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\(a,n_{CaCO_3}=\dfrac{200}{100}=2\left(mol\right)\\ Ca\left(OH\right)_2+CO_2\rightarrow CaCO_3+H_2O\)
2 2
\(Fe_2O_3+3CO\underrightarrow{t^o}2Fe+3CO_2\)
\(\dfrac{1}{6}\) 2 \(\dfrac{2}{3}\) 2
\(n_{Fe\left(thu.được\right)}=\dfrac{266}{56}=4,75\left(mol\right)\)
\(\rightarrow n_{Fe\left(H_2\right)}=4,75-\dfrac{2}{3}=\dfrac{49}{12}\left(mol\right)\)
\(Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)
\(\dfrac{49}{24}\) 6,125 \(\dfrac{49}{12}\)
\(\rightarrow\left\{{}\begin{matrix}V_{CO}=2.22,4=44,8\left(l\right)\\V_{H_2}=6,125.22,4=137,2\left(l\right)\\m_{Fe_2O_3}=\left(\dfrac{1}{6}+\dfrac{49}{24}\right).160=\dfrac{1060}{3}\left(g\right)\end{matrix}\right.\)
TL:
Tham khảo nhé:
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@tuantuthan
HT
\(n_{CaCO_3}=\dfrac{200}{100}=2\left(mol\right)\)
PTHH: CO2 + Ca(OH)2 ---> CaCO3 + H2O
2 2
\(n_{Fe}=\dfrac{266}{56}=4,75\left(mol\right)\)
PTHH:
Fe2O3 + 3CO --to--> 3CO2 + 2Fe
\(\dfrac{1}{3}\) 2 2 \(\dfrac{2}{3}\)
=> nFe (H2) = \(4,75-\dfrac{2}{3}=\dfrac{49}{12}\left(mol\right)\)
Fe2O3 + 3H2 --to--> 2Fe + 3H2O
\(\dfrac{49}{24}\) 6,125 \(\dfrac{49}{12}\)
\(\rightarrow\left\{{}\begin{matrix}V_{CO}=2.22,4=44,8\left(l\right)\\V_{H_2}=6,125.22,4=137,2\left(l\right)\\m_{Fe_2O_3}=\left(\dfrac{1}{3}+\dfrac{49}{24}\right).160=380\left(g\right)\end{matrix}\right.\)
\(nFeO=\dfrac{16}{56+16}=\dfrac{2}{9}\left(mol\right)\)
\(FeO+H_2\rightarrow Fe+H_2O\)
2/9 2/9 2/9 2/9
\(mFe=\dfrac{2}{9}.56=12,4\left(g\right)\)
\(VH_2=\dfrac{2}{9}.22,4=4,98\left(l\right)\)
a, \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
b, \(n_{Fe}=\dfrac{16,8}{56}=0,3\left(mol\right)\)
Theo PT: \(n_{O_2}=\dfrac{2}{3}n_{Fe}=0,2\left(mol\right)\Rightarrow V_{O_2}=0,2.22,4=4,48\left(l\right)\)
\(n_{Fe_3O_4}=\dfrac{1}{3}n_{Fe}=0,1\left(mol\right)\Rightarrow m_{Fe_3O_4}=0,1.232=23,2\left(g\right)\)
c, \(n_{CuO}=\dfrac{16}{80}=0,2\left(mol\right)\)
PT: \(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
Xét tỉ lệ: \(\dfrac{0,2}{1}< \dfrac{0,3}{1}\), ta được H2 dư.
Theo PT: \(n_{Cu}=n_{CuO}=0,2\left(mol\right)\Rightarrow m_{Cu}=0,2.64=12,8\left(g\right)\)
số oxh của Fe cả quá trình k đổi..bảo toàn e =>nCaC03=nC02=n0=n02/2=0,05 mol