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\(n_{P_2O_5}=\dfrac{99,4}{142}=0,7\left(mol\right)\)
\(P_2O_5+3H_2O\rightarrow2H_3PO_4\)
0,7 2,1 1,4
a, \(m_{H_3PO_4}=1,4.98=137,2\left(g\right)\)
\(m_{ddH_3PO_4}=99,4+500=599,4\left(g\right)\)
Kl nước trong dd A :
\(m_{H_2O}=599,4-137,2=462,2\left(g\right)\)
\(b,C\%_{H_3PO_4}=\dfrac{137,2}{599,4}.100\%\approx22,89\%\)
\(c,C_M=\dfrac{n}{V}=\dfrac{1,4}{0,5}=2,8M\)
Bổ sung: \(D_{HCl}=1,18\left(g/ml\right)\)
a) PTHH: \(MgO+2HCl\rightarrow MgCl_2+H_2O\)
b) Ta có: \(\left\{{}\begin{matrix}n_{MgO}=\dfrac{2}{40}=0,05\left(mol\right)\\n_{HCl}=\dfrac{100\cdot1,18\cdot20\%}{36,5}=\dfrac{236}{365}\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,05}{1}< \dfrac{\dfrac{236}{365}}{2}\) \(\Rightarrow\) HCl còn dư, MgO p/ứ hết
\(\Rightarrow n_{MgCl_2}=0,05\left(mol\right)\) \(\Rightarrow C_{M_{MgCl_2}}=\dfrac{0,05}{0,1}=0,5\left(M\right)\)
\(Na+H_2O->NaOH+\dfrac{1}{2}H_2\\ a.n_{Na}=\dfrac{m_1}{23}\left(mol\right)\\ m_{ddsau}=\dfrac{m_1}{23}+m_2-\dfrac{m_1}{46}=\dfrac{m_1}{46}+m_2\left(g\right)\\ C\%_B=\dfrac{\dfrac{40}{23}m_1}{\dfrac{m_1}{46}+m_2}\cdot100\%.\\ b.C_M=\dfrac{10dC\%}{M}=10\cdot1,2\cdot\dfrac{0,05}{40}=0,015\left(M\right)\)
\(Na+H_2O->NaOH+\dfrac{1}{2}H_2\\ a.n_{Na}=\dfrac{m_1}{23}\left(mol\right)\\ m_{ddsau}=m_1+m_2-\dfrac{m_1}{23}=\dfrac{22}{23}m_1+m_2\left(g\right)\\ C\%_B=\dfrac{\dfrac{40}{23}m_1}{\dfrac{22}{23}m_1+m_2}\cdot100\%.\\ b.C_M=\dfrac{10dC\%}{M}=10\cdot1,2\cdot\dfrac{0,05}{40}=0,015\left(M\right)\)
\(a.Fe+2HCl\rightarrow FeCl_2+H_2\\ b.n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\\ TheoPT:n_{HCl}=2n_{Fe}=0,2\left(mol\right)\\ \Rightarrow CM_{HCl}=\dfrac{0,2}{0,2}=1M\)
a, Ta có: \(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
PT: \(M+H_2SO_4\rightarrow MSO_4+H_2\)
Theo PT: \(n_M=n_{H_2}=0,2\left(mol\right)\)
\(\Rightarrow M_M=\dfrac{11,2}{0,2}=56\left(g/mol\right)\)
→ M là Fe.
b, Theo PT: \(n_{FeSO_4}=n_{H_2SO_4\left(pư\right)}=n_{H_2}=0,2\left(mol\right)\)
⇒ nH2SO4 dư = 0,5.1 - 0,2 = 0,3 (mol)
\(\Rightarrow\left\{{}\begin{matrix}C_{M_{H_2SO_4\left(dư\right)}}=\dfrac{0,3}{0,5}=0,6\left(M\right)\\C_{M_{FeSO_4}}=\dfrac{0,2}{0,5}=0,4\left(M\right)\end{matrix}\right.\)
c, Ta có: \(n_{FeSO_4.7H_2O}=n_{FeSO_4}=0,2\left(mol\right)\)
\(\Rightarrow m_{FeSO_4.7H_2O}=0,2.278=55,6\left(g\right)\)
a)
C% CuSO4 = 16/(16 + 184) .100% = 8%
b)
n NaOH = 20/40 = 0,5(mol)
CM NaOH = 0,5/4 = 0,125M
a, PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
Gọi: \(\left\{{}\begin{matrix}n_{Zn}=x\left(mol\right)\\n_{Al}=y\left(mol\right)\end{matrix}\right.\) ⇒ 65x + 27y = 17,05 (1)
Ta có: \(n_{H_2}=\dfrac{9,52}{22,4}=0,425\left(mol\right)\)
Theo PT: \(n_{H_2}=n_{Zn}+\dfrac{3}{2}n_{Al}=x+\dfrac{3}{2}y=0,425\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{Zn}=0,2\left(mol\right)\\n_{Al}=0,15\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Zn}=0,2.65=13\left(g\right)\\m_{Al}=0,15.27=4,05\left(g\right)\end{matrix}\right.\)
b, Theo PT: \(\left\{{}\begin{matrix}n_{ZnCl_2}=n_{Zn}=0,2\left(mol\right)\\n_{AlCl_3}=n_{Al}=0,15\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}C_{M_{ZnCl_2}}=\dfrac{0,2}{0,5}=0,4\left(M\right)\\C_{M_{AlCl_3}}=\dfrac{0,15}{0,5}=0,3\left(M\right)\end{matrix}\right.\)
c, Ta có: m dd HCl = 1,05.500 = 525 (g)
m dd sau pư = mhh + m dd HCl - mH2 = 541,2 (g)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{ZnCl_2}=\dfrac{0,2.136}{541,2}.100\%\approx5,03\%\\C\%_{AlCl_3}=\dfrac{0,15.133,5}{541,2}.100\%\approx3,7\%\end{matrix}\right.\)
nP2O5 = 14,2/142 = 0,1 (mol)
PTHH: P2O5 + 3H2O -> 2H3PO4
Mol: 0,1 ---> 0,3 ---> 0,2
CMddH3PO4 = 0,2/0,5 = 0,4M