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a)
\(n_{Al} = \dfrac{12,15}{27} = 0,45(mol)\\ n_{O_2} = \dfrac{6,72}{22,4} = 0,3(mol)\\ 4Al + 3O_2 \xrightarrow{t^o} 2Al_2O_3\\ \dfrac{n_{Al}}{4} = 0,1125 < \dfrac{n_{O_2}}{3} = 0,1\)
Do đó, Al dư.
\(n_{Al\ pư} = \dfrac{4}{3}n_{O_2} = 0,4(mol)\\ m_{Al\ dư} = (0,45-0,4).27 =1,35(gam)\)
b) Nhôm oxit được tạo thành.
\(n_{Al_2O_3} = \dfrac{2}{3}n_{O_2} = 0,2(mol)\\ \Rightarrow m_{Al_2O_3} = 0,2.102 = 20,4(gam)\)
\(n_{Al}=\dfrac{m}{M}=0,45\left(mol\right)\)
\(n_{O_2}=\dfrac{V}{22,4}=0,3\left(mol\right)\)
a, \(PTHH:4Al+3O_2\rightarrow2Al_2O_3\)
=> Sau phản ứng O2 hết, Al dư ( dư 0,05 mol )
=> \(m_{Aldu}=n.M=1,35\left(g\right)\)
b, Chất được tạo thành là Al2O3 .
Theo PTHH : \(n_{Al_2O_3}=0,2\left(mol\right)\)
\(\Rightarrow m_{Al_2O_3}=n.M=20,4\left(g\right)\)
Vậy ...
nP = 6.2/31 = 0.2 (mol)
nO2 = 6.72/22.4 = 0.3 (mol)
4P + 5O2 -to-> 2P2O5
0.2___0.25_____0.1
mO2 dư = ( 0.3 - 0.25) * 32 = 1.6(g)
mP2O5 = 0.1*142 = 14.2 (g)
Ta có: \(n_P=\dfrac{6.2}{31}=0.29mol\)
\(n_{O_2}=\dfrac{6.72}{22.4}=0.3mol\)
PTHH:
\(4P+5O_2\underrightarrow{t^o}2P_2O_5\)
ta có:
\(\left\{{}\begin{matrix}\dfrac{n_{P\left(bra\right)}}{nP_{\left(pthh\right)}}=\dfrac{0.2}{4}=0.05\\\dfrac{n_{O_2\left(bra\right)}}{n_{O_2}\left(pthh\right)}=\dfrac{0.3}{5}=0.06\end{matrix}\right.\)
=> \(O_2\) dư
\(4P+5O_2\underrightarrow{t^o}2P_2O_5\)
4 ----------->2
0.2---------->0.1=nP2O5
=>\(m_{P_2O_5}=142.0.1=14.2\left(g\right)\)
nAl=\(\dfrac{5,4}{27}\)=0,2mol
nO2=\(\dfrac{4,48}{22,4}\)=0,2mol
PTHH:
4Al + 3O2--to->2Al2O3
Tỉ lệ \(\dfrac{0,2}{4}\) <\(\dfrac{0,2}{3}\)->Al hết O2 dưtính theo Al
=>m O2=\(\dfrac{1}{60}\).32=\(\dfrac{8}{15}\)g
2KMnO4-to>K2MnO4+MnO2+O2
0,4--------------------------------------0,2
m KMnO4=0,4.158=63,2g
.
\(a)\\ n_{O_2} = \dfrac{6,72}{22,4} = 0,3(mol)\\ 4P + 5O_2 \xrightarrow{t^o} 2P_2O_5\\ \dfrac{n_P}{4} = 0,05 < \dfrac{n_{O_2}}{5} = 0,06\)
Do đó, Oxi dư.
