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Pt: \(2CH_3COOH+Zn\rightarrow\left(CH_3COO\right)_2Zn+H_2\)
\(n_{\left(CH_3COO\right)_2Zn}=\dfrac{14,2}{183}\approx0.077mol\)
Theo pt: nH2 = n(CH3COO)2Zn = 0,077mol
=> VH2 = 1,7248l
b) Theo pt: nCH3COOH = 2n(CH3COO)2Zn = 0,154 mol
=> CMCH3COOH = 0,154 : 0,25 = 0,616M
\(a,n_{\left(CH_3COO\right)_2Mg}=\dfrac{7,1}{142}=0,05\left(mol\right)\)
PTHH: \(Mg+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Mg+H_2\uparrow\)
0,1<----------------0,05-------------->0,05
\(\rightarrow V_{H_2}=0,05.22,4=1,12\left(l\right)\\ b,C\%_{CH_3COOH}=\dfrac{0,1.60}{100}.100\%=6\%\)
\(c,n_{C_2H_5OH}=\dfrac{6,9}{46}=0,15\left(mol\right)\)
PTHH: \(CH_3COOH+C_2H_5OH\xrightarrow[H_2SO_{4\left(đặc\right)}]{t^o}CH_3COOC_2H_5+H_2O\)
bđ 0,1 0,15
pư 0,1 0,1
spư 0 0,05 0,1
\(\rightarrow m_{este}=0,1.80\%.88=7,04\left(g\right)\)
Bài 5
Fe + 2CH3COOH \(\rightarrow\) (CH3COO)2Fe + H2(1)
nCH3COOH = \(\dfrac{4,5}{60}=0,075mol\)
a) THeo pt: n(CH3COO)2Fe = \(\dfrac{1}{2}.nCH_3COOH=0,0375mol\)
=> m = 6,525g
c) Theo pt (1) nH2 = 1/2nCH3COOH = 0,0375 mol
2H2 + O2 \(\xrightarrow[]{t^o}\) 2H2O
Theo pt: nO2 = 0,5nH2 = 0,01875mol
=> VO2 = 0,42 lít
=> Vkk = 0,42.5 = 2,1 lít
\(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
PT: \(Fe+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Fe+H_2\)
a, Theo PT: \(n_{CH_3COOH}=2n_{Fe}=0,2\left(mol\right)\Rightarrow m_{CH_3COOH}=0,2.60=12\left(g\right)\)
\(\Rightarrow m_{ddCH_3COOH}=\dfrac{12}{10\%}=120\left(g\right)\)
\(n_{H_2}=n_{Fe}=0,1\left(mol\right)\Rightarrow V_{H_2}=0,1.22,4=2,24\left(l\right)\)
b, Theo PT: \(n_{\left(CH_3COO\right)_2Fe}=n_{Fe}=0,1\left(mol\right)\)
Ta có: m dd sau pư = 5,6 + 120 - 0,1.2 = 125,4 (g)
\(\Rightarrow C\%_{\left(CH_3COO\right)_2Fe}=\dfrac{0,1.174}{125,4}.100\%\approx13,88\%\)
Ta có: \(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
PT: \(Fe+2HCl\rightarrow FeCl_2+H_2\)
____0,1______0,2_____0,1____0,1 (mol)
a, \(C_{M_{HCl}}=\dfrac{0,2}{0,15}=\dfrac{4}{3}\left(M\right)\)
\(V_{H_2}=0,1.22,4=2,24\left(l\right)\)
b, \(FeCl_2+2NaOH\rightarrow2NaCl+Fe\left(OH\right)_2\)
Theo PT: \(n_{NaOH}=2n_{FeCl_2}=0,2\left(mol\right)\)
\(\Rightarrow V_{NaOH}=\dfrac{0,2}{2}=0,1\left(l\right)\)
\(n_{Mg}=\dfrac{12}{24}=0,5\left(mol\right)\)
PT: \(Mg+H_2SO_4\rightarrow MgSO_4+H_2\)
a, \(n_{H_2}=n_{Mg}=0,5\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,5.22,4=11,2\left(l\right)\)
b, \(n_{H_2SO_4}=n_{Mg}=0,5\left(mol\right)\)\(\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,5}{0,2}=2,5\left(M\right)\)
Bài 14 :
\(n_{Fe}=\dfrac{8,4}{56}=0,15\left(mol\right)\)
Pt : \(Fe+2HCl\rightarrow FeCl_2+H_2|\)
1 2 1 1
0,15 0,3 0,15 0,15
a) \(n_{H2}=\dfrac{0,15.1}{1}=0,15\left(mol\right)\)
\(V_{H2\left(dktc\right)}=0,15.22,4=3,36\left(l\right)\)
b) \(n_{HCl}=\dfrac{0,15.2}{1}=0,3\left(mol\right)\)
\(V_{ddHCl}=\dfrac{0,3}{2}=0,15\left(l\right)\)
c) \(n_{FeCl2}=\dfrac{0,15.1}{1}=0,15\left(mol\right)\)
\(C_{M_{FeCl2}}=\dfrac{0,15}{0,15}=1\left(M\right)\)
Chúc bạn học tốt
ở đoạn c bạn có ghi nhầm ko à , tại mình cứ thấy nó sai sai
nCH3COOH=48/60=0,8 mol
2CH3COOH + Fe --> (CH3COO)2Fe + H2
0,8 0,4 0,4 mol
=>m(CH3COO)2Fe=0,4*174=69,6 g
2H2 +O2 --> 2H2O
0,4 0,2 mol
=>VO2=0,2*22,4=4,48 lít
=> V không khí =4,48*5=22,4 lít
PT: \(2CH_3COOH+Fe\rightarrow\left(CH_3COO\right)_2Fe+H_2\)
a, Ta có: \(n_{CH_3COOH}=\dfrac{4,8}{60}=0,08\left(mol\right)\)
Theo PT: \(n_{\left(CH_3COO\right)_2Fe}=\dfrac{1}{2}n_{CH_3COOH}=0,04\left(mol\right)\)
\(\Rightarrow m_{\left(CH_3COO\right)_2Fe}=0,04.174=6,96\left(g\right)\)
b, Theo PT: \(n_{H_2}=\dfrac{1}{2}n_{CH_3COOH}=0,04\left(mol\right)\)
PT: \(2H_2+O_2\underrightarrow{t^o}2H_2O\)
___0,04__0,02 (mol)
\(\Rightarrow V_{O_2}=0,02.22,4=0,448\left(l\right)\)
\(\Rightarrow V_{kk}=0,448.5=2,24\left(l\right)\)
Bạn tham khảo nhé!
Mg+2CH3COOH->(CH3COO)2Mg+H2
0,15------0,3-------------0,15-------------0,15
n Mg=\(\dfrac{3,6}{24}\)=0,15 mol
m CH3COOH=24g =>n CH3COOH=\(\dfrac{24}{60}\)=0,6 mol
->CH3COOH dư
=>C% (CH3COO)2Mg=\(\dfrac{0,15.142}{200+3,6-0,15.2}\).100=10,48%
=>C% CH3COOH dư= \(\dfrac{0,3.60}{200+3,6-0,15.2}\).100=8,85%
a) \(n_{\left(CH_3COO\right)_2Mg}=\dfrac{7,1}{142}=0,05\left(mol\right)\)
PTHH: 2CH3COOH + Mg --> (CH3COO)2Mg + H2
0,1<----------------------0,05------->0,05
=> VH2 = 0,05.22,4 = 1,12 (l)
b) \(C_{M\left(dd.CH_3COOH\right)}=\dfrac{0,1}{0,025}=4M\)