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a. \(n_P=\frac{6,2}{31}=0,2mol\)
\(V_{O_2}=V_{kk}.\frac{1}{5}=\frac{18,48}{5}=3,696l\)
\(n_{O_2}=\frac{3,696}{22,4}=0,165mol\)
PTHH: \(4P+5O_2\xrightarrow{t^o}2P_2O_5\)
Tỷ lệ \(\frac{0,2}{4}>\frac{0,165}{5}\)
Vậy P dư
\(n_{P\left(\text{phản ứng }\right)}=\frac{4}{5}n_{O_2}=0,132mol\)
\(n_{P\left(dư\right)}=0,2-0,132=0,068mol\)
\(\rightarrow m_{P\left(dư\right)}=0,068.31=2,108g\)
b. \(n_{P_2O_5}=\frac{2}{5}n_{O_2}=0,066mol\)
\(\rightarrow m_{P_2O_5}=0,066.142=9,372g\)
c. PTHH: \(2KClO_3\xrightarrow{t^o}2KCl+3O_2\)
\(n_{KClO_3}=\frac{2}{3}n_{O_2}=0,11mol\)
\(\rightarrow m_{KClO_3}=0,11.122,5=13,475g\)
\(1,2H_2+O_2\underrightarrow{t}2H_2O\)
\(2Mg+O_2\underrightarrow{t}2MgO\)
\(2Cu+O_2\underrightarrow{t}2CuO\)
\(S+O_2\underrightarrow{t}SO_2\)
\(4Al+3O_2\underrightarrow{t}2Al_2O_3\)
\(C+O_2\underrightarrow{t}CO_2\)
\(4P+5O_2\underrightarrow{t}2P_2O_5\)
\(2,PTHH:C+O_2\underrightarrow{t}CO_2\)
\(a,n_{O_2}=0,2\left(mol\right)\Rightarrow n_{CO_2}=0,2\left(mol\right)\Rightarrow m_{CO_2}=8,8\left(g\right)\)
\(b,n_C=0,3\left(mol\right)\Rightarrow n_{CO_2}=0,3\left(mol\right)\Rightarrow m_{CO_2}=13,2\left(g\right)\)
c, Vì\(\frac{0,3}{1}>\frac{0,2}{1}\)nên C phản ửng dư, O2 phản ứng hết, Bài toán tính theo O2
\(n_{O_2}=0,2\left(mol\right)\Rightarrow n_{CO_2}=0,2\left(mol\right)\Rightarrow m_{CO_2}=8,8\left(g\right)\)
\(3,PTHH:CH_4+2O_2\underrightarrow{t}CO_2+2H_2O\)
\(C_2H_2+\frac{5}{2}O_2\underrightarrow{t}2CO_2+H_2O\)
\(C_2H_6O+3O_2\underrightarrow{t}2CO_2+3H_2O\)
\(4,a,PTHH:4P+5O_2\underrightarrow{t}2P_2O_5\)
\(n_P=1,5\left(mol\right)\Rightarrow n_{O_2}=1,2\left(mol\right)\Rightarrow m_{O_2}=38,4\left(g\right)\)
\(b,PTHH:C+O_2\underrightarrow{t}CO_2\)
\(n_C=2,5\left(mol\right)\Rightarrow n_{O_2}=2,5\left(mol\right)\Rightarrow m_{O_2}=80\left(g\right)\)
\(c,PTHH:4Al+3O_2\underrightarrow{t}2Al_2O_3\)
\(n_{Al}=2,5\left(mol\right)\Rightarrow n_{O_2}=1,875\left(mol\right)\Rightarrow m_{O_2}=60\left(g\right)\)
\(d,PTHH:2H_2+O_2\underrightarrow{t}2H_2O\)
\(TH_1:\left(đktc\right)n_{H_2}=1,5\left(mol\right)\Rightarrow n_{O_2}=0,75\left(mol\right)\Rightarrow m_{O_2}=24\left(g\right)\)
\(TH_2:\left(đkt\right)n_{H_2}=1,4\left(mol\right)\Rightarrow n_{O_2}=0,7\left(mol\right)\Rightarrow m_{O_2}=22,4\left(g\right)\)
\(5,PTHH:S+O_2\underrightarrow{t}SO_2\)
\(n_{O_2}=0,46875\left(mol\right)\)
\(n_{SO_2}=0,3\left(mol\right)\)
Vì\(0,46875>0,3\left(n_{O_2}>n_{SO_2}\right)\)nên S phản ứng hết, bài toán tính theo S.