\(n_{O_2\ pư} = \dfrac{5}{4}n_P = 0,25(mol)\\ \Rightarrow m_{O_2\ dư} = (0,3 - 0,25).32 = 1,6(gam)\\ b)\\ n_{P_2O_5} = \dfrac{n_P}{2} = 0,1(mol)\\ \Rightarrow m_{P_2O_5} = 0,1.142 = 14,2(gam)\)
Bài 1:
\(a,2Cu+O_2\underrightarrow{t^o}2CuO\)
b, \(n_{O_2}=\dfrac{1,12}{32}=0,035mol\)
\(n_{Cu}=\dfrac{6,4}{64}=0,1mol\)
\(\dfrac{0,1}{2}>\dfrac{0,035}{1}\) => Cu dư, O2 đủ
\(n_{Cu}\left(dư\right)=0,1-0,07=0,039\left(mol\right)\)
c, \(m_{CuO}=0,07.80=5,6g\)
Bài 2:
\(n_{Al}=\dfrac{13,5}{27}=0,5mol\)
\(n_{O_2}=\dfrac{6,67}{32}=0,21\left(mol\right)\)
\(4Al+3O_2\underrightarrow{t^o}2Al_2O_3\)
\(\dfrac{0,5}{4}>\dfrac{0,21}{3}\) => Al dư, O2 đủ
\(n_{Al_2O_3}=\dfrac{2}{3}.0,21=0,14\left(mol\right)\)
\(m_{Al_2O_3}=0,14.102=14,28g\)
nP=\(\dfrac{62}{31}\)=0,2(mol)
nO2=\(\dfrac{7,84}{22,4}\)=0,35(mol)
PTHH:4P+5O2to→2P2O5
tpứ: 0,2 0,35
pứ: 0,2 0,25 0,1
spứ: 0 0,1 0,1
a)chất còn dư là oxi
mO2dư=0,1.32=3,2(g)
b)mP2O5=n.M=0,1.142=14,2(g)
\(a.n_P=0,2\left(mol\right);n_{O_2}=0,35\left(mol\right)\\ 4P+5O_2-^{t^o}\rightarrow2P_2O_5\\ LTL:\dfrac{0,2}{4}< \dfrac{0,35}{5}\\ \Rightarrow SauphảnứngO_2dư\\ n_{O_2\left(pứ\right)}=\dfrac{5}{4}n_P=0,25\left(mol\right)\\ \Rightarrow m_{P\left(dư\right)}=\left(0,35-0,25\right).32=3,2\left(g\right)\\ b.n_{P_2O_5}=\dfrac{1}{2}n_P=0,1\left(mol\right)\\ \Rightarrow m_{P_2O_5}=0,1.142=14,2\left(g\right)\)
\(n_{Na}=\dfrac{4.6}{23}=0.2\left(mol\right)\)
\(n_{O_2}=\dfrac{0.448}{22.4}=0.02\left(mol\right)\)
\(4Na+O_2\underrightarrow{^{^{t^0}}}2Na_2O\)
\(4..........1\)
\(0.2.....0.02\)
\(LTL:\dfrac{0.2}{4}>\dfrac{0.02}{1}\Rightarrow Nadư\)
\(m_{Na\left(dư\right)}=\left(0.2-0.08\right)\cdot23=2.76\left(g\right)\)
\(m_{Na_2O}=0.04\cdot62=2.48\left(g\right)\)
a) \(n_{Al}=\dfrac{12,15}{27}=0,45\left(mol\right)\)
\(n_{O_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
PTHH: 4Al + 3O2 --to--> 2Al2O3
Xét tỉ lệ: \(\dfrac{0,45}{4}>\dfrac{0,3}{3}\)=> Al dư, O2 hết
PTHH: 4Al + 3O2 --to--> 2Al2O3
0,4<--0,3-------->0,2
=> \(m_{Al\left(dư\right)}=\left(0,45-0,4\right).27=1,35\left(g\right)\)
b) \(m_{Al_2O_3}=0,2.102=20,4\left(g\right)\)