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a) \(n_{SO_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
PTHH: S + O2 --to--> SO2
0,5<-0,5<------0,5
=> mS = 0,5.32 = 16(g)
=> \(\left\{{}\begin{matrix}\%m_S=\dfrac{16}{22,2}.100\%=72,07\%\\\%m_P=\dfrac{22,2-16}{22,2}.100\%=27,93\%\end{matrix}\right.\)
b) \(n_P=\dfrac{22,2-16}{31}=0,2\left(mol\right)\)
PTHH: 4P + 5O2 --to--> 2P2O5
0,2-->0,25----->0,1
=> \(V_{O_2}=0,25.22,4=5,6\left(l\right)\)
c)
PTHH: 2KClO3 --to--> 2KCl + 3O2
0,5<-------------------0,75
=> \(m_{KClO_3}=0,5.122,5=61,25\left(g\right)\)
a) PTHH:
\(S+O_2\rightarrow\left(t^o\right)SO_2\\ 4P+5O_2\rightarrow\left(t^o\right)2P_2O_5\)
- Chất khí mùi hắc là SO2
- Chất rắn sau phản ứng có m(g) là P2O5
Đặt: nS=a(mol); nP=b(mol) (a,b>0) (nguyên, dương)
\(\Rightarrow\left\{{}\begin{matrix}32a+31b=22,2\\22,4a=11,2\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,5\\b=0,2\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}\%m_S=\dfrac{0,5.32}{22,2}.100\approx72,072\%\\\%m_P\approx100\%-72,072\%\approx27,928\%\end{matrix}\right.\)
b)
\(n_{O_2}=a+\dfrac{5}{4}b=0,5+\dfrac{5}{4}.0,2=0,75\left(mol\right)\\ \Rightarrow V_{O_2\left(đktc\right)}=0,75.22,4=16,8\left(l\right)\)
c)
\(2KClO_3\rightarrow\left(t^o\right)2KCl+3O_2\\ n_{KClO_3}=\dfrac{2}{3}.n_{O_2}=\dfrac{2.0,75}{3}=0,5\left(mol\right)\\ \Rightarrow m_{KClO_3}=122,5.0,5=61,25\left(g\right)\)
a)\(n_{Al}=\dfrac{5,4}{27}=0,2\left(m\right)\)
\(PTHH:4Al+3O_2\underrightarrow{t^o}2Al_2O_3\)
tỉ lệ :4 3 2
số mol :0,2 0,15 0,1
\(V_{O_2}=0,15.22,4=3,36\left(l\right)\)
b)\(m_{Al_2O_3}=0,1.102=10,2\left(g\right)\)
c)\(PTHH:2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
tỉ lệ :2 1 1 1
số mol :0,3 0,15 0,15 0,15
\(m_{KMnO_4}=0,3.126=37,8\left(g\right)\)
\(n_{Na}=\dfrac{3,68}{23}=0,16\left(mol\right)\\ PTHH:4Na+O_2\underrightarrow{t^o}2Na_2O\left(natri.oxit\right)\\ Theo.pt:n_{O_2}=\dfrac{1}{4}n_{Na}=\dfrac{1}{4}.0,16=0,04\left(mol\right)\\ V_{O_2}=0,04.22,4=0,896\left(l\right)\)
a/ PTHH: 4Al + 3O2 ===> 2Al2O3
b/ Áp dụng định luật bảo toàn khối lượng
=> mAl2O3 = mAl + mO2 = 5,4 + 6,4 =11,8 gam
2KMnO4-to>K2MnO4+MnO2+O2
0,3-----------------0,15-----0,15------0,15 mol
n KMnO4=\(\dfrac{47,4}{158}\)=0,3 mol
=>mcr=0,15.197.0,15.87=42,6g
=>VO2=0,15.22,4=3,36l
b) 4P+5O2-to>2P2O5
0,1--------------0,05
nP=\(\dfrac{3,1}{31}\)=0,1 mol
->O2 dư
=>m P2O5=0,05.142=7,1g
mKMnO4 = 47,4/158 = 0,3 (mol)
PTHH: 2KMnO4 -> (t°) K2MnO4 + MnO2 + O2
Mol: 0,3 ---> 0,15 ---> 0,15 ---> 0,15
m = 0,15 . 197 + 0,15 . 87 = 85,2 (g)
V = VO2 = 0,15 . 22,4 = 3,36 (l)
nP = 3,1/31 = 0,1 (mol)
PTHH: 4P + 5O2 -> (t°) 2P2O5
LTL: 0,1/4 < 0,15/5 => O2 dư
nP2O5 = 0,1/2 = 0,05 (mol)
mP2O5 = 0,05 . 142 = 7,1 (g)
a.\(n_{KMnO_4}=\dfrac{m_{KMnO_4}}{M_{KMnO_4}}=\dfrac{3,16}{158}=0,02mol\)
\(2KMnO_4\rightarrow\left(t^o\right)K_2MnO_4+MnO_2+O_2\)
0,02 0,01 ( mol )
\(V_{O_2}=n_{O_2}.22,4=0,01.22,4=0,224l\)
b.
\(4Al+3O_2\rightarrow\left(t^o\right)2Al_2O_3\)
1/75 0,01 1/150 ( mol )
\(m_{Al}=n_{Al}.M_{Al}=\dfrac{1}{75}.27=0,36g\)
\(m_{Al_2O_3}=n_{Al_2O_3}.M_{Al_2O_3}=\dfrac{1}{150}.102=0,68g\)
2KMnO4-to>K2MnO4+MnO2+O2
0,02-------------------------------------0,01
4Al+3O2-to->2Al2O3
\(\dfrac{1}{75}\)---0,01---------\(\dfrac{1}{150}\)
n KMnO4=\(\dfrac{3,16}{158}\)=0,02 mol
=>VO2=0,01.22,4=0,224 l
b)m Al=\(\dfrac{1}{75}\).27=0,36g
=>m Al2O3=\(\dfrac{1}{150}\)102=0,68g
a.\(n_{Al}=\dfrac{m_{Al}}{M_{Al}}=\dfrac{5,4}{27}=0,2mol\)
\(4Al+3O_2\rightarrow\left(t^o\right)2Al_2O_3\)
4 3 2 ( mol )
0,2 0,1
\(m_{Al_2O_3}=n_{Al_2O_3}.M_{Al_2O_3}=0,1.102=10,2g\)
b.\(n_{Al}=\dfrac{m}{M}=\dfrac{5,4}{27}=0,2mol\)
\(n_{O_2}=\dfrac{V}{22,4}=\dfrac{2,24}{22,4}=0,1mol\)
\(4Al+3O_2\rightarrow\left(t^o\right)2Al_2O_3\)
4 3 2
0,2 < 0,1 ( mol )
0,1 1/15
\(m_{Al_2O_3}=n.M=\dfrac{1}{15}.102=6,8g\)
a) \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)
PTHH : 4Al + 3O2 -> 2Al2O3
0,2 0,1
\(m_{Al_2O_3}=0,1.102=10,2\left(g\right)\)
b. \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)
\(n_{O_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
PTHH : 4Al + 3O2 -> 2Al2O3
0,1 \(\dfrac{0,2}{3}\)
Xét tỉ lệ : \(\dfrac{0,2}{4}>\dfrac{0,1}{3}\) => Al dư , O2 đủ
\(m_{Al_2O_3}=\dfrac{0,2}{3}.102=6,8\left(g\right)\)