\(a,\Rightarrow n_S=n_{SO_2}=0,3\left(mol\right)\Rightarrow m_S=9,6\left(g\right)\)
\(n_{O_2}\left(dư\right)=0,16875\left(mol\right)\Rightarrow m_{O_2}\left(dư\right)=5,4\left(g\right)\)
\(6,a,PTHH:C+O_2\underrightarrow{t}CO_2\)
\(n_{O_2}=1,5\left(mol\right)\Rightarrow n_C=1,5\left(mol\right)\Rightarrow m_C=18\left(g\right)\)
\(b,PTHH:2H_2+O_2\underrightarrow{t}2H_2O\)
\(n_{O_2}=1,5\left(mol\right)\Rightarrow n_{H_2}=0,75\left(mol\right)\Rightarrow m_{H_2}=1,5\left(g\right)\)
\(c,PTHH:S+O_2\underrightarrow{t}SO_2\)
\(n_{O_2}=1,5\left(mol\right)\Rightarrow n_S=1,5\left(mol\right)\Rightarrow m_S=48\left(g\right)\)
\(d,PTHH:4P+5O_2\underrightarrow{t}2P_2O_5\)
\(n_{O_2}=1,5\left(mol\right)\Rightarrow n_P=1,2\left(mol\right)\Rightarrow m_P=37,2\left(g\right)\)
\(7,n_{O_2}=5\left(mol\right)\Rightarrow V_{O_2}=112\left(l\right)\left(đktc\right)\);\(V_{O_2}=120\left(l\right)\left(đkt\right)\)
\(8,PTHH:C+O_2\underrightarrow{t}CO_2\)
\(m_C=0,96\left(kg\right)\Rightarrow n_C=0,08\left(kmol\right)=80\left(mol\right)\Rightarrow n_{O_2}=80\left(mol\right)\Rightarrow V_{O_2}=1792\left(l\right)\)
\(9,n_p=0,2\left(mol\right);n_{O_2}=0,3\left(mol\right)\)
\(PTHH:4P+5O_2\underrightarrow{t}2P_2O_5\)
Vì\(\frac{0,2}{4}< \frac{0,3}{5}\)nên P hết O2 dư, bài toán tính theo P.
\(a,n_{O_2}\left(dư\right)=0,05\left(mol\right)\Rightarrow m_{O_2}\left(dư\right)=1,6\left(g\right)\)
\(b,n_{P_2O_5}=0,1\left(mol\right)\Rightarrow m_{P_2O_5}=14,2\left(g\right)\)
a) Ta có:
nMg= \(\frac{m_{Mg}}{M_{Mg}}=\frac{6}{24}=0,25\left(mol\right)\)
PTHH: Mg + 2HCl -> MgCl2 + H2 (1)
PTHH: 2H2 + O2 \(\underrightarrow{t^o}\) 2H2O (2)
b) Theo các PTHH và đề bài , ta có:
\(n_{H_2}\)= nMg= 0,25 (mol)
Thể tích khí H2 thu được (đktc):
=> \(V_{H_2\left(đktc\right)}=n_{H_2\left(1\right)}.22,4=0,25.22,4=5,6\left(l\right)\)
c) Ta có: \(n_{H_2\left(2\right)}=n_{H_2\left(1\right)}=0,25\left(mol\right)\)
Mà, ta lại có: \(n_{H_2O\left(2\right)}=n_{H_2\left(2\right)}=0,25\left(mol\right)\)
=> \(m_{H_2O\left(2\right)}=n_{H_2O\left(2\right)}.M_{H_2O}=0,25.18=4,5\left(g\right)\)
\(nNa=\dfrac{6,9}{23}=0,3\left(mol\right)\)
\(4Na+O_2\underrightarrow{t^o}2Na_2O\)
4 1 2 (mol)
0,3 0,075 0,15
\(VO_2=0,075.22,4=1,68\left(l\right)\)
\(Na_2O+H_2O\rightarrow2NaO H\)
1 1 2 (mol)
0,15 0,15 0,3 (mol)
\(m_{NaOH}=0,3.40=12\left(g\right)\)
\(C\%_{ddA}=\dfrac{12.100}{180}=6,67\%\)
\(a) 4Na + O_2 \xrightarrow{t^o} 2Na_2O\\ b) n_{Na} = \dfrac{4,6}{23} = 0,2(mol)\\ n_{O_2} = \dfrac{1}{4}n_{Na} = 0,05(mol)\\ V_{O_2} = 0,05.22,4 = 1,12(lít)\\ c) Na_2O + H_2O \to 2NaOH\\ n_{NaOH} = n_{Na} = 0,2(mol)\\ C\%_{NaOH} = \dfrac{0,2.40}{160}.100\% = 5\%\\ d)\)
