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Đáp án B
nH+ = nHCl = 0,006
nOH- = nNaOH = 0,005
Khi pha trộn: H+ + OH- → H2O
=> nH+ dư = 0,001
=> [H+] = 0,001/0,1 = 0,01 => pH = 2
a) \(n_{H^+}=n_{HCl}+2n_{H_2SO_4}=0,1\cdot0,12+0,1\cdot0,04=0,016\)
\(C_M=\dfrac{0,016}{0,2}=0,08M\)
\(\Rightarrow pH=-log\left(0,08\right)=1,1\)
b) \(n_{OH^-}=n_{KOH}+2n_{Ba\left(OH\right)_2}=0,012+2\cdot0,004=0,02\)
\(C_M=\dfrac{0,02}{0,2}=0,1\)
\(\Rightarrow pH=-log\left(\dfrac{10^{-14}}{0,1}\right)=13\)
Chọn C
pH = 11 → [ OH - ] = 10 - 3 (M)
pH = 12 → [ OH - ] = 10 - 2 (M)
Tổng số mol OH - có trong dung dịch X là: n = 0 , 1 . 10 - 3 + 0 , 05 . 10 - 2 = 6 . 10 - 4 (mol)
a, \(n_{HCl}=0,1.0,2=0,02\left(mol\right)=n_{H^+}=n_{Cl^-}\)
\(n_{H_2SO_4}=0,1.0,2=0,02\left(mol\right)=n_{SO_4^{2-}}\) \(\Rightarrow n_{H^+}=2n_{H_2SO_4}=0,04\left(mol\right)\)
\(n_{NaOH}=0,3.0,4=0,12\left(mol\right)=n_{Na^+}=n_{OH^-}\)
\(\Rightarrow\sum n_{H^+}=0,02+0,04=0,06\left(mol\right)\)
\(H^++OH^-\rightarrow H_2O\)
0,06__0,06 (mol)
⇒ nOH- dư = 0,12 - 0,06 = 0,06 (mol)
\(\Rightarrow\left\{{}\begin{matrix}\left[Cl^-\right]=\dfrac{0,02}{0,1+0,3}=0,05\left(M\right)\\\left[SO_4^{2-}\right]=\dfrac{0,02}{0,1+0,3}=0,05\left(M\right)\\\left[Na^+\right]=\dfrac{0,12}{0,1+0,3}=0,3\left(M\right)\\\left[OH^-\right]=\dfrac{0,06}{0,1+0,3}=0,15\left(M\right)\end{matrix}\right.\)
b, pH = 14 - (-log[OH-]) ≃ 13,176
a, \(\left[Na^+\right]=0,1\)
\(\left[K^+\right]=0,1\)
\(\left[OH^-\right]=0,2\)
\(\left[SO_4^{2-}\right]=0,2\)
\(\left[H^+\right]=0,4\)
b, \(n_{H^+}=0,1.0,4=0,04\left(mol\right)\)
\(n_{OH^-}=0,1.0,2=0,02\left(mol\right)\)
\(H^++OH^-\rightarrow H_2O\)
\(\Rightarrow n_{H^+dư}=0,02\left(mol\right)\)
\(\Rightarrow\left[H^+\right]=\dfrac{0,02}{200}=10^{-4}\)
\(\Rightarrow pH=4\)
$n_{NaOH} = n_{KOH} = 0,1.0,1 = 0,01(mol)$
$n_{H_2SO_4} = 0,02(mol)$
OH- + H+ → H2O
Bđ : 0,01...0,04..................(mol)
Pư : 0,01...0,01...................(mol)
Sau pư : 0......0,03...................(mol)
$V_{dd} = 0,1 + 0,1 = 0,2(lít)$
Vậy :
$[K^+] = [Na^+] = \dfrac{0,01}{0,2} = 0,05M$
$[H^+] = \dfrac{0,03}{0,2} = 0,15M$
$[SO_4^{2-}] = \dfrac{0,02}{0,2} = 0,1M$
b)
$pH = -log(0,15) = 0,824$
\(n_{NaOH}=0,006\left(mol\right)\\ \Rightarrow n_{Na^+}=0,006\left(mol\right);n_{OH^-}=0,006\left(mol\right)\\ n_{H_2SO_4}=0,005\left(mol\right)\\ \Rightarrow n_{H^+}=0,01\left(mol\right);n_{SO_4^{2-}}=0,005\left(mol\right)\\ H^++OH^-\rightarrow H_2O\\ LTL:\dfrac{0,01}{1}>\dfrac{0,006}{1}\Rightarrow H^+dư\\ \left[H^+_{dư}\right]=\dfrac{0,01-0,006}{0,1}=0,04M\\ \left[Na^+\right]=\dfrac{0,006}{0,1}=0,06M\\ \left[SO_4^{2-}\right]=\dfrac{0,005}{0,1}=0,05M\)