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a, \(2Zn+O_2\underrightarrow{t^o}2ZnO\)
b, \(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
Theo PT: \(n_{O_2}=\dfrac{1}{2}n_{Zn}=0,1\left(mol\right)\Rightarrow V_{O_2}=0,1.22,4=2,24\left(l\right)\)
\(\Rightarrow V_{kk}=5V_{O_2}=11,2\left(l\right)\)
c, \(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
Theo PT: \(n_{KMnO_4}=2n_{O_2}=0,2\left(mol\right)\Rightarrow m_{KMnO_4}=0,2.158=31,6\left(g\right)\)
nAl=16,2/27= 0,6(mol)
a) PTHH: 4 Al +3 O2 -to-> 2 Al2O3
nO2= 3/4 . nAl=3/4 . 0,6= 0,45(mol)
=> V(O2,đktc)=0,45 x 22,4=10,08(l)
b) nAl2O3= nAl/2=0,6/2=0,3(mol)
=>mAl2O3=102. 0,3= 30,6(g)
c) 2KMnO4 -to-> K2MnO4 + MnO2 + O2
nKMnO4= 2.nO2=2. 0,45=0,9(mol)
=>mKMnO4= 158 x 0,9= 142,2(g)
nP = 3,1 : 31 = 0,1 (mol)
pthh : 4P + 5O2 -t--> 2P2O5 (1)
0,1--> 0,125 (mol)
=> VO2 = 0,125 .22,4 = 2,8(l)
pthh : 2KMnO4 -t--> K2MnO4 + MnO2 +O2 (2)
0,25<--------------------------- 0,125(mol)
=> mKMnO4 = 0,25 .158 = 39,5(g)
d ) (1) là Phản ứng hóa hợp
(2) là phản ứng phân hủy
nP = 3,1/31 = 0,1 (mol)
PTHH: 4P + 5O2 -> (t°) 2P2O5 (phản ứng hóa hợp)
Mol: 0,1 ---> 0,125
VO2 = 0,125 . 22,4 = 2,8 (l)
PTHH: 2KMnO4 -> (t°) K2MnO4 + MnO2 + O2 (phản ứng phân hủy)
nKMnO4 = 0,125 . 2 = 0,25 (mol)
mKMnO4 = 0,25 . 158 = 39,5 (g)
4P+5O2-to>2P2O5
0,04----0,05----0,02
n P=0,04 mol
=>m P2O5=0,02.142=2,84g
=>VO2=0,05.22,4=1,12l
c)
2KMnO4-to>K2MnO4+MnO2+O2
0,1----------------------------------------0,05
H=10%
m KMnO4=0,1.158.110%=17,28g
\(n_P=\dfrac{1,24}{31}=0,04\left(mol\right)\\ pthh:4P+5O_2\underrightarrow{T^O}2P_2O_5\)
0,04 0,05 0,02
=> \(\left\{{}\begin{matrix}m_{P_2O_5}=0,02.142=2,84\left(g\right)\\V_{O_2}=0,05.22,4=1,12\left(l\right)\end{matrix}\right.\)
\(pthh:2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
0,1 0,05
=> \(m_{KMnO_4}=0,1.158=15,8\left(g\right)\)
\(m_{KMnO_4\left(d\text{ùng}\right)}=15,8.110\%=17,38\left(g\right)\)
a) $n_{Al} = \dfrac{5,4}{27} = 0,2(mol)$
$4Al + 3O_2 \xrightarrow{t^o} 2Al_2O_3$
Theo PTHH : $n_{O_2} = \dfrac{3}{4}n_{Al} = 0,15(mol)$
$V_{O_2} = 0,15.22,4 = 3,36(lít)$
b) $2 KClO_3 \xrightarrow{t^o} 2KCl + 3O_2$
$n_{KClO_3} = \dfrac{2}{3}n_{O_2} = 0,1(mol)$
$m_{KClO_3} = 0,1.122,5 = 12,25(gam)$
\(n_{Al}=\dfrac{m}{M}=\dfrac{5,4}{27}=0,2\left(mol\right)\\ PTHH:4Al+3O_2-^{t^o}>2Al_2O_3\)
tỉ lệ: 4 : 3 : 2
n(mol) 0,2---->0,15---->0,1
\(V_{O_2\left(dktc\right)}=n\cdot22,4=0,15\cdot22,4=3,36\left(l\right)\\ PTHH:2KClO_3-^{t^o}>2KCl+3O_2\)
tỉ lệ: 2 : 2 : 3
n(mol) 0,1<-------------------------0,15
\(m_{KClO_3}=n\cdot M=0,1\cdot\left(39+35,5+16\cdot3\right)=12,25\left(g\right)\)
a.b.\(n_{Mg}=\dfrac{m}{M}=\dfrac{6,4}{24}=\dfrac{4}{15}mol\)
\(2Mg+O_2\rightarrow\left(t^o\right)2MgO\)
4/15 2/15 ( mol )
\(V_{O_2}=n.22,4=\dfrac{2}{15}.22,4=\dfrac{224}{75}l\)
c.\(2KMnO_4\rightarrow\left(t^o\right)K_2MnO_4+MnO_2+O_2\)
4/15 2/15 ( mol )
\(m_{KMnO_4}=n.M=\dfrac{4}{15}.158=\dfrac{632}{15}g\)
nMg = 6,4 : 24= 0,26(mol)
pthh : 2Mg+O2 -t--> 2MgO
0,26 --> 0,13 (mol )
=> VO2(đktc) = 0,13.22,4=2,912(l)
pthh : 2KMnO4-t--> K2MnO4 + MnO2+ O2
0,26<------------------------------0,13(mol)
=> mKMnO4 = 0,26.158= 41,08(g)
\(2Zn+O2-->2ZnO\)
a)\(n_{Zn}=\frac{26}{65}=0,4\left(mol\right)\)
\(n_{O2}=\frac{1}{2}n_{Zn}=0,2\left(mol\right)\)
\(V_{O2}=0,2.22,4=4,48\left(l\right)\)
b)\(2KMnO4-->K2MnO4+MnO2+O2\)
\(n_{KMnO4}=2n_{O2}=0,4\left(mol\right)\)
\(m_{KMnO4}=0,4.158=63,2\left(g\right)\)
c)Do phản ứng bị hao hụt 5%
==>\(m_{KMnO4}=63,2-63,2.5\%=60,04\left(g\right)\)