Hãy nhập câu hỏi của bạn vào đây, nếu là tài khoản VIP, bạn sẽ được ưu tiên trả lời.
1.GS có 100g dd $HCl$
=>m$HCl$=100.20%=20g
=>n$HCl$=20/36,5=40/73 mol
=>n$H2$=20/73 mol
Gọi n$Fe$(X)=a mol n$Mg$(X)=b mol
=>n$HCl$=2a+2b=40/73
mdd sau pứ=56a+24b+100-40/73=56a+24b+99,452gam
m$MgCl2$=95b gam
C% dd $MgCl2$=11,79%=>95b=11,79%(56a+24b+99,452)
=>92,17b-6,6024a=11,725
=>a=0,13695 mol và b=0,137 mol
=>C%dd $FeCl2$=127.0,13695/mdd.100%=15,753%
2.Bảo toàn klg=>mhh khí bđ=m$C2H2$+m$H2$
=0,045.26+0,1.2=1,37 gam
mC=mA-mbình tăng=1,37-0,41=0,96 gam
HH khí C gồm $H2$ dư và $C2H6$ không bị hấp thụ bởi dd $Br2$ gọi số mol lần lượt là a và b mol
Mhh khí=8.2=16 g/mol
mhh khí=0,96=2a+30b
nhh khí=0,06=a+b
=>a=b=0,03 mol
Vậy n$H2$=n$C2H6$=0,03 mol
nH2 = \(\frac{3,36}{22,4}\)= 0,15 mol
Fe + 2HCl➞ FeCl2 + H2
0,15 0,15
=> mFe = 0,15.56=8,4 gam
Cu không tác dụng với HCl
=> mCu = 10 - mFe = 1,6 gam
=> %mFe = \(\frac{8,4}{10}\) = 84 %
=> %mCu = 100 - 84 = 16 %
15
a)\(Fe+H2SO4-->FeSO4+H2\)
\(n_{H2}=\frac{33,6}{22,4}=1,5\left(mol\right)\)
\(n_{Fe}=n_{H2}=1,5\left(mol\right)\)
\(m_{Fe}=1,5.56=84\left(g\right)\)
b)\(n_{FeSO4}=n_{H2}=1,5\left(mol\right)\)
\(m=m_{FeSO4}=1,5.152=228\left(g\right)\)
c)\(n_{H2SO4}=n_{H2}=1,5\left(mol\right)\)
\(C_{M\left(H2SO4\right)}=\frac{1,5}{0,5}=3\left(M\right)\)
16.
n\(_{H2}=\frac{2,24}{22,4}=0,1\left(mol\right)\)
Gọi \(n_{Mg}=x,n_{Fe}=y\)
\(Mg+2HCl--.MgCl2+H2\)
x-------------------------x----------x(mol)
\(Fe=2HCl-->FeCl2+H2\)
y----------------------------y------y(mol)
Theo bài ta có hpt
\(\left\{{}\begin{matrix}24x+56y=4\\x+y=0,1\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,05\\y=0,05\end{matrix}\right.\)
\(m_{MgCl2}=0,05.95=4,75\left(g\right)\)
\(m_{FeCl2}=0,05.127=6,35\left(g\right)\)
17.
\(n_{H2}=\frac{13,44}{22,4}=0,6\left(mol\right)\)
\(Fe+2HCl--.FeCl2+H2\)
x----------------------------------x(mol)
\(2Al+6HCl--.2AlCl3+3H2\)
y----------------------------------------1,5y(mol)
theo bài ta có hpt
\(\left\{{}\begin{matrix}56x+27y=22,2\\x+1,5y=0,6\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,3\\y=0,2\end{matrix}\right.\)
\(\%m_{Fe}=\frac{0,3.56}{22,2}.100\%=75,68\%\%\)
\(\%m_{Al}=100-75,68=24,32\%\)
18.
