_2 SO_4 ->Na_2 SO_4 +2H_2 O`
`n_[H_2 SO_4]=0,2.1=0,2(mol)`
`n_[NaOH]=[200.10]/[100.40]=0,5(mol)`
Ta có: `[0,2]/1 < [0,5]/2=>NaOH` dư, `H_2 SO_4` hết.
`=>` Quỳ tím chuyển xanh.
`C2:`
`SO_3 +H_2 O->H_2 SO_4`
`0,2` `0,2` `(mol)`
`n_[SO_3]=16/80=0,2(mol)`
`C_[M_[H_2 SO_4]]=[0,2]/[0,25]=0,8(M)`
Bài 10:
- Giả sử có 100 gam dd H2SO4 98%
\(m_{H_2SO_4}=\dfrac{100.98}{100}=98\left(g\right)\) => \(n_{H_2SO_4}=\dfrac{98}{98}=1\left(mol\right)\)
\(V_{dd.H_2SO_4.98\%}=\dfrac{100}{1,84}=\dfrac{1250}{23}\left(ml\right)=\dfrac{5}{92}\left(l\right)\)
\(C_{M\left(dd.H_2SO_4.98\%\right)}=\dfrac{1}{\dfrac{5}{92}}=18,4M\)
\(n_{H_2SO_4}=18,4.0,05=0,92\left(mol\right)\)
=> \(m_{H_2SO_4}=0,92.98=90,16\left(g\right)\)
=> \(m_{dd.H_2SO_4.10\%}=\dfrac{90,16.100}{10}=901,6\left(g\right)\)
Bài 11:
a) Do dd sau pư có 3 chát tan với nồng độ % bằng nhau
=> \(m_{Al_2\left(SO_4\right)_3}=m_{ZnSO_4}=m_{H_2SO_4\left(dư\right)}\)
Gọi số mol Al, Zn là a, b (mol)
PTHH: 2Al + 3H2SO4 --> Al2(SO4)3 + 3H2
a----->1,5a------->0,5a----->1,5a
Zn + H2SO4 --> ZnSO4 + H2
b----->b--------->b----->b
=> \(\left\{{}\begin{matrix}m_{Al_2\left(SO_4\right)_3}=342.0,5a=171a\left(g\right)\\m_{ZnSO_4}=161b\left(g\right)\end{matrix}\right.\)
=> 171a = 161b
=> \(\dfrac{a}{b}=\dfrac{161}{171}\) (1)
Có: \(\dfrac{m_{Al}}{m_{Zn}}=\dfrac{27.n_{Al}}{65.n_{Zn}}=\dfrac{27}{65}.\dfrac{161}{171}=\dfrac{483}{1235}\)
b) \(n_{H_2}=1,5a+b=\dfrac{11,2}{22,4}=0,5\left(mol\right)\) (2)
(1)(2) => \(\left\{{}\begin{matrix}a=\dfrac{161}{825}\left(mol\right)\\b=\dfrac{57}{275}\left(mol\right)\end{matrix}\right.\)
=> \(x=\dfrac{161}{825}.27+\dfrac{57}{275}.65=\dfrac{5154}{275}\left(g\right)\)
\(m_{H_2SO_4\left(dư\right)}=m_{Al_2\left(SO_4\right)_3}=342.0,5\dfrac{161}{825}=\dfrac{9177}{275}\left(g\right)\)
=> \(m_{H_2SO_4\left(bđ\right)}=98\left(1,5a+b\right)+\dfrac{9177}{275}=\dfrac{22652}{275}\left(g\right)\)
=> \(y=\dfrac{\dfrac{22652}{275}.100}{10}=\dfrac{45304}{55}\left(g\right)\)
a) Ta có: \(n_{NaCl}=\dfrac{5,85}{58,5}=0,1\left(mol\right)\)
\(\Rightarrow C_{M_{NaCl}}=\dfrac{0,1}{0,5}=0,2\left(M\right)=\left[Na^+\right]=\left[Cl^-\right]\)
b) Ta có: \(n_{Ba\left(OH\right)_2}=\dfrac{34,2}{171}=0,2\left(mol\right)\)
\(\Rightarrow C_{M_{Ba\left(OH\right)_2}}=\dfrac{0,2}{0,5}=0,4\left(M\right)\) \(\Rightarrow\left\{{}\begin{matrix}\left[Ba^{2+}\right]=0,4\left(M\right)\\\left[OH^-\right]=0,8\left(M\right)\end{matrix}\right.\)
c) Ta có: \(n_{H_2SO_4}=0,025\cdot2=0,05\left(mol\right)\)
