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\(n_{Br_2}=\dfrac{4}{160}=0,025mol\)
\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
0,025 0,025 ( mol )
\(V_{hh}=\dfrac{2,8}{22,4}=0,125mol\)
\(\%V_{C_2H_4}=\dfrac{0,025}{0,125}.100=20\%\)
\(\%V_{CH_4}=100\%-20\%=80\%\)
C2H2+2Br2->C2H2Br4
0,05-----0,1
n Br2=\(\dfrac{16}{160}=0,1mol\)
=>%VC2H2=\(\dfrac{0,05.22,4}{3,36}100\)=33,3%
=>%VCH4=66,7%
Gọi số mol của \(C_2H_2\) và \(CH_4\) lần lượt là x và y.
\(C_2H_2+2Br_2\rightarrow CHBr_2+CHBr_2\)
x 2x
\(CH_4+Br_2\rightarrow CH_3Br+HBr\)
y y
Ta có hệ pt :
\(\left\{{}\begin{matrix}x+y=\dfrac{3,36}{22,4}\\2x+y=\dfrac{16}{160}\end{matrix}\right.\)
Giải hệ ta được : x = -0,05:))
coi lại đề mỗi cái đề cx đưa ko đàng hoàng nx.-.
\(n_{hh}=\dfrac{3,36}{22,4}=0,15mol\)
\(n_{Br_2}=\dfrac{2,4}{160}=0,015mol\)
\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
0,0075 0,015 ( mol )
\(V_{C_2H_2}=0,0075.22,4=0,168l\)
\(V_{CH_4}=3,36-0,168=3,192l\)
\(\%V_{C_2H_2}=\dfrac{0,168}{3,36}.100=5\%\)
\(\%V_{CH_4}=100\%-5\%=95\%\)
a)
\(n_{Br_2}=\dfrac{8}{160}=0,05\left(mol\right)\)
PTHH: C2H4 + Br2 --> C2H4Br2
0,05<-0,05
=> \(n_{CH_4}=\dfrac{3,36}{22,4}-0,05=0,1\left(mol\right)\)
\(\%m_{CH_4}=\dfrac{0,1.16}{0,1.16+0,05.28}.100\%=53,33\%\)
\(\%m_{C_2H_4}=\dfrac{0,05.28}{0,1.16+0,05.28}.100\%=46,67\%\)
b)
PTHH: CH4 + 2O2 --to--> CO2 + 2H2O
0,1-->0,2
C2H4 + 3O2 --to--> 2CO2 + 2H2O
0,05--->0,15
=> \(V_{O_2}=\left(0,2+0,15\right).22,4=7,84\left(l\right)\)
PT: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
Gọi: \(\left\{{}\begin{matrix}n_{C_2H_4}=x\left(mol\right)\\n_{C_2H_2}=y\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow x+y=\dfrac{2,24}{22,4}=0,1\left(mol\right)\left(1\right)\)
\(n_{Br_2}=n_{C_2H_4}+2n_{C_2H_2}=x+2y=\dfrac{24}{160}=0,15\left(mol\right)\left(2\right)\)
Từ (1) và (2) \(\Rightarrow x=y=0,05\left(mol\right)\)
\(\Rightarrow\%V_{C_2H_4}=\%V_{C_2H_2}=\dfrac{0,05.22,4}{2,24}.100\%=50\%\)
Cho hỗn hợp qua dung dịch brom dư
\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
Khí thoát ra là \(CH_4\)
\(CH_4+2O_2\rightarrow^{t^o}CO_2+2H_2O\)
\(Ca\left(OH\right)_2+CO_2\rightarrow CaCO_3+H_2O\)
Ta có:
\(n_{CaCO_3}=\frac{40}{100}=0,4mol=n_{CO_2}=n_{CH_4}\)
\(\rightarrow V_{CH_4}=0,4.22,4=8,96l\)
\(\rightarrow\%V_{CH_4}=\frac{8,96}{13,56}=66\%\rightarrow\%V_{C_2H_4}=34\%\)
a) \(n_{C_2H_4Br_2}=\dfrac{18,8}{188}=0,1\left(mol\right)\)
PTHH: C2H4 + Br2 --> C2H4Br2
0,1<----0,1<---0,1
=> \(m_{Br_2}=0,1.160=16\left(g\right)\)
b)
\(\%V_{C_2H_4}=\dfrac{0,1.22,4}{4}.100\%=56\%\)
=> \(\%V_{CH_4}=100\%-56\%=44\%\)
c) \(n_{CH_4}=\dfrac{4.44\%}{22,4}=\dfrac{11}{140}\left(mol\right)\)
PTHH: CH4 + 2O2 --to--> CO2 + 2H2O
\(\dfrac{11}{140}\)-->\(\dfrac{11}{70}\)
C2H4 + 3O2 --to--> 2CO2 + 2H2O
0,1---->0,3
=> \(V_{O_2}=\left(\dfrac{11}{70}+0,3\right).22,4=10,24\left(l\right)\)
=> Vkk = 10,24.5 = 51,2 (l)
n Br2=\(\dfrac{32}{160}\)=0,2 mol
C2H2+2Br2->C2H2Br4
0,1------0,2 mol
=>%VC2H2=\(\dfrac{0,1.22,4}{5,6}\).100=40%
=>%VCH4=100-40=60%
=>n CH4=\(\dfrac{5,6-0,1.22,4}{22,4}\)=0,15 mol
CH4+2O2-to>CO2+2H2O
0,15----0,3
C2H2+\(\dfrac{5}{2}\)O2-to>2CO2+H2O
0,1-----0,25 mol
=>VO2=(0,3+0,25).22,4=12,32l
C2H4+Br2-->C2H4Br2
0,05---0,05
nBr2=8\160=0,05 mol
=>VC2H4=0,05.22,4=1,12l
=>%VC2H4=1,12\3,36.100=33,3%
=>%VCH4=66,7%