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a, \(n_{Zn}=\dfrac{19,5}{65}=0,3\left(mol\right)\)
\(m_{HCl}=200.14,6\%=29,2\left(g\right)\Rightarrow n_{HCl}=\dfrac{29,2}{36,5}=0,8\left(mol\right)\)
PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
Xét tỉ lệ: \(\dfrac{0,3}{1}< \dfrac{0,8}{2}\), ta được HCl dư.
Theo PT: \(n_{H_2}=n_{Zn}=0,3\left(mol\right)\Rightarrow V_{H_2}=0,3.22,4=6,72\left(l\right)\)
b, \(n_{ZnCl_2}=n_{Zn}=0,3\left(mol\right)\Rightarrow m_{ZnCl_2}=0,3.136=40,8\left(g\right)\)
c, \(n_{HCl\left(pư\right)}=2n_{Zn}=0,6\left(mol\right)\Rightarrow n_{HCl\left(dư\right)}=0,2\left(mol\right)\)
Ta có: m dd sau pư = 19,5 + 200 - 0,3.2 = 218,9 (g)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{HCl}=\dfrac{0,2.36,5}{218,9}.100\%\approx3,33\%\\C\%_{ZnCl_2}=\dfrac{40,8}{218,9}.100\%\approx18,64\%\end{matrix}\right.\)
\(a)n_{Zn}=\dfrac{19,5}{65}=0,3mol\\ n_{HCl}=\dfrac{200.14,6}{100.36,5}=0,8mol\\ Zn+2HCl\rightarrow ZnCl_2+H_2\\ \Rightarrow\dfrac{0,3}{1}< \dfrac{0,8}{2}\Rightarrow HCl.dư\\ n_{H_2}=n_{ZnCl_2}=n_{Zn}=0,3mol\\ V_{H_2}=0,3.22,4=6,72l\\ b)m_{ZnCl_2}=0,3.136=40,8g\\ c)n_{HCl.pư}=0,3.2=0,6mol\\ C_{\%ZnCl_2}=\dfrac{40,8}{200+19,5-0,3.2}\cdot100=18,64\%\\ C_{\%HCl.dư}=\dfrac{\left(0,8-0,6\right).36,5}{200+19,5-0,3.2}\cdot100=3,33\%\)
a) \(Na_2O+H_2O\rightarrow2NaOH\)
\(n_{NaOH}=2n_{Na_2O}=2.\dfrac{11,16}{62}=0,32\left(mol\right)\)
\(C\%_{NaOH}=\dfrac{0,32.40}{11,16+88,84}.100=12,8\%\)
b) \(n_{Fe}=\dfrac{4,48}{56}=0,08\left(mol\right)\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(n_{H_2}=n_{Fe}=0,08\left(mol\right)\\ \Rightarrow V_{H_2}=0,08.22,4=1,792\left(lít\right)\)
\(n_{HCl}=2n_{Fe}=0,16\left(mol\right)\)
\(m_{ddHCl}=\dfrac{0,16.36,5}{7,3\%}=80\left(g\right)\)
\(n_{FeCl_2}=n_{Fe}=0,08\left(mol\right)\\ m_{ddsaupu}=4,48+80-0,08.2=84,32\left(g\right)\)
\(C\%_{FeCl_2}=\dfrac{0,08.127}{84,32}.100=12,05\%\)
\(n_K=\dfrac{5,85}{39}=0,15\left(mol\right)\)
PTHH: 2K + 2H2O --> 2KOH + H2
_____0,15------------->0,15-->0,075
=> VH2 = 0,075.22,4 =1,68(l)
mdd = 5,85 + 100 - 0,075.2 = 105,7(g)
=> \(C\%=\dfrac{0,15.56}{105,7}.100\%=7,95\%\)
Fe+H2SO4->FeSO4+H2
0,15---0,15-----0,15---0,15 mol
n Fe=8,4\56=0,15 mol
=>VH2=0,15.22,4=3,36l
=>m H2SO4=0,15.98=14,7g
=>C% H2SO4=14,7\245 .100=6%
=>m dd muối=8,4+245-0,15.2=253,1g
=>C% muối =0,15.152\253,1 .100=9%
a) \(n_{Al}=\dfrac{10,8}{27}=0,4\left(mol\right)\)
PTHH: 2Al + 3H2SO4 --> Al2(SO4)3 + 3H2
0,4-->0,6---------->0,2------->0,6
=> \(C_{M\left(dd.H_2SO_4\right)}=\dfrac{0,6}{0,15}=4M\)
b) VH2 = 0,6.22,4 = 13,44 (l)
c) \(C_{M\left(Al_2\left(SO_4\right)_3\right)}=\dfrac{0,2}{0,15}=\dfrac{4}{3}M\)
\(n_{Al}=\dfrac{10,8}{27}=0,4\left(mol\right)\\
pthh:2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
0,4 0,6 0,2 0,6
\(C_M_{H_2SO_4}=\dfrac{0,6}{0,15}=4M\\ V_{H_2}=0,622,4=13,44L\)
\(C_M=\dfrac{0,2}{0,15}=1,3M\)
\(n_K=\dfrac{7,8}{39}=0,2\left(mol\right)\)
a) Pt : \(2K+2H_2O\rightarrow2KOH+H_2\)
0,2 0,2 0,1
b) \(V_{H2\left(dktc\right)}=0,1.22,4=2,24\left(l\right)\)
c) \(m_{KOH}=0,2.56=11,2\left(g\right)\)
d)
\(C\%_{KOH}=\dfrac{11,2}{100}.100\%=11,2\%\)
Chúc bạn học tốt
`a)PTHH:`
`2Al + 6HCl -> 2AlCl_3 + 3H_2`
`0,2` `0,6` `0,3` `(mol)`
`n_[Al]=[5,4]/27=0,2(mol)`
`b)V_[H_2]=0,3.22,4=6,72(l)`
`c)m_[dd HCl]=[0,6.36,5]/10 . 100 =219(g)`
Ta có: \(n_{Na}=\dfrac{2,3}{23}=0,1\left(mol\right)\)
a. PTHH: 2Na + 2H2O ---> 2NaOH + H2↑
b. Ta có: \(n_{H_2O}=\dfrac{97,8}{18}=5,43\left(mol\right)\)
Ta thấy: \(\dfrac{0,1}{2}< \dfrac{5,43}{2}\)
=> H2O dư.
Theo PT: \(n_{H_2}=\dfrac{1}{2}.n_{Na}=\dfrac{1}{2}.0,1=0,05\left(mol\right)\)
=> \(V_{H_2}=0,05.22,4=1,12\left(lít\right)\)
c. Ta có: \(m_{dd_{NaOH}}=2,3+97,8=100,1\left(g\right)\)
Theo PT: \(n_{NaOH}=n_{Na}=0,1\left(mol\right)\)
=> \(m_{NaOH}=0,1.40=4\left(g\right)\)
=> \(C_{\%_{NaOH}}=\dfrac{4}{100,1}.100\%=3,996\%\)