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Đáp án:
m =32,4g
mddH2SO4 = 49g
Giải thích các bước giải:
a) MgCO3 + H2SO4 → MgSO4 + H2O +CO2 ↑
MgSO4 + 2NaOH → Mg(OH)2 + Na2SO4
$Mg{(OH)_2}\buildrel {to} \over
\longrightarrow MgO + {H_2}O$
b) nCO2 = 2,24 : 22,4 = 0,1mol
nMgCO3 = nCO2 = 0,1 mol
nMgO = 12:40=0,3mol
nMgSO4 = nMgO - nMgCO3 = 0,3 - 0,1 = 0,2mol
m = mMgCO3 + mMgSO4
= 0,1 .84+0,2.120=32,4g
nH2SO4 = nCO2 = 0,1 mol
mH2SO4 = 0,1.98=9,8g
mddH2SO4 = 9,8:20.100=49g
chúc bạn học tốt
\(a.n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\\ Đặt:\left\{{}\begin{matrix}n_{Al}=a\left(mol\right)\\n_{Mg}=b\left(mol\right)\end{matrix}\right.\left(a,b>0\right)\\ 2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\\ Mg+H_2SO_4\rightarrow MgSO_4+H_2\\ \rightarrow\left\{{}\begin{matrix}27a+24b=5,1\\1,5a+b=0,25\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\\ \left\{{}\begin{matrix}\%m_{Al}=\dfrac{27.0,1}{5,1}.100\approx52,941\%\\\%m_{Mg}\approx47,059\%\end{matrix}\right.\)
\(b.m_{ddH_2SO_4}=\dfrac{0,25.98.100}{9,8}=250\left(g\right)\\ m_{ddsau}=m_{Al,Mg}+m_{ddH_2SO_4}-m_{H_2}=5,1+250-0,25.2=254,6\left(g\right)\\ C\%_{ddAl_2\left(SO_4\right)_3}=\dfrac{0,05.342}{254,6}.100\approx6,716\%\\ C\%_{ddMgSO_4}=\dfrac{0,1.120}{254,6}.100\approx4,713\%\)
nH2 = \(\frac{1,68}{22,4}\) = 0,075 (mol)
Mg + 2HCl \(\rightarrow\) MgCl2 + H2\(\uparrow\) (1)
0,075 <--------0,075 <--0,075 (mol)
MgO + 2HCl \(\rightarrow\) MgCl2 + H2O (2)
%mMg= \(\frac{0,075.24}{5,8}\) . 100% = 31,03 %
%m MgO = 68,97%
nMgO = \(\frac{5,8-0,075.24}{40}\) = 0,1 (mol)
Theo pt(2) nMgCl2 = nMgO= 0,1 (mol)
mdd sau pư = 5,8 + 194,35 - 0,075.2 = 200 (g)
C%(MgCl2) = \(\frac{95\left(0,075+0,1\right)}{200}\) . 100% = 8,3125%
\(n_{Fe_2O_3}=\dfrac{8}{160}=0,05\left(mol\right)\)
PTHH: Fe2O3 + 3H2SO4 --> Fe2(SO4)3 + 3H2O
______0,05------>0,15--------->0,05
=> mH2SO4 = 0,15.98 = 14,7(g)
=> \(C\%\left(H_2SO_4\right)=\dfrac{14,7}{100}.100\%=14,7\%\)
\(C\%\left(Fe_2\left(SO_4\right)_3\right)=\dfrac{0,05.400}{8+100}.100\%=18,52\%\)
PTHH: Fe2(SO4)3 + 6NaOH --> 2Fe(OH)3\(\downarrow\) + 3Na2SO4
________0,05----------------------->0,1
=> mFe(OH)3 = 0,1.107=10,7(g)
PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
Ta có: \(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{Fe}=n_{FeCl_2}=n_{H_2}=0,2\left(mol\right)\\n_{HCl}=0,4\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{Fe}=0,2\cdot56=11,2\left(g\right)\\m_{FeCl_2}=0,2\cdot127=25,4\left(g\right)\\m_{ddHCl}=\dfrac{0,4\cdot36,5}{10\%}=146\left(g\right)\\m_{H_2}=0,2\cdot2=0,4\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd}=m_{Fe}+m_{ddHCl}-m_{H_2}=156,8\left(g\right)\) \(\Rightarrow C\%_{FeCl_2}=\dfrac{25,4}{156,8}\cdot100\%\approx16,2\%\)
PTHH: \(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\) (1)
\(MgO+2HCl\rightarrow MgCl_2+H_2O\) (2)
a) Ta có: \(n_{H_2}=\dfrac{22,4}{22,4}=1\left(mol\right)=n_{Mg}\) \(\Rightarrow m_{Mg}=1\cdot24=24\left(g\right)\)
\(\Rightarrow\%m_{Mg}=\dfrac{24}{32}\cdot100\%=75\%\) \(\Rightarrow\%m_{MgO}=25\%\)
b) Theo 2 PTHH: \(\left\{{}\begin{matrix}n_{HCl\left(1\right)}=2n_{Mg}=2mol\\n_{HCl\left(2\right)}=2n_{MgO}=2\cdot\dfrac{32-24}{40}=0,4mol\end{matrix}\right.\)
\(\Rightarrow\Sigma n_{HCl}=2,4mol\) \(\Rightarrow m_{ddHCl}=\dfrac{2,4\cdot36,5}{7,3\%}=1200\left(g\right)\)
c) Theo PTHH: \(\Sigma n_{MgCl_2}=\dfrac{1}{2}\Sigma n_{HCl}=1,2mol\)
\(\Rightarrow\Sigma m_{MgCl_2}=1,2\cdot95=114\left(g\right)\)
Mặt khác: \(m_{H_2}=1\cdot2=2\left(g\right)\)
\(\Rightarrow m_{dd}=m_{hh}+m_{ddHCl}-m_{H_2}=1230\left(g\right)\)
\(\Rightarrow C\%_{MgCl_2}=\dfrac{114}{1230}\cdot100\%\approx9,27\%\)
Gọi x,y,z lần lượt là số mol của Al,Mg,Zn
PT:
2Al + 6HCl--->2AlCl3 + 3H2
x-------3x----------------------1,5x mol
Mg + 2HCl--->MgCl2 + H2
y-----2y----------------------y mol
Zn + 2HCl--->ZnCl2 + H2
z----2z--------------------z mol
b.
Số mol H2: nH2=16,352/22,4=0,73 mol
1,5x+y+z=0,73
27x = 24y =>x=8y/9
=>7y/3 +z =0,73 (*)
27x + 24y + 65z=19,6
27x = 24y
=> 48y + 65z =19,6 (**)
Từ (*),(**)
=>y=0,27 => mMg =6,48 g
z=0,1=>mZn = 6,5 g
x=0,24=>mAl =6,48g
c.
nHCl =2nH2
=>nHCl =2.0,73=1,46 mol
=>V dd=1,46/2=0,73(l)
a)\(PTHH:Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
\(Mg+H_2SO_4\rightarrow MgSO_4+H_2\)
\(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)
\(n_{H_2}=\frac{2,688}{22,4}=0,12\left(mol\right)\)
\(n_{SO^{ }_4}=\frac{1}{2}n_{H_2}=0,06\left(mol\right)\)
\(m_{muối}=m_{KL}+m_{SO_4}=6,44+0,06.96=12,2\left(g\right)\)
b) \(n_{H_2SO_4}=n_{H_2}=0,12\left(mol\right)\)
\(m_{ddH_2SO_4}=\frac{0,12.98}{9,8\%}=120\left(g\right)\)
avt là ...............