\(Mg+2HCl--.MgCl2+H2\)
\(Fe+2HCl--.FeCl2+H2\)
Chất rắn k tan là Cu = 2,54(g)
=>\(m_{Mg+Fe}=10,54-02,54=10\left(g\right)\)
\(n_{H2}=\frac{4,48}{22,4}=0,2\left(mol\right)\Rightarrow m_{H2}=0,4\left(g\right)\)
\(n_{HCl}=n_{H2}=0,4\left(mol\right)\Rightarrow m_{HCl}=0,4.36,5=14,6\left(g\right)\)
\(m=m_{Fe+Mg}+m_{HCl}-m_{H2}=10+14,6-0,4=24,2\left(g\right)\)
Bài 2
mol HCl=3.0,1=0,3mol(100ml=0,1l)
CuO+2HCl->CuCl2+H2O (1)
xmol 2xmol
ZnO+2HCl->ZnCl2+H2O(2)
ymol 2ymol
Từ 1 và 2 ta co hệ phương trình
2x+2y=0,3 ->x=0,05=molCuO
80x+81y=12,1 ->y=0,1=molZnO
=>mCuO=0,05.80=4g
->%CuO=(4.100)/12,1=33,075%
->%ZnO=100-33,075=66,943%
b. CuO+H2SO4->CuSO4+H2O (3)
Theo ptpu 3 taco nH2SO4=nCuO=0,05 mol
ZnO+H2SO4->ZnSO4+H2O (4)
Theo ptpu 4 ta co nH2SO4=nZnO=0,1mol
=>nH2SO4=0.05+0,1=0,15mol
->mH2SO4=0,15.98=14,7g
=>mddH2SO4=(14,7.100)/20=73,5g
Bài 1
a/. Phương trình phản ứng hoá học:
Fe + 2HCl --> FeCl2 + H2
b/. nH2 = V/22,4 = 3,36/22,4 = 0,15 (mol)
....... Fe.....+ 2HCl --> Fecl2 + H2
TPT 1 mol....2 mol.................1 mol
TDB x mol....y mol................0,15 mol
nFe = x = (0,15x1)/1 = 0,15 (mol)
mFe = n x M = 0,15 x 56 = 8,4 (g)
c/. nHCl = y = (0,15x2)/1 = 0,3 (mol)
CMHCl = n/V = 0,3/0,05 = 6 (M)
PTHH:
\(CaCO_3+2HCl\rightarrow CaCl_2+H_2O+CO_2\uparrow\)
0,15 0,15
\(CaO+2HCl\rightarrow CaCl_2+H_2O\)
Ta có: \(n_{CO_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
\(\Rightarrow m_{CaCO_3}=0,15\cdot100=15\left(g\right)\)
\(\Rightarrow m_{CaO}=20,6-15=5,6\left(g\right)\)
\(\Rightarrow\%m_{CaCO_3}=\dfrac{15\cdot100}{20,6}\approx73\%\)
\(\Rightarrow\%m_{CaO}=100\%-73\%=27\%\)
a, gọi a= nFe
b= nFeO
=> 56a + 72b= 12,8 (1)
Fe +H2SO4 -> FeSO4 +H2
a b b a
FeO +H2SO4 -> FeSO4 +H2O
b b b
a=nH2 = 2,24/22,4= 0,1 mol
từ (1) => b= 0,1
mFe= 56.0,1=5,6(g)
m FeO = 72.0,1= 7,2(g)
b, nH2SO4 (bđ) = 0,25 mol
nH2SO4 pứ = a+b =0,2 mol
=> nH2SO4 dư = 0,25-0,2=0,05 mol
2NaOH +H2SO4 -> Na2SO4 +2H2O
0,1 0,05
V(NaOH)= 0,1/ 1= 0,1 lit =100ml
\(\text{Đặt }n_{Al}=x(mol);n_{Fe}=y(mol)\\ \Rightarrow 27x+56y=13,9(1)\\ n_{H_2}=\dfrac{7,84}{22,4}=0,35(mol)\\ a,PTHH:2Al+6HCl\to 2AlCl_3+3H_2(1)\\ Fe+2HCl\to FeCl_2+H_2(2)\\ b,\text{Từ 2 PT: }1,5x+y=0,35(2)\\ (1)(2)\Rightarrow x=0,1(mol);y=0,2(mol)\\ \Rightarrow m_{Al}=0,1.27=2,7(g)\\ m_{Fe}=0,2.56=11,2(g)\)
