dẫn khí h2 qua m(g) fe2o3 thu được n(g) fr tác dụng với hcl sinh ra 2,8(l) h2 (đktc) tính m,n
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\(n_{Fe}=\dfrac{2.8}{56}=0.05\left(mol\right)\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(0.05................................0.05\)
\(V_{H_2}=0.05\cdot22.4=1.12\left(l\right)\)
\(n_{CuO}=\dfrac{6}{80}=0.075\left(mol\right)\)
\(CuO+H_2\underrightarrow{^{^{t^0}}}Cu+H_2O\)
\(1............1\)
\(0.075......0.05\)
Chất khử : H2 . Chất OXH : CuO
\(LTL:\dfrac{0.075}{1}>\dfrac{0.05}{1}\Rightarrow CuOdư\)
\(m_{CuO\left(dư\right)}=\left(0.075-0.05\right)\cdot64=1.6\left(g\right)\)
Câu 13:
\(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\\ PTHH:R_2O_3+3H_2\underrightarrow{t^o}2R+3H_2O\\ Theo.pt:n_{R_2O_3}=\dfrac{1}{3}n_{H_2}=\dfrac{1}{3}.0,3=0,1\left(mol\right)\\ M_{R_2O_3}=\dfrac{16}{0,1}=160\left(\dfrac{g}{mol}\right)\\ \Leftrightarrow2R+16.3=160\\ \Leftrightarrow R=56\left(\dfrac{g}{mol}\right)\\ \Leftrightarrow R.là.Fe\\ CTHH:Fe_2O_3\)
Bài 14:
\(n_{H_2}=\dfrac{2,8}{22,4}=0,125\left(mol\right)\\ PTHH:Fe+H_2SO_{4\left(loãng\right)}\rightarrow FeSO_4+H_2\uparrow\left(1\right)\\ Theo.pt\left(1\right):n_{Fe}=n_{H_2}=0,125\left(mol\right)\\ PTHH:Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\left(2\right)\\ Theo.pt\left(2\right):n_{Fe_2O_3}=\dfrac{1}{3}n_{Fe}=\dfrac{1}{3}.0,125=\dfrac{1}{24}\left(mol\right)\\ m=m_{Fe_2O_3}=\dfrac{1}{24}.160=\dfrac{20}{3}\left(g\right)\\ n=n_{Fe}=0,125.56=7\left(g\right)\)
a.
\(n_{H_2}=\dfrac{3,36}{22,4}=0,15mol\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,15 0,15 ( mol )
\(m_{Zn}=0,15.65=9,75g\)
b.
\(n_{Fe_2O_3}=\dfrac{6,4}{160}=0,04mol\)
\(Fe_2O_3+3H_2\rightarrow\left(t^o\right)2Fe+3H_2O\)
0,04 < 0,15 ( mol )
0,04 0,08 ( mol )
\(m_{Fe}=0,08.56=4,48g\)
\(n_{H_2}=\dfrac{2.8}{22.4}=0.125\left(mol\right)\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(0.125............................0.125\)
\(Fe_2O_3+3H_2\underrightarrow{^{^{t^0}}}2Fe+3H_2O\)
\(0.0625...............0.125\)
\(m_{Fe}=0.125\cdot56=7\left(g\right)\)
\(m_{Fe_2O_3}=0.0625\cdot160=10\left(g\right)\)
Bài 2: \(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
Theo PTHH: \(n_{Fe}=n_{H_2}=0,1\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,1\cdot22,4=2,24\left(l\right)\)
Theo PTHH: \(n_{FeCl_2}=n_{Fe}=0,1\left(mol\right)\)
\(\Rightarrow m_{FeCl_2}=127\cdot0,1=12,7\left(g\right)\)
a) $Zn+ 2HCl \to ZnCl_2 + H_2$
b) $n_{HCl} = \dfrac{250.7,3\%}{36,5} = 0,5(mol)$
$n_{Zn} = n_{H_2} = \dfrac{1}{2}n_{HCl} = 0,25(mol)$
$m = 0,25.65 =16,25(gam) ; V_{H_2} = 0,25.22,4 = 5,6(lít)$
c)
$m_{dd\ sau\ pư} = 16,25 + 250 - 0,25.2 = 265,75(gam)$
$C\%_{ZnCl_2} = \dfrac{0,25.136}{265,75}.100\% = 12,8\%$
\(a/ 4Zn+2HCl \to ZnCl_2+H_2 \\ n_{HCl}=\frac{250.7,3\%}{36,5}=0,5(mol)\\ b/ \\ n_{Zn}=n_{H_2}=n_{ZnCl_2}=\frac{1}{2}.n_{HCl}=\frac{1}{2}.0,5=0,25(mol)\\ m_{Zn}=0,25.65=16,25(g)\\ V_{H_2}=0,25.22,4=5,6(l)\\ c/ \\ C\%_{ZnCl_2}=\frac{0,25.136}{16,25+250-0,25.2}.100=12,8\% \)
a)
Zn+2HCl→ZnCl2+H2
b)
nHCl=250.7,3%/36,5=0,5(mol)
nZn=nH2=12nHCl=0,25(mol)
m=0,25.65=16,25(gam);VH2=0,25.22,4=5,6(lít)
c)
mdd sau pư=16,25+250−0,25.2=265,75(gam)
C%ZnCl2=0,25.136/265,75.100%=12,8%
\(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)
PTHH :
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)
0,2 0,2 0,3
\(a,m_{AlCl_3}=0,2.133,5=26,7\left(g\right)\)
\(b,V_{H_2}=0,3.22,4=6,72\left(l\right)\)
nH2= 2,8 : 22,4 = 0,125 (mol)
pthh : H2 + Fe2O3 -t--> Fe + H2O
0,125 0,125
=> m = mFe2O3 = 0,125 . 160 = 20 (G)
pthh : Fe + 2HCl --> FeCl2 + H2
0,125 0,125
=> n = mFe = 0,125 . 56 = 7 (g)