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1) Gọi số mol P2O5 là a (mol)
PTHH: P2O5 + 3H2O --> 2H3PO4
a----------------->2a
\(m_{H_3PO_4\left(tổng\right)}=98.2a+\dfrac{10.200}{100}=196a+20\left(g\right)\)
mdd sau pư = 142a + 200 (g)
=> \(C\%_{dd.sau.pư}=\dfrac{196a+20}{142a+200}.100\%=17,93\%\)
=> a = 0,093 (mol)
=> mP2O5 = 0,093.142 = 13,206 (g)
2)
a) \(n_{O_2}=\dfrac{10,08}{22,4}=0,45\left(mol\right)\)
PTHH: 2KMnO4 --to--> K2MnO4 + MnO2 + O2
0,9<-----------0,45<----0,45<----0,45
=> \(m_{KMnO_4\left(Pư\right)}=0,9.158=142,2\left(g\right)\)
=> \(m_{KMnO_4\left(tt\right)}=\dfrac{142,2.100}{80}=177,75\left(g\right)\)
=> \(m=\dfrac{177,75.100}{90}=197,5\left(g\right)\)
b)
X \(\left\{{}\begin{matrix}m_{K_2MnO_4}=0,45.197=88,65\left(g\right)\\m_{MnO_2}=0,45.87=39,15\left(g\right)\\m_{KMnO_4}=177,75-142,2=35,55\left(g\right)\\m_{tạp.chất}=197,5.10\%=19,75\left(g\right)\end{matrix}\right.\)
\(a) n_P = \dfrac{12,4}{31} = 0,4(mol)\\ 4P + 5O_2 \xrightarrow{t^o} 2P_2O_5\\ n_{P_2O_5} = \dfrac{1}{2}n_P = 0,2(mol)\\ \Rightarrow m_{P_2O_5} = 0,2.142 = 28,4(gam)\\ b) P_2O_5 + 3H_2O \to 2H_3PO_4\\ n_{H_3PO_4} = 2n_{P_2O_5} = 0,4(mol)\\ m_{dd} = 28,4 + 200 = 228,4(gam)\\ \Rightarrow C\%_{H_3PO_4} = \dfrac{0,4.98}{228,4}.100\% = 17,16\%\)
a, \(n_{P_2O_5}=\dfrac{21,3}{142}=0,15\left(mol\right)\)
PT: \(P_2O_5+3H_2O\rightarrow2H_3PO_4\)
Theo PT: \(n_{H_3PO_4}=2n_{P_2O_5}=0,3\left(mol\right)\)
\(\Rightarrow m_{H_3PO_4}=0,3.98=29,4\left(g\right)\)
b, m dd sau pư = 21,3 + 300 = 321,3 (g)
\(\Rightarrow C\%_{H_3PO_4}=\dfrac{29,4}{321,3}.100\%\approx9,15\%\)
\(3CaO+2H_3PO_4\rightarrow Ca_3\left(PO_4\right)_2+3H_2O\)
\(nCaO=\dfrac{240}{56}=4,3\left(mol\right)4,3\)
\(nH_3PO_4=2,9\left(mol\right)\)
mH2PO4 = 2,9 . 97=281,3(g)
a) 4P + 5O2 --to--> 2P2O5
b) \(n_P=\dfrac{24,8}{31}=0,8\left(mol\right)\)
PTHH: 4P + 5O2 --to--> 2P2O5
0,8--------------->0,4
=> mP2O5 = 0,4.142 = 56,8 (g)
c)
PTHH: P2O5 + 3H2O --> 2H3PO4
0,4--------------->0,8
=> mH3PO4 = 0,8.98 = 78,4 (g)
\(n_{H_2SO_4}=\dfrac{200.7,35\%}{98}=0,15\left(mol\right)\)
PTHH: 2NaOH + H2SO4 --> Na2SO4 + 2H2O
0,3<----0,15-------->0,15
=> mNaOH = 0,3.40 = 12 (g)
\(m_{dd.NaOH}=\dfrac{12.100}{8}=150\left(g\right)\)
mdd sau pư = 200 + 150 = 350 (g)
mNa2SO4 = 0,15.142 = 21,3 (g)
=> \(C\%_{dd.Na_2SO_4}=\dfrac{21,3}{350}.100\%=6,086\%\)
Bài 1:
Ta có: \(n_{HCl}=0,2.0,5=0,1\left(mol\right)\)
BTNT H, có: \(n_{HCl}=2n_{H_2O}\Rightarrow n_{H_2O}=0,05\left(mol\right)\)
Theo ĐL BTKL, có: m oxit + mHCl = mmuối + mH2O
⇒ mmuối = 2,8 + 0,1.36,5 - 0,05.18 = 5,55 (g)
Bài 2:
\(m_{KOH}=200.5,6\%=11,2\left(g\right)\Rightarrow n_{KOH}=\dfrac{11,2}{56}=0,2\left(mol\right)\)
PT: \(2KOH+CuCl_2\rightarrow2KCl+Cu\left(OH\right)_2\)
Theo PT: \(n_{Cu\left(OH\right)_2}=\dfrac{1}{2}n_{KOH}=0,1\left(mol\right)\)
\(\Rightarrow m_{Cu\left(OH\right)_2}=0,1.98=9,8\left(g\right)\)
ớ chất sản phẩm la H4P2O7-axitđiphotphoric chứ
1) Gọi số mol P2O5 là a (mol)
PTHH: P2O5 + 3H2O --> 2H3PO4
a----------------->2a
mH3PO4(tổng)=98.2a+10.200100=196a+20(g)��3��4(�ổ��)=98.2�+10.200100=196�+20(�)
mdd sau pư = 142a + 200 (g)
=> C%dd.sau.pư=196a+20142a+200.100%=18%�%��.���.�ư=196�+20142�+200.100%=18
=> a = 0.094 mol)
=> mP2O5 = 0,094.142 = 13.348(g)