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PTHH: \(2CO+O_2\underrightarrow{t^o}2CO_2\) (1)
\(2H_2+O_2\underrightarrow{t^o}2H_2O\) (2)
Ta có: \(\left\{{}\begin{matrix}n_{CO_2}=n_{CO}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\Rightarrow n_{O_2\left(1\right)}=0,1\left(mol\right)\\\Sigma n_{O_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{O_2\left(2\right)}=0,2\left(mol\right)\) \(\Rightarrow n_{H_2}=0,4\left(mol\right)\)
\(\Rightarrow\%V_{H_2}=\dfrac{0,4}{0,4+0,2}\cdot100\%\approx66,67\%\)
\(\Rightarrow\%V_{CO}=33,33\%\)
nO2(tổng)=0,3(mol); nCO2=0,2(mol)
CO + 1/2 O2 -to-> CO2 (1)
0,2<----0,1<-------0,2(mol)
H2 + 1/2 O2 -to-> H2O (2)
0,4<---0,2<-------0,4(mol)
nO2(2)= nO2(tổng)- nO2(1)=0,3-0,1=0,2(mol)
Vì số mol tỉ lệ thuận thể tích:
=> %V(CO/hh)= [0,2/(0.2+0,4)].100=33,333%
=>%V(H2/hh)=100%-33,333%=66,667%
\(n_{CO_2}=\dfrac{4,958}{24,79}=0,2\left(mol\right)\\ n_{O_2}=\dfrac{7,437}{24,79}=0,3\left(mol\right)\)
PTHH:
2CO + O2 --to--> 2CO2
0,2 0,1 0,2
-> nO2 = 0,3 - 0,1 = 0,2 (mol)
2H2 + O2 --to--> 2H2O
0,4 0,2
\(\rightarrow n_{hhkhí}=0,1+0,4=0,5\left(mol\right)\\ \rightarrow\left\{{}\begin{matrix}\%V_{CO}=\dfrac{0,2}{0,5}=40\%\\\%V_{H_2}=100\%-40\%=60\%\end{matrix}\right.\)
\(n_{O_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
\(n_{CO_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
\(CO+\dfrac{1}{2}O_2\underrightarrow{t^o}CO_2\)
0,3 0,3
\(n_{H_2}=0,5-0,3=0,2\left(mol\right)\)
\(\%_{V_{CO}}=\dfrac{0,3.22,4.100}{11,2}=60\%\)
\(\%_{V_{H_2}}=\dfrac{0,2.22,4.100}{11,2}=40\%\)
☕T.Lam
\(2CO + O_2 \xrightarrow{t^o} 2CO_2(1)\\ 2H_2 + O_2 \xrightarrow{t^o} 2H_2O(2)\\ n_{CO} = n_{CO_2} = \dfrac{4,48}{22,4} = 0,2(mol)\\ n_{O_2(1)} = \dfrac{n_{CO_2}}{2} = 0,1(mol)\\ \Rightarrow n_{H_2} = 2n_{O_2(2)} = 2.(\dfrac{6,72}{22,4}-0,1)=0,4(mol)\\ \%V_{CO} = \dfrac{0,2}{0,2+0,4}.100\% = 33,33\%\\ \%V_{H_2} = 100\% -33,33\% = 66,67\%\)
\(\%m_{CO} = \dfrac{0,2.28}{0,2.28+0,4.2}.100\% = 87,5\%\\ \%m_{H_2} = 100\% - 87,5\% = 12,5\%\)
\(n_{H_2O}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
\(2H_2+O_2\underrightarrow{t^o}2H_2O\)
0,2 0,2
=> \(V_{H_2}=0,2.22,4=4,48\left(l\right)\\
\%V_{H_2}=\dfrac{4,48}{4,48+6,72}.100\%=40\%\\
\Rightarrow\%V_{O_2}=100\%-40\%=60\%\)
\(2CO + O_2 \xrightarrow{t^o} 2CO_2\\ 2H_2 + O_2 \xrightarrow{t^o} 2H_2O\\ n_{CO} = n_{CO_2} = \dfrac{8,8}{44} = 0,2(mol)\\ n_{O_2} = \dfrac{n_{CO} + n_{H_2}}{2}=\dfrac{0,2+n_{H_2}}{2} = \dfrac{9,6}{32} = 0,3(mol)\\ \Rightarrow n_{H_2} = 0,4(mol)\\ \%V_{CO} = \dfrac{0,2}{0,2 + 0,4}.100\% = 33,33\%\\ \%V_{H_2} = 100\% - 33,33\% = 66,67\%\\ \%m_{CO} = \dfrac{0,2.28}{0,2.28+0,4.2}.100\%=87,5\%\\ \%m_{H_2} = 100\% - 87,5\% = 12,5\%\)
\(n_{O_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\\ n_{CO_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
PTHH:
2CO + O2 --to--> 2CO2
0,2<---0,1<--------0,2
2H2 + O2 --to--> 2H2O
0,4<--0,2<-------0,2
\(\Rightarrow\left\{{}\begin{matrix}\%V_{CO}=\dfrac{0,2}{0,2+0,4}.100\%=33,33\%\\\%V_{H_2}=100\%-33,33\%=66,67\%\end{matrix}\right.\)
\(n_{CO_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\\ n_{O_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
PTHH: 2CO + O2 --to--> 2CO2
0,3<--0,15<------0,3
2H2 + O2 --to--> 2H2O
0,1<--0,05
\(\Rightarrow\left\{{}\begin{matrix}\%V_{CO}=\%n_{CO}=\dfrac{0,3}{0,3+0,1}.100\%=75\%\\\%V_{H_2}=100\%-75\%=25\%\end{matrix}\right.\)