\(n_{Na\ thêm} = x(mol)\\ 2Na + 2H_2O \to 2NaOH + H_2\\ n_{NaOH} = n_{Na} = x(mol)\\ n_{H_2} =0,5x(mol)\\ \Rightarrow m_{dd} = 23x + 160 -0,5x.2 = 22x + 160(gam)\\ \Rightarrow C\% = \dfrac{0,2.40 + 40x}{22x + 160}.100\% = 5\% + 5\%\\ \Rightarrow x = \dfrac{40}{189}\\ m_{Na} = \dfrac{40}{189}.23 = 4,87(gam)\)
\(n_{Na}=\dfrac{4.6}{23}=0.2\left(mol\right)\)
\(4Na+O_2\underrightarrow{^{t^0}}2Na_2O\)
\(0.2.....0.05.........0.1\)
\(V_{O_2}=0.05\cdot22.4=1.12\left(l\right)\)
\(Na_2O+H_2O\rightarrow2NaOH\)
\(0.1.......................0.2\)
\(m_{NaOH}=0.2\cdot40=8\left(g\right)\)
\(C\%_{NaOH}=\dfrac{8}{160}\cdot100\%=5\%\)
Để C% tăng thêm 5%
\(Na+H_2O\rightarrow NaOH+\dfrac{1}{2}H_2\)
\(a...............a.......0.5a\)
\(m_{NaOH}=40a\left(g\right)\)
\(m_{dd_{NaOH}}=23a+160-0.5a\cdot2=22a+160\left(g\right)\)
\(C\%_{NaOH}=\dfrac{40a+8}{22a+160}\cdot100\%=5\%\)
\(\Rightarrow a=0\)
=> Sai đề
a)
nNa = 11,5 : 23 = 0,5 mol
4Na + O2 → 2Na2O
Theo tỉ lệ phương trình => nO2 phản ứng = 1/4nNa = 0,5 : 4 = 0,125 mol
=> VO2 phản ứng = 0,125.22,4 = 2,8 lít.
b)
Na2O + H2O → 2NaOH
nNa2O = 1/2 nNa = 0,25 mol
=> nNaOH = 2nNa2O = 0,5 mol
<=> CNaOH = 0,5 : 0,25 = 2M. Và A thuộc loại hợp chất bazơ.
\(n_{H_2}=\dfrac{3,36}{22,4}=0,15(mol)\\ PTHH:Fe+H_2SO_4\to FeSO_4+H_2\\ \Rightarrow n_{H_2SO_4}=n_{H_2}=0,15(mol)\\ \Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,15}{0,05}=3M\\ PTHH:2H_2+O_2\xrightarrow{t^o}2H_2O\\ \Rightarrow n_{O_2}=\dfrac{1}{2}n_{H_2}=0,075(mol)\\ \Rightarrow V_{O_2}=0,075.22,4=1,68(l)\)
Bài 1 :
a. \(n_{Al}=\dfrac{10,8}{27}=0,4\left(mol\right)\)
\(n_{O_2}=\dfrac{16}{32}=0,5\left(mol\right)\)
b. PTHH : 4Al + 3O2 -to> 2Al2O3
0,4 0,3 0,2
Xét tỉ lệ : \(\dfrac{0,4}{4}< \dfrac{0,5}{3}\) => Al đủ , O2 dư
\(m_{O_2\left(dư\right)}=\left(0,5-0,3\right).32=6,4\left(g\right)\)
c. \(m_{Al_2O_3}=0,2.102=20,4\left(g\right)\)
Bài 2:
| Các thời điểm | Fe2O3 (gam) | CO (lít) | Fe(gam) | CO2(lít) | dkhí/H2 |
| Thời điểm t0 | 16 | 8,96 | 11,2 | 6,72 | 20 |
| Thời điểm t1 | 3,2 | 1,344 | 2,24 | 1,344 | 22 |
| Thời điểm t2 | 128/15 | 3,584 | 448/75 | 3,584 | 22 |
| Thời điểm t3 | 16 | 6,72 | 11,2 | 6,72 | 22 |
\(n_P=\dfrac{6,2}{31}=0,2mol\)
\(4P+5O_2\rightarrow\left(t^o\right)2P_2O_5\)
0,2 0,25 0,1 ( mol )
\(V_{O_2}=0,25.22,4.\left(100+30\right)\%=7,28l\)
\(m_{H_2O}=\dfrac{235,8}{18}=13,1mol\)
\(P_2O_5+3H_2O\rightarrow2H_3PO_4\)
0,1 < 13,1 ( mol )
0,1 0,2 ( mol )
\(m_{ddspứ}=\left(0,1.142\right)+235,8=250g\)
\(C\%_{H_3PO_4}=\dfrac{0,2.98}{250}.100=7,84\%\)
\(V_{H_3PO_4}=\dfrac{0,2.98}{1,25}=15,68ml=0,01568l\)
\(C_M=\dfrac{0,2}{0,01568}=12,75M\)
Lần đầu thấy công thức \(m=\dfrac{V}{M}\) và cái sai thứ 2 là dùng m mà đơn vị mol