\(\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,05}{0,125+0,025}\approx0,33\left(M\right)\) \(\Rightarrow\left\{{}\begin{matrix}\left[H^+\right]=0,66\left(M\right)\\\left[SO_4^{2-}\right]=0,33\left(M\right)\end{matrix}\right.\)
Bài 1:
\(n_{KNO_3}=\dfrac{20}{101}=0,198\left(mol\right)\)
\(C_M=\dfrac{n}{V}=\dfrac{0,198}{0,85}=0,233M\)
Bài 2:
\(C_M=\dfrac{n}{V}=\dfrac{0,5}{0,75}=0,66M\)
Bài 3:
\(n_{KNO_3}=2.0,5=1\left(mol\right)\)
\(m_{KNO_3}=1.101=101\left(g\right)\)
Bài 4:
\(C\%=\dfrac{20}{600}.100=3,33\%\)
Bài 1:
\(n_{KNO_3}=\dfrac{20}{101}=0,198\left(mol\right)\)
\(C_{M_{ddKNO_3}}=\dfrac{0,198}{0,85}\approx0,23M\)
Bài 2:
\(C_{M_{ddKCl}}=\dfrac{0,5}{0,75}\approx0,667M\)
Bài 3:
\(n_{KNO_3}=0,5.2=1\left(mol\right)\Rightarrow m_{KNO_3}=1.101=101\left(g\right)\)
Bài 4:
\(C\%_{ddKCl}=\dfrac{20.100\%}{600}=3,333\%\)
\(n_{Fe_2O_3}=0,2(mol)\\ Fe_2O_3+6HCl \to 2FeCl_3+3H_2O\\ n_{HCl}=1,2(mol)\\ V_{ddHCl}=\frac{250}{1,25}=200(ml)=0,2(l)\\ CM_{HCl}=\frac{1,2}{0,2}=6M$\)
\(n_{K_2O}=\dfrac{23.5}{94}=0.25\left(mol\right)\)
\(K_2O+H_2O\rightarrow2KOH\)
\(0.25...................0.5\)
\(C_{M_{KOH}}=\dfrac{0.5}{0.5}=1\left(M\right)\)
\(2KOH+H_2SO_4\rightarrow K_2SO_4+H_2O\)
\(0.5............0.25............0.25\)
\(m_{dd_{H_2SO_4}}=\dfrac{0.25\cdot98}{20\%}=122.5\left(g\right)\)
\(V_{dd_{H_2SO_4}}=\dfrac{122.5}{1.14}=107.5\left(ml\right)=0.1075\left(l\right)\)
\(C_{M_{K_2SO_4}}=\dfrac{0.25}{0.1075+0.5}=0.4\left(M\right)\)
\(a,n_{HCl}=\dfrac{7,3}{36,5}=0,2\left(mol\right)\\ C_{M\left(HCl\right)}=\dfrac{0,2}{0,4}=0,5M\\ b,n_{H_2SO_4}=\dfrac{73,5}{98}=0,75\left(mol\right)\\ C_{M\left(H_2SO_4\right)}=\dfrac{0,75}{0,5}=1,5M\\ n_{NaOH}=\dfrac{16}{40}=0,4\left(mol\right)\\ C_{M\left(NaOH\right)}=\dfrac{0,4}{0,25}=1,6M\\ n_{Ba\left(OH\right)_2}=\dfrac{34,2}{171}=0,2\left(mol\right)\\ C_{M\left(Ba\left(OH\right)_2\right)}=\dfrac{0,2}{0,8}=0,25M\)
250ml = 0,25 lít
\(C_{M_{KOH}}=\dfrac{0,5}{0,25}=2M\)
\(n_{Fe}=\dfrac{11,2}{56}=0,2mol\)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
0,2 0,2 0,2 0,2
a)\(V_{H_2}=0,2\cdot22,4=4,48l\)
b)\(C_{M_{H_2SO_4}}=\dfrac{0,2}{0,5}=0,4M\)
c)\(C_{M_{FeSO_4}}=\dfrac{0,2}{0,5}=0,4M\)
\(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\)
pthh : \(Fe+H_2SO_4->FeSO_4+H_2\)
0,2 0,2
=> \(V_{H_2}=0,2.22,4=4,48\left(L\right)\)
\(m_{H_2SO_4}=\dfrac{0,5}{22,4}.98\approx2,188\left(g\right)\)
=> mdd=11,2+2,188=13,388(g)
C%=\(\dfrac{2,188}{13,388}.100\%=16,3\%\)
`n_[H_2 SO_4]=[9,8]/98=0,1(mol)`
`=>C_[M_[H_2 SO_4]]=[0,1]/[0,25]=0,4(M)`
cho mik hỏi là tại sao lại lấy 9.8 chia cho 98 v ạ?