Hòa tan hoàn toàn 5,475g CaCl2.6H2O vào 100 ml dd X. Tính nồng độ mol của dd X
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\(n_{CaCl_2.6H_2O}=n_{CaCl_2}=\dfrac{5,475}{219}=0,025\left(mol\right)\)
Ta có :100ml H2O ~ 100g H2O
=> \(C\%_{CaCl_2}=\dfrac{0,025.111}{100+5,4750}.100=2,63\%\)
\(n_{Zn}=\dfrac{4,55}{65}=0,07(mol)\\ Zn+2HCl\to ZnCl_2+H_2\\ a,n_{HCl}=0,14(mol)\\ \Rightarrow C_{M_{HCl}}=\dfrac{0,14}{0,2}=0,7M\\ b,n_{H_2}=0,07(mol)\\ \Rightarrow V_{H_2}=0,07.22,4=1,568(l)\\ c,n_{ZnCl_2}=0,07(mol)\\ \Rightarrow m_{ZnCl_2}=0,07.136=9,52(g)\\ c,ZnCl_2+2AgNO_3\to 2AgCl\downarrow+Zn(NO_3)_2\)
\(m_{dd_{ZnCl_2}}=200.0,8+4,55-0,07.2=164,41(g)\\ n_{AgCl}=0,14(mol);n_{Zn(NO_3)_2}=0,07(mol)\\ \Rightarrow C\%_{Zn(NO_3)_2}=\dfrac{0,07.189}{164,41+200-0,14.143,5}.100\%=3,84%\)
$n_{Na_2CO_3} = n_{Na_2CO_3.10H_2O} = \dfrac{28,6}{286} = 0,1(mol)$
$C_{M_{Na_2CO_3}} = \dfrac{0,1}{0,2} = 0,5M$
$m_{dd} = D.V = 200.1,05 = 210(gam)$
$C\%_{Na_2CO_3} = \dfrac{0,1.106}{210}.100\% = 5,05\%$
a, \(Fe+2HCl\rightarrow FeCl_2+H_2\)
Ta có: \(n_{Fe}=\dfrac{14}{56}=0,25\left(mol\right)\)
Theo PT: \(\left\{{}\begin{matrix}n_{HCl}=2n_{Fe}=0,5\left(mol\right)\\n_{H_2}=n_{Fe}=0,25\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow V_{H_2}=0,25.24,79=6,1975\left(l\right)\)
\(a=C_{M_{HCl}}=\dfrac{0,5}{0,1}=5\left(M\right)\)
b, Theo PT: \(n_{FeCl_2}=n_{Fe}=0,25\left(mol\right)\)
Ta có: \(n_{AgNO_3}=0,4.1,3=0,52\left(mol\right)\)
PT: \(2AgNO_3+FeCl_2\rightarrow Fe\left(NO_3\right)_2+2AgCl_{\downarrow}\)
______0,5______0,25______0,25________0,5 (mol)
\(AgNO_3+Fe\left(NO_3\right)_2\rightarrow Fe\left(NO_3\right)_3+Ag_{\downarrow}\)
0,02______0,02________0,02________0,02 (mol)
⇒ m = mAgCl + mAg = 0,5.143,5 + 0,02.108 = 73,91 (g)
- Dd sau pư gồm: Fe(NO3)3: 0,02 (mol) và Fe(NO3)2: 0,25 - 0,02 = 0,23 (mol)
\(\Rightarrow\left\{{}\begin{matrix}C_{M_{Fe\left(NO_3\right)_3}}=\dfrac{0,02}{0,1+0,4}=0,04\left(M\right)\\C_{M_{Fe\left(NO_3\right)_2}}=\dfrac{0,23}{0,1+0,4}=0,46\left(M\right)\end{matrix}\right.\)
\(Fe+2HCl->FeCl_2+H_2\\ a.V=\dfrac{14}{56}\cdot22,4=5,6\left(L\right)\\ a=\dfrac{\dfrac{14}{56}\cdot2}{0,1}=5\left(M\right)\\ b.n_{AgNO_3}=0,4\cdot1,3=0,52mol\\ FeCl_2+AgNO_3->Fe\left(NO_3\right)_2+AgCl\\ Fe\left(NO_3\right)_2+AgNO_3->Ag+Fe\left(NO_3\right)_3\\ m=0,25\cdot143,5+0,25\cdot108=62,875\left(g\right)\\ C_{M\left(AgNO_3\right)}=\dfrac{0,02}{0,5}=0,04M\\ C_{M\left(Fe\left(NO_3\right)_3\right)}=\dfrac{0,25}{0,5}=0,5M\)
a. Ta có: \(n_{MgO}=\dfrac{1,2}{40}=0,03\left(mol\right)\)
PTHH: \(MgO+H_2SO_4--->MgSO_4+H_2O\)
Theo PT: \(n_{H_2SO_4}=n_{MgO}=0,03\left(mol\right)\)
Đổi 300ml = 0,3 lít
=> \(C_{M_{H_2SO_4}}=\dfrac{0,03}{0,3}=0,1M\)
b. Theo PT: \(n_{MgSO_4}=n_{MgO}=0,03\left(mol\right)\)
=> \(m_{MgSO_4}=0,03.120=3,6\left(g\right)\)
Ta có : \(n_{CaCl_2.6H_2O}=n_{CaCl_2}=\dfrac{5,475}{219}=0,025\left(mol\right)\)
=> CM CaCl2= \(\dfrac{0,025}{0,1}=0,25M\)