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\(m_O=6-4.2=1.8\left(g\right)\)
\(n_{Fe}=\dfrac{4.2}{56}=0.075\left(mol\right)\)
\(n_O=\dfrac{1.8}{16}=0.1125\left(mol\right)\)
\(n_{Fe}:n_O=0.075:0.1125=2:3\)
\(CT:Fe_2O_3\)
\(n_{FeCl_2}=\dfrac{25.4}{127}=0.2\left(mol\right)\)
\(n_{H_2O}=\dfrac{5.4}{18}=0.3\left(mol\right)\)
\(Fe_xO_y+yH_2\underrightarrow{t^0}xFe+yH_2O\)
...........................\(x\) ..........\(y\)
...........................\(0.2\) ......\(0.3\)
\(\Rightarrow0.3x=0.2y\)
\(\Rightarrow\dfrac{x}{y}=\dfrac{0.2}{0.3}=\dfrac{2}{3}\)
\(CT:Fe_2O_3\)
\(m_{Fe_2O_3}=0.2\cdot2\cdot160=64\left(g\right)\)
\(n_{H_2O}=\dfrac{5,4}{18}=0,3\left(mol\right)\)
Bảo toàn O: \(n_{O\left(oxit\right)}=n_{H_2O}=0,3\left(mol\right)\)
\(n_{FeCl_2}=\dfrac{25,4}{127}=0,2\left(mol\right)\)
PTHH: Fe + 2HCl ---> FeCl2 + H2
0,2 <-------------- 0,2
CTHH của oxit FexOy
=> x : y = 0,2 : 0,3 = 2 : 3
CTHH Fe2O3
nH2=4/2=2(mol)
PTHH: Fe3O4 + 4 H2 -to-> 3 Fe + 4 H2O
nFe= 3/4. nH2= 3/4 . 2= 1,5(mol)
=>mFe= 1,5. 56= 84(g)
\(n_{FeO}=\dfrac{3.2}{72}=\dfrac{2}{45}\left(mol\right)\)
\(FeO+H_2\underrightarrow{^{^{t^0}}}Fe+H_2O\)
\(\dfrac{2}{45}....\dfrac{2}{45}....\dfrac{2}{45}\)
\(V_{H_2}=\dfrac{2}{45}\cdot22.4=1\left(l\right)\)
\(Fe+\dfrac{3}{2}Cl_2\underrightarrow{^{t^0}}FeCl_3\)
\(\dfrac{2}{45}.............\dfrac{2}{45}\)
\(m_{FeCl_3}=\dfrac{2}{45}\cdot162.5=7.22\left(g\right)\)
Oxit sắt : FexOy
\(CO_2 + Ca(OH)_2 \to CaCO_3 + H_2O\\ n_{CO_2} = n_{CaCO_3} =\dfrac{22,5}{100} = 0,225(mol)\\ Fe_xO_y + yCO \xrightarrow{t^o} xFe + yCO_2\\ n_{oxit} = \dfrac{n_{CO_2}}{y} = \dfrac{0,225}{y}(mol)\\ \Rightarrow \dfrac{0,225}{y}(56x + 16y) = 12\\ \Rightarrow \dfrac{x}{y} = \dfrac{2}{3}\)
Vậy CTHH của oxit : Fe2O3
\(CT:Fe_xO_y\)
\(Fe_xO_y+yH_2\underrightarrow{^{t^o}}xFe+yH_2O\left(1\right)\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\left(2\right)\)
\(n_{Fe}=n_{H_2\left(2\right)}=\dfrac{4.032}{22.4}=0.18\left(mol\right)\)
\(n_{H_2\left(1\right)}=\dfrac{y}{x}\cdot n_{Fe}=\dfrac{5.376}{22.4}=0.24\left(mol\right)\)
\(\Leftrightarrow\dfrac{y}{x}\cdot0.18=0.24\)
\(\Leftrightarrow\dfrac{x}{y}=\dfrac{3}{4}\)
\(CT:Fe_3O_4\)
\(m_{Fe_3O_4}=\dfrac{0.18}{3}\cdot232=13.92\left(g\right)\)
a, \(Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)
b, \(n_{Fe}=\dfrac{24}{56}=\dfrac{3}{7}\left(mol\right)\)
Theo PT: \(n_{Fe_2O_3}=\dfrac{1}{2}n_{Fe}=\dfrac{3}{14}\left(mol\right)\Rightarrow m_{Fe_2O_3}=\dfrac{3}{14}.160=\dfrac{240}{7}\left(g\right)\)
c, Theo PT: \(n_{H_2}=\dfrac{3}{2}n_{Fe}=\dfrac{9}{14}\left(mol\right)\Rightarrow V_{H_2}=\dfrac{9}{14}.22,4=14,4\left(l\right)\)
\(n_{Fe}=\dfrac{m}{M}=\dfrac{24}{56}\approx0,43\left(mol\right)\\ a.PTHH:Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)
2 3 2 3
0,43 0,645 0,45 0,645
\(b.m_{Fe_2O_3}=n.M=0,43.\left(56.2+16.3\right)=68,8\left(g\right)\\ c.V_{H_2}=n.24,79=0,645.24,79=15,98955\left(l\right).\)
Đặt công thức phân tử của oxit sắt là F e x O y (sắt có hóa trị 2x/y)