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nNO=3,36/22,4=0,15
Theo định luật bảo toàn mol e
\(Fe^0\rightarrow Fe^{+3}+3e
\)
\(Cu^0\rightarrow Cu^{+2}+2e\)
\(N^{+5}+3e\rightarrow N^{+2}\)
=> 3a+2b=3.0,15=0,45
Ta có hpt:\(\begin{cases}3a+2b=0,45\\56a+64b=12,4\end{cases}\Leftrightarrow\begin{cases}a=0,05\left(mol\right)\\b=0,15\left(mol\right)\end{cases}}\)
\(n_{Fe\left(NO3\right)3}=n_{Fe}=0,05,n_{Cu\left(NO3\right)2}=n_{Cu_{ }_{ }}=0,15\)Từ đó tính m nha bạn
a) Zn+Cl2---->ZnCl2
Ca+Cl2---->CaCl2
b) Gọi n Zn=x------>m Zn=65x
n Ca=y--------->m Ca=40y
--->65x+40y=1,45(1)
n Cl2=0,672/22,4=0,03(mol)
--->x+y=0,03(2)
Từ 1 và 2 ta có hpt
\(\left\{{}\begin{matrix}65x+40y=1,45\\x+y=0,03\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,01\\y=0,02\end{matrix}\right.\)
%m Zn=0,01.65/1,45.100%=44,83%
%m Ca=100-44,83=55,17%
c)ZnCl2+2AgNO3--->2AgCl+Zn(NO3)2
0,1-------------------->0,2(mol)
CaCl2+2AgNO3--->2AgCl+Ca(NO3)2
0,2----------------------->0,4(mol)
Tổng n AgCl=0,6(mol)
m AgCl=0,6.143,5=86,1(g)
Chúc bạn học tốt
a)Fe + 2HCl ->FeCl2 + H2\(\uparrow\)
0.01 0.01
FeS + 2HCl ->FeCl2 + H2S\(\uparrow\)
0.1 0.1
H2S + Pb(NO3)2->PbS \(\downarrow\) + 2HNO3
0.1 0.1
nPbS =2.39/239=0.1 mol , n (hỗn hợp khí) =2.464/22.4=0.11 mol
n(H2)+n(H2S)=0.11 ->n(H2)=0.01 mol
V(H2)=n * 22.4 = 0.01*22.4=0.224(l)
V(H2S)=n*22.4=0.1*22.4=2.24(l)
m(Fe)=n*M=0.01*56=0.56(g)
m(FeS)=n*M=0.1*88=8.8(g)
Câu 1:
Gọi \(\left\{{}\begin{matrix}n_{Cu}:x\left(mol\right)\\n_{Fe}:y\left(mol\right)\end{matrix}\right.\)
\(Cu+Cl_2\rightarrow CuCl_2\)
\(Fe+Cl_2\rightarrow FeCl_2\)
\(\left\{{}\begin{matrix}64x+56y=30,4\\2x+3y=1,2\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,3\\y=0,2\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Cu}=0,3.64=19,2\left(g\right)\\m_{Fe}=0,2.56=11,2\left(g\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Cu}=63,16\%\\\%m_{Fe}=36,84\%\end{matrix}\right.\)
BTNT Cl:
\(n_{AgCl}=2.n_{Cl2}=1,2\left(mol\right)\)
\(\Rightarrow m_{AgCl}=172,2\left(g\right)\)
Câu 2:
Gọi \(\left\{{}\begin{matrix}n_{Al}:x\left(mol\right)\\n_{Zn}:y\left(mol\right)\end{matrix}\right.\)
\(2Al+6HCl2\rightarrow AlCl_3+3H_2\)
x______________x________3x/2
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
y___________y_________y
\(m_{kl}=27x+65y=3,57\left(1\right)\)
\(m_{muoi}=133,5x+136y=12,09\left(2\right)\)
\(\left(1\right)+\left(2\right)\Rightarrow\left\{{}\begin{matrix}x=0,06\\y=0,03\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Al}=0,06.27=1,62\left(g\right)\\m_{Zn}=0,03.65=1,95\left(g\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%_{Al}=45,38\%\\\%_{Zn}=54,62\%\end{matrix}\right.\)
Bảo toàn e: \(n_{H2}=0,12\left(mol\right)\Rightarrow V=\frac{32}{12}=2,46\left(l\right)\)