\(c,n_{HCl(1)}=3n_{Al}=0,3(mol);n_{AlCl_3}=0,1(mol);n_{H_2(1)}=0,15(mol)\\ \Rightarrow m_{dd_{HCl(1)}}=\dfrac{0,3.36,5}{14,6\%}=75(g)\\ \Rightarrow C\%_{AlCl_3}=\dfrac{0,1.133,5}{2,7+75-0,15.2}.100\%=17,25\%\)
\(n_{HCl(2)}=2n_{Fe}=0,4(mol);n_{FeCl_2}=n_{H_2(2)}=n_{Fe}=0,2(mol)\\ \Rightarrow m{dd_{HCl(2)}}=\dfrac{0,4.36,5}{14,6\%}=100(g)\\ \Rightarrow C\%_{FeCl_2}=\dfrac{0,2.127}{11,2+100-0,2.2}.100\%=22,92\%\)
a) 2Al + 6HCl --> 2AlCl3 + 3H2
Fe + 2HCl --> FeCl2 + H2
b) Gọi số mol Al, Fe lần lượt là a,b
=> 27a + 56b = 13,9
\(n_{H_2}=\dfrac{7,84}{22,4}=0,35\left(mol\right)\)
2Al + 6HCl --> 2AlCl3 + 3H2
a----->3a--------->a------->1,5a______(mol)
Fe + 2HCl --> FeCl2 + H2
b------>2b-------->b----->b__________(mol)
=> 1,5a + b = 0,35
=> \(\left\{{}\begin{matrix}a=0,1=>m_{Al}=0,1.27=2,7\left(g\right)\\b=0,2=>m_{Fe}=0,2.56=11,2\left(g\right)\end{matrix}\right.\)
c) nHCl = 3a + 2b = 0,7 (mol)
=> mHCl = 0,7.36,5 = 25,55(g)
=> \(m_{ddHCl}=\dfrac{25,55.100}{14,6}=175\left(g\right)\)
\(m_{dd\left(saupu\right)}=13,9+175-2.0,35=188,2\left(g\right)\)
\(\left\{{}\begin{matrix}m_{AlCl_3}=0,1.133,5=13,35\left(g\right)\\m_{FeCl_2}=0,2.127=25,4\left(g\right)\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}C\%\left(AlCl_3\right)=\dfrac{13,35}{188,2}.100\%=7,1\%\\C\%\left(FeCl_2\right)=\dfrac{25,4}{188,2}.100\%=13,5\%\end{matrix}\right.\)
nH2=0,84(mol)
PTHH: Fe + 2 HCl -> FeCl2 + H2
0,84__________________0,84(mol)
=>mFe=0,84.56=47,04(g)
=> mCaCO3=48,8-47,04=1,76(g)
b) %mCaCO3=(1,76/48,8).100=3,607%
=>%mFe= 96,393%
PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
\(CaCO_3+2HCl\rightarrow CaCl_2+H_2O+CO_2\uparrow\)
Ta có: \(n_{Fe}=n_{H_2}=\dfrac{18,816}{22,4}=0,84\left(mol\right)\)
\(\Rightarrow m_{Fe}=0,84\cdot56=47,04\left(g\right)\) \(\Rightarrow m_{CaCO_3}=1,76\left(g\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{CaCO_3}=\dfrac{1,76}{48,8}\cdot100\%\approx3,61\%\\\%m_{Fe}=96,39\%\end{matrix}\right.\)