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\(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\\ a,Fe+2HCl\rightarrow FeCl_2+H_2\\ n_{HCl}=2.0,2=0,4\left(mol\right)\\ b,m_{ddHCl}=\dfrac{0,4.36,5.100}{20}=73\left(g\right)\\ c,n_{H_2}=n_{FeCl_2}=n_{Fe}=0,2\left(mol\right)\\ m_{ddsau}=11,2+73-0,2.2=83,8\left(g\right)\\ C\%_{ddFeCl_2}=\dfrac{0,2.127}{83,8}.100\approx30,31\%\)
nZn=0,1 mol
Zn +2HCl=> ZnCl2+ H2
0,1 mol =>0,2 mol
=>mHCl=36,5.0,2=7,3g
=>m dd HCl=7,3/14,6%=50g
mdd sau pứ=6,5+50-0,1.2=56,3g
=>C% dd ZnCl2=(0,1.136)/56,3.100%=24,16%
a.b. Zn + 2HCl ---> ZnCl2 + H2 (1)
Theo pt: 65g 73g 136g 2g
Theo đề: 6,5g 7,3g 13,6g
=> mddHCl=\(\frac{7,3.100}{14,6}=50\left(g\right)\)
c. Từ pt (1), ta có: \(C_{\%}=\frac{13,6}{50+6,5}.100\%=24,1\%\)
\(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\\ PTHH:Zn+2HCl\rightarrow ZnCl_2+H_2\\ n_{ZnCl_2}=n_{Zn}=n_{H_2}=0,15\left(mol\right);n_{HCl}=2.0,15=0,3\left(mol\right)\\ a,m=m_{Zn}=0,15.65=9,75\left(g\right)\\ b,C_{MddHCl}=\dfrac{0,3}{0,15}=0,2\left(l\right)\\ c,m_{ZnCl_2}=0,15.136=20,4\left(g\right)\)
\(a,n_{H_2}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\)
PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
0,05<-0,1<------0,05<---0,05
\(b,m_{Fe}=0,05.56=2,8\left(g\right)\\ c,m_{ddHCl}=\dfrac{0,1.36,5}{14,6\%}=25\left(g\right)\\ m_{dd}=25+2,8-0,05.2=27,7\left(g\right)\\ \rightarrow C\%_{FeCl_2}=\dfrac{0,05.127}{27,7}.100\%=22,92\%\)
nAl = 5.4 / 27 = 0.2 (mol)
2Al + 6HCl => 2AlCl3 + 3H2
0.2......0.6............0.2.......0.3
a) VH2 = 0.3 * 22.4 = 6.72 (l)
b) mAlCl3 = 0.2 * 133.5 = 26.7 (g)
c) VddHCl = 0.6 / 1.5 = 0.4 (l)
d) CMAlCl3 = 0.2 / 0.4 = 0.5 (M)
PTHH: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)
Ta có: \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{HCl}=0,6\left(mol\right)\\n_{AlCl_3}=0,2\left(mol\right)\\n_{H_2}=0,3\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,3\cdot22,4=6,72\left(l\right)\\m_{AlCl_3}=0,2\cdot133,5=26,7\left(g\right)\\V_{HCl}=\dfrac{0,6}{1,5}=0,4\left(l\right)=400\left(ml\right)\\C_{M_{AlCl_3}}=\dfrac{0,2}{0,4}=0,5\left(M\right)\end{matrix}\right.\)
a) \(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
PTHH: Fe + 2HCl --> FeCl2 + H2
0,1-->0,2------>0,1--->0,1
=> \(m_{FeCl_2}=0,1.127=12,7\left(g\right)\)
b) mdd sau pư = 5,6 + 200 - 0,1.2 = 205,4 (g)
=> \(C\%=\dfrac{12,7}{205,4}.100\%=6,18\%\)
\(n_{Al}=\dfrac{10,8}{27}=0,4\left(mol\right)\)
PTHH :
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)
0,4 1,2 0,4 0,6
\(a,V_{H_2}=0,6.22,4=13,44\left(l\right)\)
\(b,m_{HCl}=1,2.36,5=43,8\left(g\right)\)
\(c,m_{AlCl_3}=133,5.0,4=53,4\left(g\right)\)
\(m_{ddHCl}=\dfrac{43,8.100}{10}=438\left(g\right)\)
\(m_{ddAlCl_3}=10,8+438-\left(0,6.2\right)=447,6\left(g\right)\)
\(C\%=\dfrac{53,8}{447,6}.100\%\approx12,02\%\)
\(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\)
\(PTHH:Fe+2HCl\rightarrow FeCl_2+H_2\)
(mol)____0,2____0,4____0,2____0,2__
\(a.m_{FeCl_2}=0,2.127=25,4\left(g\right)\)
\(b.C\%_{ddFeCl_2}=\dfrac{m_{ct}}{m_{ddspu}}.100=\dfrac{25,4}{11,2+120-0,2.2}.100=19,4\left(\%\right)\)
\(c.C\%_{ddHCl}=\dfrac{36,5.0,4}{120}.100=12,17\left(\%\right)\)