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nH2=0,15 mol
2Al+3H2SO4=>Al2(SO4)3+3H2
0,1 mol<= 0,15 mol
mAl=0,1.27=2,7g
nAl2(SO4)3=0,05 mol
=>mAl2(SO4)3=342.0,05=17,1g
nH2SO4=0,15 mol=>mH2SO4=14,7
mdd H2SO4=14,7/10%=147g
mdd sau pứ=2,7+147-0,15.2=149,4g
C%dd Al2(SO4)3=17,1/149,4.100%=11,45%
- Đặt \(\left\{{}\begin{matrix}n_{Al}=a\left(mol\right)\\n_{Mg}=b\left(mol\right)\end{matrix}\right.\Rightarrow27a+24b=10,2\left(1\right)\)
Khí thu được sau p/ứ là khí H2: \(n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)
2 3 (mol)
a 3/2 a (mol)
\(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)
1 1 (mol)
b b (mol)
Từ hai PTHH trên ta có: \(\dfrac{3}{2}a+b=0,5\left(2\right)\)
\(\left(1\right),\left(2\right)\) ta có hệ: \(\left\{{}\begin{matrix}27a+24b=10,2\\\dfrac{3}{2}a+b=0,5\end{matrix}\right.\)
Giải ra ta có \(\left\{{}\begin{matrix}a=0,2\left(mol\right)\\b=0,2\left(mol\right)\end{matrix}\right.\)
a) \(\%Al=\dfrac{m_{Al}}{m_{hh}}.100\%=\dfrac{0,2.27}{10,2}.100\%\approx52,94\%\)
\(\%Mg=100\%-\%Al=100\%-52,94=47,06\%\)
b)
\(3H_2+Fe_2O_3\rightarrow^{t^0}2Fe+3H_2O\)
3 1 2 (mol)
0,5 1/6 1/3 (mol)
\(m_{Fe}=\dfrac{1}{3}.56=\dfrac{56}{3}\left(g\right)\)
\(m_{Fe_2O_3\left(pứ\right)}=\dfrac{1}{6}.160=\dfrac{80}{3}\left(g\right)\)
\(m_{Fe_2O_3\left(dư\right)}=60-m_{Fe}=60-\dfrac{56}{3}=\dfrac{124}{3}\left(g\right)\)
\(a=\dfrac{124}{3}+\dfrac{80}{3}=68\left(g\right)\)
Sửa thành 2,24 gam cho số đẹp bạn nhé!
Ta có: \(n_{Fe}=\dfrac{2,24}{56}=0,04\left(mol\right)\)
PT: \(Fe+2HCl\rightarrow FeCl_2+H_2\)
___0,04__0,08____0,04__0,04 (mol)
Ta có: \(m_{HCl}=0,08.36,5=2,92\left(g\right)\)
\(\Rightarrow m_{ddHCl}=\dfrac{2,92}{14,6\%}=20\left(g\right)\)
Ta có: m dd sau pư = mFe + m dd HCl - mH2 = 2,24 + 20 - 0,04.2 = 22,16 (g)
\(\Rightarrow C\%_{FeCl_2}=\dfrac{0,04.127}{22,16}.100\%\approx22,9\%\)
Bạn tham khảo nhé!
\(a.2Al+3H_2SO_4->Al_2\left(SO_4\right)_3+3H_2\\ n_{H_2SO_4}=\dfrac{100.29,4}{98.100}=0,3mol\\ m_{Al}=\dfrac{2}{3}.27.0,3=5,4g=m\\ V_{H_2}=22,4.0,3=6,72L\\ m_{ddsau}=m+100-0,3.2=104,8g\\b. C\%=\dfrac{342.0,1}{104,8}.100\%=32,63\%\)
a)
PTHH: 2Al+3H\(_2\)SO\(_4\) → Al\(_2\)(SO4)\(_3\)+3H\(_2\)
n\(_{H_2SO_4}\) = \(\dfrac{100.29,4\%}{98}\) = 0,3 (mol)
Theo PT: n\(_{H_2}\)= n\(_{H_2SO_4}\)= 0,3 (mol)
\(\Rightarrow\)V\(_{H_2}\)= 0,3.22,4 = 6,72(l)
Theo PT: n\(_{Al}\) = \(\dfrac{2}{3}\)n\(_{H_2}\) = 0,2 (mol)
\(\Rightarrow\)m=m\(_{Al}\) = 0,2.27 = 5,4 (g)
b)
m\(_{dd}\) = 5,4+100−0,3.2 = 104,8 (g)
Theo PT: n\(_{Al_2\left(SO_4\right)_3}\) = \(\dfrac{1}{2}\)n\(_{Al}\) = 0,1 (mol)
\(\Rightarrow\) C%\(_{Al_2\left(SO_4\right)_3}\) = \(\dfrac{0,1.342}{104,8}\).100% = 32,63%
\(n_{Al_2O_3}=\dfrac{10,2}{102}=0,1(mol)\\ Al_2O_3+3H_2SO_4\to Al_2(SO_4)_3+3H_2O\\ \Rightarrow n_{H_2SO_4}=0,3(mol)n_{Al_2(SO_4)_3}=0,1(mol)\\ \Rightarrow C\%_{H_2SO_4}=\dfrac{0,3.98}{300}.100\%=9,8\%\\ \Rightarrow C\%_{Al_2(SO_4)_3}=\dfrac{0,1.342}{10,2+300}.100\%=11,03\%\)
Sai rồi bạn nhé !