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\(n_{Zn}=\dfrac{9,75}{65}=0,15\left(mol\right)\\ pthh:Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)
0,15 0,15 0,15
\(V_{H_2}=0,15.22,4=3,36\left(l\right)\\
C_M=\dfrac{0,15}{0,1}=1,5M\)
\(a,PTHH:2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\\ n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\\ \Rightarrow n_{Al}=\dfrac{2}{3}n_{H_2}=0,1\left(mol\right)\\ \Rightarrow m_{Al}=0,1\cdot27=2,7\left(g\right)\\ b,n_{H_2SO_4}=n_{H_2}=0,15\left(mol\right)\\ \Rightarrow m_{H_2SO_4}=0,15\cdot98=14,7\left(g\right)\\ c,n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{3}n_{H_2}=0,05\left(mol\right)\\ \Rightarrow m_{Al_2\left(SO_4\right)_3}=0,05\cdot342=17,1\left(g\right)\)
Gọi x,y lần lượt là số mol của Al, Fe
nH2 = \(\dfrac{8,96}{22,4}\)=0,4 mol
Pt: 2Al + 3H2SO4 --> Al2(SO4)3 + 3H2
......x.................................0,5x...........1,5x
.....Fe + H2SO4 --> FeSO4 + H2
.......y..........................y............y
Ta có hệ pt:
{27x+56y=11
1,5x+y=0,4
⇔x=0,2, y=0,1
% mAl = \(\dfrac{0,2.27}{11}\).100%=49,1%
% mFe = \(\dfrac{0,1.56}{11}\).100%=50,9%
mAl2(SO4)3 = 0,5x . 342 = 0,5 . 0,2 . 342 = 34,2 (g)
mFeSO4 = 152y = 152 . 0,1 = 15,2 (g)
Gọi CTTQ: MxOy
Pt: MxOy + yH2 --to--> xM + yH2O
\(\dfrac{0,4}{y}\)<-------0,4
Ta có: 232,2=\(\dfrac{0,4}{y}\)(56x+16y)
⇔23,2=\(\dfrac{22,4x}{y}\)+6,4
⇔\(\dfrac{22,4x}{y}\)=16,8
⇔22,4x=16,8y
⇔x:y=3:4
Vậy CTHH của oxit: Fe3O4
\(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
PTHH: Zn + H2SO4 ---> ZnSO4 + H2
0,1 <----------------------------- 0,1
=> mZn = 0,1.65 = 6,5 (g)
\(a.Zn+2HCl\rightarrow ZnCl_2+H_2\\ n_{Zn}=n_{ZnCl_2}=n_{H_2}=0,25\left(mol\right)\\ \Rightarrow m_{Zn}=0,25.65=16,25\left(g\right)\\ m_{ZnCl_2}=0,25.136=34\left(g\right)\\ b.FeO+H_2-^{t^o}\rightarrow Fe+H_2O\\ Tacó:n_{Fe}=n_{H_2}=0,25\left(mol\right)\\ \Rightarrow m_{Fe}=0,25.56=14\left(g\right)\)
\(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
\(PTHH:Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)
(mol)_____0,2____0,2______0,2____0,2__
\(a.V_{H_2}=22,4.0,2=4,48\left(l\right)\)
\(b.m_{ddH_2SO_4}=\dfrac{0,2.98.100}{24,5}=80\left(g\right)\)
\(c.m_{ddspu}=13+80-0,2.2=92,6\left(g\right)\\ \Rightarrow C\%_{ddspu}=\dfrac{0,2.136}{92,6}.100=29,4\left(\%\right)\)
Đặt :
nAl = a (mol)
nFe = b(mol)
mX = 27a + 56b = 16.6 (g) (1)
2Al + 3H2SO4 => Al2(SO4)3 + 3H2
Fe + H2SO4 => FeSO4 + H2
mM = 342a + 152b = 64.6 (g) (2)
(1) , (2):
a = 4/55
b = 23/88
%Al = (4/55*27) / 16.6 *100% = 11.83%
%Fe = 100 - 11.83 = 88.17%
nH2 = 3/2a + b = 3/2 * 4/55 + 23/88 = 163/440 (mol)
VH2 = 8.3 (l)
a) Zn + 2HCl --> ZnCl2 + H2
b) \(n_{ZnCl_2}=\dfrac{13,6}{136}=0,1\left(mol\right)\)
PTHH: Zn + 2HCl --> ZnCl2 + H2
0,1<-----------0,1----->0,1
=> mZn = 0,1.65 = 6,5 (g)
b) VH2 = 0,1.22,4 = 2,24 (l)
1) \(n_{O_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
Theo ĐLBTKL: m = 4,4 + 1,8 - 0,15.32 = 1,4 (g)
2)
\(n_{Mg}=\dfrac{1,2}{24}=0,05\left(mol\right)\)
PTHH: Mg + H2SO4 --> MgSO4 + H2
0,05------------------------->0,05
=> VH2 = 0,05.22,4 = 1,12 (l)
mO2 = ( 3,36 : 22,4 ) . 32 = 4,8 (g)
ADDLBTKL ta co :
mA + mO2 = mCO2 + mH2O
=> mA = mCO2 + mH2O - mO2
= 4,4 + 1,8 - 4,8 = 1,4 (g)
=> m= 1,4 (g)
2
nMg = 1,2 : 24 = 0,05 (mol)
pthh : Mg +H2SO4 ---> MgSO4 + H2
0,05--------------------------->0,05(mol)
=> VH2 = 0,05 .22,4 = 1,12 (l)
\(n_{H_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)
PTHH: Zn + H2SO4 --> ZnSO4 + H2
=> nZn = 0,4 (mol)
=> mZn = 0,4.65 = 26(g)
Zn+H2SO4->ZnSO4+H2
0,4------------------------0,4 mol
n H2=\(\dfrac{8,96}{22,4}\)=0,4 mol
=>a=m Zn=0,4.65=26g